全文获取类型
收费全文 | 214篇 |
免费 | 2篇 |
国内免费 | 3篇 |
专业分类
化学 | 139篇 |
力学 | 1篇 |
数学 | 53篇 |
物理学 | 26篇 |
出版年
2023年 | 1篇 |
2022年 | 3篇 |
2021年 | 5篇 |
2020年 | 2篇 |
2019年 | 1篇 |
2018年 | 3篇 |
2017年 | 5篇 |
2016年 | 3篇 |
2015年 | 2篇 |
2014年 | 6篇 |
2013年 | 10篇 |
2012年 | 9篇 |
2011年 | 18篇 |
2010年 | 11篇 |
2009年 | 7篇 |
2008年 | 12篇 |
2007年 | 22篇 |
2006年 | 13篇 |
2005年 | 9篇 |
2004年 | 13篇 |
2003年 | 8篇 |
2002年 | 11篇 |
2001年 | 2篇 |
2000年 | 3篇 |
1999年 | 5篇 |
1998年 | 2篇 |
1997年 | 2篇 |
1996年 | 3篇 |
1995年 | 1篇 |
1994年 | 5篇 |
1993年 | 4篇 |
1991年 | 4篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1986年 | 2篇 |
1985年 | 3篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1974年 | 2篇 |
1972年 | 1篇 |
排序方式: 共有219条查询结果,搜索用时 0 毫秒
31.
Dwyer JT Holden J Andrews K Roseland J Zhao C Schweitzer A Perry CR Harnly J Wolf WR Picciano MF Fisher KD Saldanha LG Yetley EA Betz JM Coates PM Milner JA Whitted J Burt V Radimer K Wilger J Sharpless KE Hardy CJ 《Analytical and bioanalytical chemistry》2007,389(1):37-46
This article illustrates the importance of having analytical data on the vitamin and mineral contents of dietary supplements
in nutrition studies, and describes efforts to develop an analytically validated dietary supplement ingredient database (DSID)
by a consortium of federal agencies in the USA. Preliminary studies of multivitamin mineral supplements marketed in the USA
that were analyzed as candidates for the DSID are summarized. Challenges are summarized, possible future directions are outlined,
and some related programs at the Office of Dietary Supplements, National Institutes of Health are described. The DSID should
be helpful to researchers in assessing relationships between intakes of vitamins and minerals and health outcomes. 相似文献
32.
33.
Marikkar FS Carter C Kieltyka K Robertson JW Williamson C Simmonds A Zangmeister R Fritz T Armstrong NR 《Langmuir : the ACS journal of surfaces and colloids》2007,23(20):10395-10402
Conducting polymer diffraction gratings on Au substrates have been created using microcontact printing of C18-alkanethiols, followed by electropolymerization of either poly(aniline) (PANI) or poly(3,4-ethylenedioxythiophene) (PEDOT). Soft-polymer replicas of simple diffraction grating masters (1200 lines/mm) were used to define the alkanethiol template for polymer growth. Growth of PANI and PEDOT diffraction gratings was followed in real time, through in situ tapping-mode atomic force microscopy, and by monitoring diffraction efficiency (DE) as a function of grating depth. DE increased as grating depth increased, up to a limiting efficiency (13-26%, with white light illumination), defined by the combined optical properties of the grating and the Au substrate, and ultimately limited by the loss of resolution due to coalescence of the polymer films. Grating efficiency is strongly dependent upon the grating depth and the refractive index contrast between the grating material and the surrounding solutions. Both PEDOT and PANI gratings show refractive index changes as a function of applied potential, consistent with changes in refractive index brought about by the doping/dedoping of the conducting polymer. The DE of PANI gratings are strongly dependent on the pH of the superstrate solution; the maximum sensitivity (DeltaDE/DeltapH) is achieved with PANI gratings held at +0.4 V versus Ag/AgCl, where the redox chemistry is dominated by the acid-base equilibrium between the protonated (emeraldine salt) and deprotonated (emeraldine base) forms of PANI. Simulations of DE were conducted for various combinations of conducting polymer refractive index and grating depth, to compute sensitivity parameters, which are maximized when the grating depth is ca. 50% of its maximum obtainable depth. 相似文献
34.
Kathy C. Chuang Daniel A. Scheiman Joyce Fu Marcus Crawford 《Journal of polymer science. Part A, Polymer chemistry》1999,37(14):2559-2567
Thermoplastic and thermoset polyimides derived from 2,2-bis[4-(4-aminophenoxy)phenyl]propane (BAPP) and 4,4′-bis(4-aminophenoxy)-2,2′-dimethylbiphenyl (BAPD) were prepared and characterized. Their physical and thermal properties as well as the polyelectrolyte effect exhibited by BTDA–BAPP polyamic acids in NMP solution were discussed. © 1999 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 37: 2559–2567, 1999 相似文献
35.
36.
A fluorogen named 1-decyl-1-methyl-2,5-bis{4-[(N,N-diethylamino)methyl]phenyl}-3,4-diphenylsilole (3) was synthesized. It emitted weakly as isolated molecule but strongly as
supramolecular aggregate, showing a characteristic behavior of aggregation-induced emission (AIE). The molecules of 3 formed
highly emissive nanoparticles in aqueous media, which quickly and selectively marked cytoplasm of HeLa cells and posed no
toxicity to the living cells. The fluorogen is thus a promising candidate material for cell imaging as a sensitive, selective
and cytocompatible biosensor.
Supported by the Research Grants Council of Hong Kong (Grant Nos. 603008, 601608 and 602707), the National Natural Science
Foundation of China (Grant No. 20634020) and the CAO GuangBiao Foundation of Zhejiang University. 相似文献
37.
A commercial in-tube sorptive extraction device, known as solid-phase dynamic extraction (SPDE), has been evaluated for the extraction of non-polar volatile aromatic analytes from aqueous solutions in both headspace and liquid injection modes. An automated sampler is used with a gas-tight 2.5 ml syringe equipped with a special needle that is coated on the inside with a non-polar extraction phase. After absorption onto the phase, the analytes were thermally desorbed directly into a GC-MS system. The technique was evaluated for the determination of furan, benzene and toluene. The sensitivity for toluene was greatly improved on using SPDE compared to static headspace. A slight increase in sensitivity was observed for benzene but none for determination of furan. Estimated limits of detection ranged from 0.2 to 2 microg/l. 相似文献
38.
Emily C. Corcoran William Forest Robert Horton David G. Kelly Kristine Mattson Curtis McDonld Kathy S. Nielsen Kristin Topping Ron D. Weir Andre Yonkeu 《Journal of Radioanalytical and Nuclear Chemistry》2012,291(1):251-256
Commercial radio-opaque combat (CRC) fabrics, for incorporation into personal protective equipment used by first responders
and armed forces, are marketed as having the ability to provide a level of protection against specific types of radiation.
For a CRC material, a standard combat uniform and a multi-layered chemical, biological, radiological, nuclear (CBRN) protective
material, the present work examines chemical composition and radiation protection against gamma-rays and neutron fluxes. Significant
reduction in gamma-ray transmittance occurs only for the CRC fabric (46–514 keV) with gamma-ray attenuation coefficients of
3.10 to <0.10 cm2 g−1. Reduction in neutron transmittance, for all three fabrics, could not be assessed with certainty as the measured transmittance
was obscured by large statistical uncertainties. 相似文献
39.
Kathy Hoke 《Discrete Applied Mathematics》1995,60(1-3):211-217
Let P be a simplicial d-polytope with n facets ((d − 1)-dimensional faces) in Rd. A shelling of P is an ordering of the facets of P such that the intersection of each facet F with the union of all facets that precede it the ordering is a nonempty union of (d − 2)-faces of F. The following open question was raised by Tverberg and is recorded in [4]. Suppose for some k < n, there is an ordering of k of the facets of P so that the intersection of each of these facets with the union of all of the facets that precede it in the ordering is a nonempty union of (d − 2)-faces. Can this initial “segment” be extended to a shelling of all the facets? This question is open even in the case that P is the dual of the d-dimensional hypercube. The question in this case has resurfaced several times since G. Danaraj and V. Klee (1978) in a variety of forms. It is related to the hierarchies of completely unimodal pseudo-Boolean functions studied in P.L. Hammer et al. (1988), the author (1988) and D. Wiedemann (1986). (A pseudo-Boolean function is a function mapping the vertices of the d-dimensional hypercube into the reals). In this paper, the hierarchies are compared and combined. This hierarchy is then extended to general simple polytopes, and the relationship to the above open question is explained. 相似文献
40.
Kathy Hann 《Geometriae Dedicata》1997,64(3):355-364
In this paper we will establish bounds on the average number of normals through a point in a convex body in a Minkowski plane for certain classes of convex bodies. Also, a related Euler relation is discussed. 相似文献