全文获取类型
收费全文 | 940篇 |
免费 | 42篇 |
国内免费 | 8篇 |
专业分类
化学 | 775篇 |
晶体学 | 16篇 |
力学 | 3篇 |
数学 | 77篇 |
物理学 | 119篇 |
出版年
2023年 | 12篇 |
2022年 | 13篇 |
2021年 | 24篇 |
2020年 | 37篇 |
2019年 | 30篇 |
2018年 | 14篇 |
2017年 | 9篇 |
2016年 | 31篇 |
2015年 | 29篇 |
2014年 | 17篇 |
2013年 | 68篇 |
2012年 | 77篇 |
2011年 | 76篇 |
2010年 | 30篇 |
2009年 | 30篇 |
2008年 | 58篇 |
2007年 | 78篇 |
2006年 | 75篇 |
2005年 | 53篇 |
2004年 | 38篇 |
2003年 | 34篇 |
2002年 | 32篇 |
2001年 | 8篇 |
2000年 | 8篇 |
1999年 | 9篇 |
1998年 | 8篇 |
1997年 | 5篇 |
1996年 | 6篇 |
1995年 | 5篇 |
1994年 | 7篇 |
1993年 | 3篇 |
1992年 | 5篇 |
1991年 | 4篇 |
1990年 | 3篇 |
1989年 | 3篇 |
1988年 | 5篇 |
1987年 | 4篇 |
1986年 | 3篇 |
1985年 | 2篇 |
1983年 | 4篇 |
1982年 | 6篇 |
1981年 | 2篇 |
1980年 | 3篇 |
1978年 | 2篇 |
1976年 | 2篇 |
1974年 | 2篇 |
1972年 | 2篇 |
1948年 | 1篇 |
1943年 | 1篇 |
1940年 | 1篇 |
排序方式: 共有990条查询结果,搜索用时 15 毫秒
111.
112.
The 60 MHz 1H NMR spectra of racemic 5-[[3,5-bis(1,1-dimethylethyl)-4-hydroxyphenyl]methyl]-4-thiazolidinone, 1, have been studied in CDCl3 solution at 28° with the achiral lanthanide shift reagent (LSR), tris (6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)europium (III), 2, and the chiral LSRs, tris[3-(heptafluoropropylhydroxymethylene)- (+)-camphoratojeuropium(III), 3, and tris[3-(trifluoromethylhydroxymethylene-(+) -camphorato]europium (III), 4, Significant enantiomeric shift differences were observed in the presence of added 3, for the aryl protons of 1 that should permit direct determination of enantiomeric excess. Relative magnitudes of lanthanide-induced shift for the different nuclei of 1 with the three LSRs are compared and discussed in terms of preferred LSR binding sites. A favored conformation of 1 with respect to rotation about the C(5)-CH2 bond is suggested. 相似文献
113.
Recent work on Pitman closeness has compared estimators under Type-II censored samples from exponential distribution based on observed number of failures. In this paper, we carry out similar Pitman closeness comparisons for Type-I censored samples from exponential distribution based on time under test. 相似文献
114.
Katherine Pinzon 《代数通讯》2013,41(6):2186-2194
Absolutely pure modules act in ways similar to injective modules. There are conditions on a ring which guarantee that the class of injective modules will be covering. In this article, we define conditions on the ring R which guarantee that the class of absolutely pure modules will be covering. These include R being left coherent, which we show implies a number of other necessary properties. 相似文献
115.
Marcus B. Kindervater Katherine M. Marczenko Ulrike Werner‐Zwanziger Saurabh S. Chitnis 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(23):7932-7937
Reaction of a tethered triamine ligand with Bi(NMe2)3 gives a Bi triamide, for which a BiI electronic structure is shown to be most appropriate. The T‐shaped geometry at bismuth provides the first structural model for edge inversion in bismuthines and the only example of a planar geometry for pnictogen triamides. Analogous phosphorus compounds exhibit a distorted pyramidal geometry because of different Bi?N and P?N bond polarities. Although considerable BiI character is indicated for the title Bi triamide, it exhibits reactivity similar to BiIII electrophiles, and expresses either a vacant or a filled p orbital at Bi, as evidenced by coordination of either pyridine N‐oxide or W(CO)5. The product of the former shows evidence of coordination‐induced oxidation state change at bismuth. 相似文献
116.
Katherine M. Marczenko Joseph A. Zurakowski Karlee L. Bamford Joshua W. M. MacMillan Saurabh S. Chitnis 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(50):18264-18269
A rigid naphthalenediamine framework has been used to prepare antimony hydrides that feature LUMO shapes and energies similar to those found in secondary boranes. By exploiting this feature, we introduce the first examples of uncatalyzed hydrostibination reactions of robust C≡C, C=C, C=O, and N=N bonds as new elementary hydrometalation reactions analogous to hydroboration. These results endorse the notion of a diagonal relationship between the lightest p‐block element and the heaviest Group 15 elements and may lead to the conception of novel reaction chemistry. 相似文献
117.
Walker M. Jones Aaron G. Davis R. Hunter Wilson Katherine L. Elliott Isaiah Sumner 《Journal of computational chemistry》2019,40(22):1969-1977
The mechanism used by the ubiquitin-conjugating enzyme, Ubc13, to catalyze ubiquitination is probed with three computational techniques: Born–Oppenheimer molecular dynamics, single point quantum mechanics/molecular mechanics energies, and classical molecular dynamics. These simulations support a long-held hypothesis and show that Ubc13-catalyzed ubiquitination uses a stepwise, nucleophilic attack mechanism. Furthermore, they show that the first step—the formation of a tetrahedral, zwitterionic intermediate—is rate limiting. However, these simulations contradict another popular hypothesis that supposes that the negative charge on the intermediate is stabilized by a highly conserved asparagine (Asn79 in Ubc13). Instead, calculated reaction profiles of the N79A mutant illustrate how charge stabilization actually increases the barrier to product formation. Finally, an alternate role for Asn79 is suggested by simulations of wild-type, N79A, N79D, and H77A Ubc13: it stabilizes the motion of the electrophile prior to the reaction, positioning it for nucleophilic attack. © 2019 Wiley Periodicals, Inc. 相似文献
118.
119.
Katherine A. Seaton 《International Journal of Mathematical Education in Science & Technology》2019,50(7):1063-1072
ABSTRACTTo date, the way that academic misconduct is manifested in undergraduate mathematics coursework has been unexamined in the literature, with the consequence that policy and preventive education can fail to address it appropriately. This paper describes the particular features of the responses expected in mathematical tasks and provides concrete examples of what lapses of integrity look like in this context. The intent is to lay groundwork for discussion and a response to this issue from within our discipline. 相似文献
120.
Dr. Katherine Villa Dr. Jan Vyskočil Dr. Yulong Ying Dr. Jaroslav Zelenka Prof. Martin Pumera 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(14):3039-3043
Yeasts play a key role in the production of alcoholic beverages by fermentation processes. However, because of their continuous growth, they commonly cause spoilage of the final product. Herein, we introduce dual magnetic/light-responsive self-propelled microrobots that can actively move in a beer sample and capture yeast cells. The presence of magnetic nanoparticles on the surface of the microrobots enables their magnetic actuation under fuel-free conditions. In addition, their photoactivity under visible-light irradiation leads to an overall enhancement of their swimming and yeast removal capabilities. It was found that after the application of the microrobots into a real unfiltered beer sample, these micromachines were able to remove almost 100 % of residual yeasts. In addition, these microrobots could also be added at the initial step of the fermentation process without altering the final beer properties, such as alcohol level, color, and pH. This work demonstrates the potential of using externally actuated microrobots as an innovative and low-cost solution for avoiding yeast spoilage in complex liquid environments, such as alcoholic beverages. Therefore, these autonomous self-propelled microrobots open new avenues for future applications in the food industry. 相似文献