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Mueller CA Weinmann W Dresen S Schreiber A Gergov M 《Rapid communications in mass spectrometry : RCM》2005,19(10):1332-1338
A new multi-target screening (MTS) procedure for drugs in blood and urine for toxicological analysis has been developed using a hybrid triple-quadrupole linear ion trap mass spectrometer (QTrap) for the fast detection and identification of 301 forensically important drugs, e.g. tranquilizers (benzodiazepines), hypnotics, drugs of abuse (opiates, cocaine, amphetamines, cannabinoids), antidepressants, neuroleptics, and some cardiac drugs, in one single liquid chromatography/tandem mass spectrometry (LC/MS/MS) analysis. Samples were extracted either with liquid-liquid extraction or solid-phase extraction. A multiple reaction monitoring (MRM) as survey scan and an enhanced product ion (EPI) scan as dependent scan were performed in an information-dependent acquisition (IDA) experiment. Finally, drug identification was carried out by library search with a newly developed MS/MS library based on EPI spectra at three different collision energies in positive mode. The advantage of this newly developed method is the possibility to detect and identify 301 drugs in one single LC/MS/MS run. 相似文献
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John D. Mertens Katharina Kohse-Hinghaus Ronald K. Hanson Craig T. Bowman 《国际化学动力学杂志》1991,23(8):655-668
The reaction of atomic hydrogen with isocyanic acid (HNCO) to produce the amidogen radical (NH2) and carbon monoxide, has been studied in shock-heated mixtures of HNCO dilute in argon. Time-histories of the ground-state NH2 radical were measured behind reflected shock waves using cw, narrowlinewidth laser absorption at 597 nm, and HNCO time-histories were measured using infrared emission from the fundamental v2-band of HNCO near 5 μm. The second-order rate coefficient of reaction (2(a)) was determined to be: cm3 mol?1 s?1, where f and F define the lower and upper uncertainty limits, respectively. An upper limit on the rate coefficient of was determined to be: 相似文献
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Novel l -tartaric acid based stereodynamic biphenylbisphosphinite ligands with anilino linkers were prepared as cyclic diamide compounds. The influence of the constitutional substitution pattern of the amino group at the aniline moiety on the diastereoselective formation of the ligand was investigated. While the meta-anilino bridged ligands showed a highly dynamic behavior and no discrimination between (Rax) and (Sax) configuration, l -tartaric acid substitution on ortho-anilino bridged ligands leads to diastereoselective self-alignment of the central biphenol axis, which controls the stereoselectivity of the ligand and catalyst. The experimental findings were corroborated by theoretical calculations. In the rhodium-catalyzed enantioselective hydrogenation of methyl 2-acetamidoacrylate (MAA), an enantiomeric ratio of 75 : 25 (R/S) was obtained for the ortho-substituted ligand. 相似文献
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Joerg Max Siebert Grit Baier Katharina Landfester 《Journal of polymer science. Part A, Polymer chemistry》2012,50(1):80-88
A new class of polyurethanes has been designed, containing tertiary carbamate groups in the main chain of the polymer, which enable the resulting polymer to degrade completely under acid and thermal treatment. The decomposition temperatures of the polymers were determined by measuring the evolution of carbon dioxide and other decomposition products using TGA‐MS. Until decomposition of the polymer, no glass transition was found. The polymers exhibit excellent solubility in common organic solvents like chloroform and tetrahydrofuran, making them to suitable materials for film formation. From the obtained polymers, nanoparticles were synthesized by the solvent evaporation method combined with the miniemulsion technique. The resulting nanoparticles can be used as intelligent fillers in films and sensors, since they degrade at temperatures of above 180 °C, which can be detected by a color change reaction with ninhydrin. Polymeric nanocapsules were prepared by an interfacial polyaddition reaction from 2,4‐toluene diisocyanate and tertiary diols performed at the droplet's interface in inverse (water‐in‐oil) miniemulsions. These nanocapsules with an encapsulated photoacid generator can act as a release system, whereby an acidic release through irradiation with ultraviolet light can be triggered. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012 相似文献