Robust regression for mixed Poisson–Gaussian model

This paper focuses on efficient computational approaches to compute approximate solutions of a linear inverse problem that is contaminated with mixed Poisson–Gaussian noise, and when there are additional outliers in the measured data. The Poisson–Gaussian noise leads to a weighted minimization problem, with solution-dependent weights. To address outliers, the standard least squares fit-to-data metric is replaced by the Talwar robust regression function. Convexity, regularization parameter selection schemes, and incorporation of non-negative constraints are investigated. A projected Newton algorithm is used to solve the resulting constrained optimization problem, and a preconditioner is proposed to accelerate conjugate gradient Hessian solves. Numerical experiments on problems from image deblurring illustrate the effectiveness of the methods.     

A polynomial path-following interior point algorithm for general linear complementarity problems

Linear Complementarity Problems (LCPs) belong to the class of \mathbbNP{\mathbb{NP}} -complete problems. Therefore we cannot expect a polynomial time solution method for LCPs without requiring some special property of the coefficient matrix. Our aim is to construct interior point algorithms which, according to the duality theorem in EP (Existentially Polynomial-time) form, in polynomial time either give a solution of the original problem or detects the lack of property P_*([(k)\tilde]){\mathcal{P}_*(\tilde\kappa)} , with arbitrary large, but apriori fixed [(k)\tilde]{\tilde\kappa}). In the latter case, the algorithms give a polynomial size certificate depending on parameter [(k)\tilde]{\tilde{\kappa}} , the initial interior point and the input size of the LCP). We give the general idea of an EP-modification of interior point algorithms and adapt this modification to long-step path-following interior point algorithms.     

Synthesis and application of a fluorous Lawesson's reagent: convenient chromatography-free product purification

[reaction: see text] A fluorous analogue of Lawesson's reagent for thionation of carbonyl compounds has been developed and its use demonstrated on a series of amides, esters, and ketones. The separation of the Lawesson's reagent-derived byproducts can be achieved by a simple fluorous solid-phase extraction.     

On the feasibility to study inverse proximity effect in a single S/F bilayer by Polarized Neutron Reflectometry

Here we report on a feasibility study aiming to explore the potential of Polarized Neutron Reflectometry (PNR) for detecting the inverse proximity effect in a single superconducting/ferromagnetic bilayer. Experiments, conducted on the V (40 nm)/Fe (1 nm) S/F bilayer, have shown that experimental spin asymmetry measured at T = 0.5T _C is shifted towards higher Q values compared to the curve measured at T = 1.5T _C . Such a shift can be described by the appearance in superconducting vanadium of magnetic sublayer with a thickness of 7 nm and a magnetization of +0.8 kG.     

Lower bounds on the minimum distance in Hermitian one-point differential codes

Korchmáros and Nagy [Hermitian codes from higher degree places. J Pure Appl Algebra, doi: 10. 1016/j.jpaa.2013.04.002, 2013] computed the Weierstrass gap sequence G(P) of the Hermitian function field Fq2( H ) at any place P of degree 3, and obtained an explicit formula of the Matthews-Michel lower bound on the minimum distance in the associated differential Hermitian code CΩ(D, mP ) where the divisor D is, as usual, the sum of all but one 1-degree Fq2-rational places of Fq2( H ) and m is a positive integer. For plenty of values of m depending on q, this provided improvements on the designed minimum distance of CΩ(D, mP). Further improvements from G(P) were obtained by Korchmáros and Nagy relying on algebraic geometry. Here slightly weaker improvements are obtained from G(P) with the usual function-field method depending on linear series, Riemann-Roch theorem and Weierstrass semigroups. We also survey the known results on this subject.     

Mixture estimation with state-space components and Markov model of switching

The paper proposes a recursive algorithm for estimation of mixtures with state-space components and a dynamic model of switching. Bayesian methodology is adopted. The main features of the presented approach are: (i) recursiveness that enables a real-time performance of the algorithm; (ii) one-pass elaboration of the data sample; (iii) dynamic nature of the model of switching active components; (iv) orientation at explicit solutions with exploitation of numerical procedures only in those parts which cannot be computed analytically; (v) systematic approach to the Bayesian mixture estimation theory.     

Electron impact ionization of diatomic molecules

Cross sections for the ionization of N₂, CO and O₂ diatomic molecules by electron impact are calculated. The applied distorted wave model is based on our previous studies for positron impact, the molecular orbitals being described by Gaussian wavefunctions. Our study emphasizes the importance of electron exchange and of using correct distorted waves for the ejected electron.     

A Short and Efficient Synthesis of the [3]Triangulene Ring System

Triangulenes are of current interest for potential applications in molecular electronics. We describe here a three step synthesis of the 4,8,12‐trihydro[3]triangulenium cation by cascade cyclization of a tetra‐benzyl alcohol precursor in triflic acid solution. This stable carbocation is easily observed by NMR and optical spectroscopy and is highly fluorescent. Quenching of the cation into basic solutions or by hydride transfer from triethylsilane provides access to stable dihydro and tetrahydro[3]triangulenes. These neutral species interconvert with cations in a complex series of proton and hydride transfers. This route provides several important [3]triangulene precursors. Preliminary experiments designed to generate [3]triangulene in the solution phase provide evidence for its formation and rapid oligomerization.     

Exact Hamiltonian for an analytic correlated ground-state wave function for He-like ions

A correlated three-parameter variational ground-state Ψ(r₁,r₂,r₁₂) proposed by Chandrasekhar for helium-like ions gives a high percentage of the electron correlation energy resulting from the interaction energy e²/r₁₂ and also yields an analytic ground-state electron density ρ(r). Here, we extract via Schrödinger equation an exact Hamiltonian for which the Chandrasekhar wave function is the ground-state. Properties of the potential energy function in this Hamiltonian are quantified. Finally, kinetic energy densities are plotted and related to the Laplacian of ρ(r).