A generalized Jacobian based Newton method for semismooth block-triangular system of equations

This paper will consider the problem of solving the nonlinear system of equations with block-triangular structure. A generalized block Newton method for semismooth sparse system is presented and a locally superlinear convergence is proved. Moreover, locally linear convergence of some parameterized Newton method is shown.     

Conditions for blow-up of solutions of some nonlinear Volterra integral equations

In this paper we give necessary and sufficient conditions for blow-up of solutions for a particular class of nonlinear Volterra equations. We also give some examples.     

Application of the TPR method for the studies of Ni(II) in Chrysoprase

TPR method was used to elucidate the status of nickel ions in chrysoprase. Temperature profiles of chrysoprase samples were interpreted by comparing them with TPR curves of references. Two kinds of nickel species were identified in the studied samples. The first one is nickel in 2:1 layer silicates while the other is nickel in the extra-framework positions. Apparent activation energies (85±3 and 20±5 kJ mol⁻¹) which were obtained from TPR data support the above attribution. This revised version was published online in July 2006 with corrections to the Cover Date.     

Effect of Zn2+ and Cu2+ on free radical properties of melanin fromCladosporium cladosporioides

Effect of metal ions on free radical properties of natural melanin produced by soil fungiCladosporium cladosporioides was studied. The electron paramagnetic resonance (EPR) spectrum of the studied melanin consists mainly of a single line of eumelanin, and only a very weak signal of pheomelanin was observed. o-Semiquinone free radicals form paramagnetic centers in melanin. Diamagnetic Zn²⁺ ions produce an increase in the free radical concentration in melanin. Quenching of melanin EPR lines was obtained for melanin and paramagnetic Cu²⁺ ion complexes. Slow spin-lattice relaxation processes are characteristic for the free radicals in melanin samples and fast spin-lattice relaxation was observed for Cu²⁺ ions. The EPR lines of copper ions saturate at higher microwave powers than the EPR lines of melanin.     

Reinstallation of the COMPASS-D tokamak in IPP ASCR

The COMPASS-D tokamak, originally operated by UKAEA at Culham, UK, will be reinstalled at the Institute of Plasma Physics (IPP) AS CR. The COMPASS device was designed as a flexible tokamak in the 1980s mainly to explore the MHD physics. Its operation (with D-shaped vessel) began at the Culham Laboratory of the Association EURATOM/ UKAEA in 1992.The COMPASS-D tokamak will have the following unique features after putting in operation on IPP Prague. It will be the smallest tokamak with a clear H-mode and ITER-relevant geometry. ITER-relevant plasma conditions will be achieved by installation of two neutral beam injection systems (2 × 300 kW), enabling co-and counter-injections. Redeployment of the existing LH system (400 kW) is also envisaged. A comprehensive set of diagnostics focused mainly on the edge plasma will be installed.The scientific programme proposed for the COMPASS-D tokamak installed in IPP Prague will benefit from these unique features of COMPASS-D and consist of two main scientific projects, both highly relevant to ITER-Edge plasma physics (H-mode studies) and Wave-plasma interaction studies.The COMPASS-D tokamak will offer an important research potential as a small, flexible and low-cost facility with ITER-relevant geometry.     

Time-resolved streak camera system with solid state laser and optical parametric generator in different spectroscopic applications

Apparatus to study time-evolution of emission spectra over very wide time and spectral range is described. Excitation part of the equipment consists of solid state Nd:YAG laser and optical parametric generator. The heart of the detection system consists of spectrograph and streak camera. The significance of optics and electronics built in the system for proper, fast and convenient measurements is underlined. The results of donor-acceptor energy transfer in a rigid polyvinyl alcohol matrix serve here as an example of application our equipment to study complex systems.     

Synthesis of lysine derivatives containing aza-crown ethers and a chromophore unit

The synthesis of a lysine-like chromo-ionophore and its derivatives, useful in peptide chemistry, is described. The influence of the peptide framework on the anthraquinone properties is examined with spectroscopic and electrochemical methods.     

Studies of the out-of-plane emission of pions in symmetric heavy-ion collisions

Triple differential cross-sections of midrapidity pions from ²⁰⁹Bi+²⁰⁹Bi collisions were measured with the Kaon Spectrometer at SIS at incident energies of 400, 700 and 1000 AMeV. The azimuthal emission pattern of the pions has been investigated in dependence of beam energy and impact parameter. An enhanced emission of pions perpendicular to the reaction plane is observed. The strength of the anisotropy increases with beam energy and pion transverse momentum. In contrast to the nucleons the anisotropy varies only little with the impact parameter. No difference in the behaviour of positive and negative pions is observed.     

Low temperature ESR spectra of nickel — doped NaCl crystals

Paramagnetic resonance of Bridgman-grown NaCl crystals nominally doped with divalent nickel was studied over the temperature range from 4 K to 300 K. The broad isotropic EPR line with g = 2.12 ÷ 2.23 and ΔH _pp = 280 ÷ 780 G was detected at temperatures higher than 130 K for samples of various thermal history. The origin of these spectra was attributed to aggregated and precipitated Ni²⁺ ions. At temperatures lower than 40 K another ESR signal was registered. It was an anisotropic one, the intensity of which strongly depends upon the temperature. This spectrum results from substitutional Ni⁺ ions with tetragonally distorted surrounding along a S100T direction. The angular dependence of the ESR line positions was fitted to an appropriate spin-Hamiltonian with the g-factor components g _∥ and g _⊥ equal to 2.86 and 2.10, respectively. The temperature-dependence of the signal intensity at temperatures between 4 and 110 K has been interpreted in terms of a transition from the static to dynamic Jahn-Teller effect.