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排序方式: 共有235条查询结果,搜索用时 31 毫秒
21.
G. N. Nikonov A. S. Balueva A. A. Karasik I. A. Litvinov S. R. Prokhorova O. N. Kataeva 《Heteroatom Chemistry》1994,5(1):43-49
The crystal structure of 5,6-benzo-4-diphenylphosphino-2-phenyl-1,3,2-dioxaborinane 1 indicates the occurrence of an interaction between the π-systems of the 1,3,2-dioxaborinane ring and the appropriate phenyl group of the diphenylphosphino group. Complexes of compound 1 with PtCl2, PdCl2, and Cul were synthesized. Compound 1 and its complexes are readily hydrolyzed in solution to give diphenylphosphine and its corresponding complexes (NMR). 相似文献
22.
I. A. Litvinov O. N. Kataeva L. V. Ermolaeva G. A. Vagina T. V. Troepol'skaya V. A. Naumov 《Russian Chemical Bulletin》1991,40(1):62-67
Aroyl- and acetylhydrazones of acet- (I) and benzaldehydes (IV) and benzoylhydrazones of acet- (II) and benzaldehydes (III) were studied by x-ray structural and quantum-chemical methods in order to establish their structures. Compund (I) was the EEZ structure in the crystal. Calculations and spectral data showed that the EEE form occurs in nonpolar solvents and in the gas phase. According to crystallographic data molecules (I)–(IV) are the E-isomers (relative to the N-N bond) and the hydrazone fragments are planar. Intermolecular N-H...O H-bonds from in the crystals. The data obtained suggest that the majority of acylhydrazones are conformationally rigid on dissolution although exceptions do occur. Apparently the reasons for the difference of acetyl- and benzoylhydrazones in electrocarboxylation reactions are electronic and not steric factors.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 75–81, January, 1991. 相似文献
23.
Yu. V. Bakhtiyarova R. R. Minnullin D. I. Bakhtiyarov M. V. Morozov K. A. Ivshin I. V. Galkina O. N. Kataeva V. I. Galkin 《Russian Journal of General Chemistry》2017,87(12):2789-2793
The new alkylation reactions of a series of mono- and dicarboxylate phosphabetaines with methyl and ethyl iodides in different solvents have been studied. These reactions have afforded stable compounds: iodine-containing salts of phosphonium with different structure. 相似文献
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O. N. Kataeva I. A. Litvinov V. A. Naumov L. K. Yuldasheva B. A. Arbuzov 《Russian Chemical Bulletin》1987,36(12):2548-2551
Conclusions The heterocycle 2,9-dioxo-1,3,8,10-tetraoxa-2,9-dithiacyclotetradeca-5,12-diyne has a conformation of C2 symmetry in the crystal; the acetylene fragments intersect at an angle of 20.8°. The bond lengths and the endocyclic valence angles are close to their standard values.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2750–2753, December, 1987. 相似文献
26.
Semyon R. Romanov Yana V. Dolgova Maxim V. Morozov Kamil A. Ivshin Dmitriy A. Semenov Yulia V. Bakhtiyarova Irina V. Galkina Olga N. Kataeva Vladimir I. Galkin 《Mendeleev Communications》2021,31(2):242-243
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27.
M. A. Zaporozhets D. A. Baranov N. A. Kataeva I. I. Khodos V. I. Nikolaichik A. S. Avilov S. P. Gubin 《Russian Journal of Inorganic Chemistry》2009,54(4):517-520
A simple and available method is proposed for the synthesis of cobalt-containing nanoparticles. This method comprises cobalt formate thermolysis in hydrocarbon oil without extra stabilizing ligands. The size, composition, and structure of the nanoparticles are determined by transmission electron microscopy, X-ray powder diffraction, and electron diffraction. The average particle size is 10–14 nm. The major components are cobalt oxides CoO and Co3O4. Apart from these oxides, the particles contain minor metallic cobalt. 相似文献
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