Nanosecond emission spectra in μm space of Si particles sputtered by laser irradiation

Laser sputtering process from surfaces of Si and other Group IV elements are analyzed by space/time resolved spectroscopy. Our measurements demonstrate the capability of analyzing dynamical characteristics of cluster formation/fragmentation processes inμm and nanosecond resolution.     

Simultaneous determination of stable isotopically labelled L-histidine and urocanic acid in human plasma by stable isotope dilution mass spectrometry.

A capillary gas chromatographic-mass spectrometric method for the simultaneous determination of stable isotopically labelled L-histidine (L-[3,3-2H2,1',3'-15N2]histidine, L-His-[M + 4]) and urocanic acid ([3-2H,1',3'-15N2]urocanic acid, UA-[M + 3]) in human plasma was developed using DL-[2,3,3,5'-2H4,2'-13C,1',3'-15N2]histidine (DL-His-[M + 7]) and [2,3,5'-2H3,2'-13C,1',3'-15N2]urocanic acid (UA-[M + 6]) as internal standards. L-Histidine and urocanic acid were derivatized to alpha N-(trifluoroacetyl)-imN-(ethoxycarbonyl)-L-histidine n-butyl ester and imN-(ethoxycarbonyl)urocanic acid n-butyl ester. Quantification was carried out by selected ion monitoring of the molecular ions of the respective derivatives of L-His-[M + 4], DL-His-[M + 7], UA-[M + 3] and UA-[M + 6]. The sensitivity, specificity, precision and accuracy of the method were demonstrated to be satisfactory for measuring plasma concentrations of L-His-[M + 4] and UA-[M + 3] following administration of trace amounts of L-His-[M + 4] to humans.     

Trace element abundances in stone artifacts and related materials from Japan by neutron activation analysis. An approach to archaeological provenience studies

Instrumental neutron activation analysis was carried out for trace elements in green tuff cylindrical beads (KUDATAMA) and obsidians unearthed from the sites with special reference to their archaeological provenience studies. An approach based on the characteristic index elements, the correlation diagrams of some of the elements interested, and the abundance patterns of some of rare earth elements is valid for clarifying the different source regions.     

Alternative methods of globotrioside production using Vero cells: a microcarrier system procedure

Background  

Glycolipids are one component of cell membranes, and are found most prevalently at the surface of the plasma membrane. Animal cells take in amphipathic glycosides, which are later glycosylated after assimilation in biosynthetic pathways. Gycosylated glycosides are released outside of cells to the surrounding culture medium. This represents an accessible method of obtaining complex glycosides.