全文获取类型
收费全文 | 80篇 |
免费 | 0篇 |
专业分类
化学 | 58篇 |
数学 | 2篇 |
物理学 | 20篇 |
出版年
2022年 | 1篇 |
2021年 | 1篇 |
2018年 | 1篇 |
2017年 | 2篇 |
2015年 | 1篇 |
2013年 | 2篇 |
2012年 | 2篇 |
2011年 | 1篇 |
2010年 | 4篇 |
2009年 | 1篇 |
2008年 | 1篇 |
2007年 | 5篇 |
2006年 | 2篇 |
2005年 | 4篇 |
2004年 | 3篇 |
2003年 | 3篇 |
2002年 | 4篇 |
2001年 | 6篇 |
2000年 | 2篇 |
1996年 | 2篇 |
1995年 | 1篇 |
1988年 | 3篇 |
1987年 | 4篇 |
1986年 | 2篇 |
1985年 | 1篇 |
1983年 | 2篇 |
1982年 | 5篇 |
1981年 | 3篇 |
1980年 | 1篇 |
1979年 | 2篇 |
1978年 | 1篇 |
1976年 | 2篇 |
1970年 | 1篇 |
1968年 | 2篇 |
1967年 | 2篇 |
排序方式: 共有80条查询结果,搜索用时 31 毫秒
61.
Ukrainian Mathematical Journal - We consider a one-dimensional mixed problem for one class of third-order partial differential equations with nonlinear right-hand side. The concept of generalized... 相似文献
62.
O. V. Kononenko V. N. Matveev Yu. A. Kasumov I. I. Khodos D. V. Matveev S. I. Bozhko V. T. Volkov M. A. Knyazev A. A. Firsov A. I. Il’yun 《Bulletin of the Russian Academy of Sciences: Physics》2010,74(7):991-993
Single-wall carbon nanotubes were synthesized on specified parts of oxidized silicon substrates by single acetylene burst
CVD and studied with high-resolution scanning electron and scanning probe micro-scopes. The resistance of individual nanotubes
and nanotube series was measured using devices fabricated by the deposition of Pd and Pd/Al electrodes on the obtained single-wall
nanotubes. The contact potential difference between Pd electrodes and carbon nanotubes was measured in the Kelvin mode of
a scanning probe microscope. 相似文献
63.
Amberlite XAD-4 modified with N-para-anisidine-3,5-di-tert-butylsalicylaldimine was investigated as a new chealting sorbent for the selective separation and preconcentration of Cu(II). The metal ion was retained by chemical sorption on the modified resin, eluted by hydrochloric acid, and determined by high-resolution continuum source flame atomic absorption spectrometry. The prepared resin was characterized for the solid-phase extraction of Cd2+, Co2+, Cr3+, Cu2+, Fe3+, Mn2+, Ni2+, Pb2+, and Zn2+ in a column. The influence of the pH, the mass of solid phase, eluent, flow rate, and sample volume was optimized. Using the optimum conditions, only Cu(II) showed quantitative sorption at the 95% confidence level, and the recoveries of the other metal ions were below 80%. A preconcentration factor 125 was obtained for Cu(II) with a limit of detection of 0.56?µg?L?1. The method was used for the determination of Cu(II) in tap water, river water, tomato leaves, and fish. The relative standard deviation and the relative error were lower than 7%. 相似文献
64.
Kasumov VT 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2001,57(8):1649-1662
New bis[N-(2,6-di-t-butyl-1-hydroxyphenyl)salicylideneminato]copper(II) complexes bearing HO and CH3O substituents on the salicyaldehyde moiety were prepared, and their spectroscopic properties, as well as redox reactivity towards PbO2 and PPh3, examined by ESR and UV spectroscopy. In the process of synthesis of HO complexes unlike CH3O the oxidative C-C coupling of coordinated salicylaldimine ligands does not takes place. The powder ESR spectra of CH3O substituted complexes unlike of HO analogues are typical of a triplet state Cu(II) dimers with a half-field forbidden (deltaM = +/- 2) transition and the allowed transitions (AM = +/- 1) dimeric form of the complexes at 300 and 113 K. The one-electron oxidation of 3-CH3O and all of the OH complexes with PbO2 to give indophenoxyl type secondary radicals which are significantly different from those observed for analogues Cl, Br and NO2 substituted chelates. The presented complexes unlike their electron-withdrawing analogues are readily reduced by PPh3 via intramolecular electron transfer from ligand to copper(II) to give various radical intermediates as well as Cu(I) radical ligand compounds. The analysis of ESR spectra all of the complexes and radical intermediates are presented. 相似文献
65.
Tas E Ucar I Kasumov VT Kilic A Bulut A 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2007,68(3):463-468
Two new sterically hindered salicylaldimines, N-(2,2,6,6-tetramethyl-piperidine-4)-3,5-Bu2t-salicylaldimine (I) and N-(1-carboxyethyl piperidine-4)-3,5-Bu2t-salicylaldimine (II), have been prepared and characterized by IR, UV-vis, 1H NMR, 13C NMR techniques and the structure of II has been examined by X-ray crystallography. No intermolecular H-bonding, pi-pi stacking or C--H...pi interactions are observed in the structure. The crystal structure the was mainly governed by intermolecular steric repulsions, due to bulky tert-butyl groups and the tendency of salicylaldimine rings to pack in parallel mode forms one-dimensional columns. 相似文献
66.
A new N-2,3,4-trifluorophenyl-3,5-di-tert-butylsalicylaldimine (1) complexes with Cu(II) (2) and Pd(II) (3) have been synthesized and characterized by X-ray crystallography, UV-Vis, IR, 1H NMR and EPR spectroscopic techniques. The X-ray crystal structure of complex 2 reveals tetrahedrally distorted square-planar coordination geometry around Cu(II). The UV/Vis and EPR results indicate that the solid state geometry of 2 remains unchanged in solutions. Chemical oxidation of 3 with Ce(IV) in CHCl3 generates relatively stable Pd(II)-phenoxyl radical complex (g = 2.0073). The results related with the chemical oxidation of 2 and 3 as well as the catalytic activity of 3 in the hydrogenation of PhNO2 are presented. 相似文献
67.
Basset J Kasumov AY Moca CP Zaránd G Simon P Bouchiat H Deblock R 《Physical review letters》2012,108(4):046802
The current emission noise of a carbon nanotube quantum dot in the Kondo regime is measured at frequencies ν of the order or higher than the frequency associated with the Kondo effect k(B)T (K)/h, with TK the Kondo temperature. The carbon nanotube is coupled via an on-chip resonant circuit to a quantum noise detector, a superconductor-insulator-superconductor junction. We find for hν ≈ k(B)T(K) a Kondo effect related singularity at a voltage bias eV ≈ hν, and a strong reduction of this singularity for hν ≈ 3k(B)T(K), in good agreement with theory. Our experiment constitutes a new original tool for the investigation of the nonequilibrium dynamics of many-body phenomena in nanoscale devices. 相似文献
68.
69.
70.