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101.
DJ Smith KW Ledingham RP Singhal T McCanny P Graham HS Kilic P Tzallas C Kosmidis AJ Langley PF Taday 《Rapid communications in mass spectrometry : RCM》1999,13(14):1366-1373
With the development of high intensity femtosecond lasers, the ionisation and dissociation dynamics of molecules has become an area of considerable interest. Using the technique of femtosecond laser mass spectrometry (FLMS), the molecules carbon disulphide, pyrimidine, toluene, cyclohexanone and benzaldehyde are studied with pulse widths of 50 fs in the near infrared (IR) wavelength region (790 nm). Results are presented and contrasted for laser beam intensities around 10(15) and 10(16) W cm(-2). For the lower intensities, the mass spectra yield dominant singly charged parent ions. Additionally, the appearance of doubly charged parent ions is evident for carbon disulphide, toluene and benzaldehyde with envelopes of doubly charged satellite species existing in these local regions. Carbon disulphide also reveals a small triply charged component. Such atomic-like features are thought to be a strong fingerprint of FLMS at these intensities. However, upon increasing the laser intensity to approximately 10(16) W cm(-2), parent ion dominance decreases and the appearance of multiply charged atomic species occurs, particularly carbon. This phenomenon has been attributed to Coulomb explosions in which the fast absorption of many photons may produce transient highly ionised parent species which can subsequently blow apart. Copyright 1999 John Wiley & Sons, Ltd. 相似文献
102.
X Fang KW Ledingham P Graham DJ Smith T McCanny RP Singhal AJ Langley PF Taday 《Rapid communications in mass spectrometry : RCM》1999,13(14):1390-1397
The potential of femtosecond laser time-of-flight mass spectrometry (FLMS) for uniform quantitative analysis of molecules has been investigated. Various samples of molecular gases and vapours have been studied, using ultra-fast ( approximately 50 fs) laser pulses with very high intensity (up to 1.6 x 10(16) Wcm(-2)) for non-resonant multiphoton ionisation/tunnel ionisation. Some of these molecules have high ionisation potentials, requiring up to ten photons for non-resonant ionisation. The relative sensitivity factors (RSF) have been determined as a function of the laser intensity and it has been demonstrated that for molecules with very different masses and ionisation potentials, uniform ionisation has been achieved at the highest laser intensities. Quantitative laser mass spectrometry of molecules is therefore a distinct possibility. Copyright 1999 John Wiley & Sons, Ltd. 相似文献
103.
IA Simpson R Bol ID Bull RP Evershed K Petzke SJ Dockrill 《Rapid communications in mass spectrometry : RCM》1999,13(13):1315-1319
Compound specific stable isotope analyses of managed soils using isotope ratio mass spectrometry have been undertaken as a means of determining early land use practices. delta (15)N amino acid signals demonstrate differences between manured grassland, unmanured grassland and continuous cereal cultivation under long-term experimental land use control conditions, with delta (15)N in hydrophobic amino acids providing the most distinctive signals. Analysis of early modern/medieval and of Bronze age anthropogenic soils from Orkney demonstrates that such signals are retained in archaeological contexts. delta (13)C analyses of n- alkanoic acid components of the fossil, Bronze Age, anthropogenic soils suggest a major terrestrial input to these soils, with uniform composition of formation materials. Surficial soils demonstrate the assimilation of isotopically lighter carbon, providing a means of assessing the mobility of the n- alkanoic acids within soils and sediments. Copyright 1999 John Wiley & Sons, Ltd. 相似文献
104.
Shahnaz S. Rohman Chayanika Kashyap Sabnam S. Ullah Dr. Ankur K. Guha Lakhya J. Mazumder Dr. Pankaz. K. Sharma 《Chemphyschem》2019,20(4):516-518
Metal-metal triple bonds featuring s-block element have not been reported until now. Only Be−Be double bonds between have been predicted theoretically based on the intuitive electron donation from four s1 type electron-donating ligands. Herein, we theoretically predicted a novel species featuring a Be−Be triple bond in the Li6Be2 molecule. The molecule was found to be thermodynamically stable. The presence of the triple bond was confirmed by adaptive natural density partitioning (AdNDP), electron localization function (ELF), and atoms in molecules (AIM) analyses. Moreover, the mechanical strength of the Be−Be triple bond was analyzed by using compliance matrix, pointing towards its ultra-weak nature. 相似文献
105.
Lead‐free perovskite structures have been recently attracting considerable attention because of their eco‐friendly nature and properties, such as their lead‐based structure. In this work, we reviewed the lead‐free double perovskite (LFDP) structure because of its unique electronic dimensions, chemical stability, and substitutional chemistry compared with other lead‐free structures. We highlighted the recent progress on crystal structure prediction, synthesis methods, metal dopants, and ligand passivation on LFDPs. LFDPs are useful for several applications, such as solar cells, light‐emitting diodes, degradation of photocatalytic dyes, sensors, and X‐ray detectors. This report provides a summary of recent progress as a reference for further research on lead‐free perovskite structures. 相似文献
106.
Singh Udai P. Kashyap Sujata Butcher Ray J. Singh Hari Ji Mishra Bhupesh Kumar 《Structural chemistry》2011,22(4):931-941
The reactions of phenylphosphonic acid [(OH)2POC6H5] (PPA) with a variety of ditopic pyrazoles PzR1,R2H (where R1 = R2 = H for 1, R1 = R2 = Me for 2, R1 = Ph, R2 = Me for 3 and R1 = R2 = iPr for 4) produce salts 1–4. Due to the presence of different substituents on pyrazole, each salt shows different structure. This study demonstrates
that the presence of different substituents on the pyrazole moieties provides sufficient non-covalent interactions which are
responsible for the different supramolecular structures adopted. Theoretical studies reveal that the proton affinity increases
on the nitrogen having lone pair of electron with the increase of electron density on pyrazole ring but the orientation remains
the same in both the solid and gaseous phase. 相似文献
107.
A variable-wavelength-based approach of phase retrieval for contrast transfer function based methods
Kashyap YS Agrawal A Sarkar PS Shukla M Roy T Sinha A 《Journal of synchrotron radiation》2010,17(6):799-803
X-ray phase-contrast imaging has emerged as an important method for improving contrast and sensitivity in the field of X-ray imaging. This increase in the sensitivity is attributed to the fact that, in the hard X-ray regime, the phase shift is more prominent as compared with the attenuation for materials having a low X-ray absorption coefficient. Among all the methods using the X-ray phase-contrast technique, in-line phase-contrast imaging scores over the other methods in terms of ease of implementation and efficient use of available X-ray flux. In order to retrieve the projected phase map of the object from the recorded intensity pattern, a large number of algorithms have been proposed. These algorithms generally use either the transport of intensity or contrast transfer function based approach for phase retrieval. In this paper it is proposed to use multiple wavelengths for phase retrieval using the contrast transfer function based formalism. 相似文献
108.
Sujeet Chaudhary Kanwal Preet Bhatti S.C. Kashyap 《Journal of magnetism and magnetic materials》2009,321(8):966-970
In the present paper, the preliminary investigations of a series of ZnO thin films co-doped with indium and cobalt with an objective to elucidate the correlation, if any, between the carrier concentration and the induced room temperature ferromagnetism (RTFM), are presented. The single-phasic (Zn99.5In0.5)1−xCoxO thin films are deposited by spray pyrolysis. The substitution of Zn2+ by Co2+ has been established by optical transmission analysis of these films. The films are ferromagnetic at room temperature; and the magnetization has higher value for indium and cobalt co-doped thin film as compared with Zn090Co0.1O thin film (having no indium). 相似文献
109.
We report the wavelength conversion based on double-pass cascaded nonlinear interaction (χ(2):χ(2)) of sum and difference frequency generation in quasi-phase matched lithium niobate waveguides and compare it with double-pass cascaded second harmonic generation and difference frequency generation with and without waveguide loss. It is shown that the efficiency decreases considerably even for the low-loss waveguide compared to the lossless one especially for long waveguides and to achieve the higher efficiency for the same length, the amount of the extra power to compensate the loss increases. Also, an increased detuning of pump wavelength is proposed to flatten the response with a small efficiency penalty. The detuning- and loss-compensating pump powers can be found using the design diagrams in which the criteria for the design of waveguide length and the assignment of pumps power to obtain the desired efficiency, ripple and bandwidth are presented assuming a 75-nm pump wavelength difference. 相似文献
110.
We report on the design and fabrication of complex microcomponents based on multimode optical interference, using a CO2 laser ablation technique. Mode confinement, power division and losses are assessed. Power splitters show a good balance in the intensity division but beam combiners exhibit a variation in output power. The devices are compact and show a low sensitivity to imperfections in the fabrication process. The results demonstrate the technique's potential to develop multiport integrated circuits. 相似文献