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排序方式: 共有217条查询结果,搜索用时 31 毫秒
61.
62.
K Umetsu M Tanaka I Yuasa N Saitou I Takeyasu N Fuku E Naito K Ago N Nakayashiki A Miyoshi S Kashimura G Watanabe M Osawa 《Electrophoresis》2001,22(16):3533-3538
A number of mutations in coding and noncoding regions of mitochondrial DNA (mtDNA) have previously been studied. In the present study, we simultaneously typed six mutation sites in the coding region by use of amplified product-length polymorphism (APLP) analysis. The mtDNA variations of 2471 individuals from 20 populations of Japanese, Korean, Chinese, and German were examined and classified into 18 haplotypes. Two of these haplotypes, B1 (estimated ancestral haplotype) and C1, were distributed among all populations tested. However, the haplotypes A1, A2, B2, B3, and C2 were mostly restricted to the Mongoloid populations, whereas haplotypes B5 and C5 appeared almost exclusively in the German population. Phylogenetic analysis by the neighbor-joining method revealed that the Japanese populations were more closely related to each other than to the other East Asian populations surveyed. The multiplex APLP method is suitable for large-scale screening studies of mtDNA variability because it is both rapid and economical. 相似文献
63.
Kazuhiro Ohashi Shigenori MiharaAkihiro H. Sato Masataka IdeTetsuo Iwasawa 《Tetrahedron letters》2014
A convenient synthesis of 1-haloethenamides has been achieved by utilizing halotrimethylsilane (TMSX, X = Cl, Br, I) and water. Halotrimethylsilane in 1 M CH2Cl2 solution functions as a halogen source of the in situ generated HX, and the HX added to the terminal triple bonds of ynamides in Markovnikov fashion. 相似文献
64.
Akio Yoshioka Kazutomo Takematsu Ikuo Kurisaki Kaori Fukuzawa Yuji Mochizuki Tatsuya Nakano Eri Nobusawa Katsuhisa Nakajima Shigenori Tanaka 《Theoretical chemistry accounts》2011,130(4-6):1197-1202
Effective interactions between amino acid residues in antigen?Cantibody complex of influenza virus hemagglutinin (HA) protein can be evaluated in terms of the inter-fragment interaction energy (IFIE) analysis with the fragment molecular orbital (FMO) method, in which each fragment contains the side chain of corresponding amino acid residue. We have carried out the FMO-MP2 (second-order Moeller?CPlesset) calculation for the complex of HA antigen and Fab antibody of influenza virus H3N2 A/Aichi/2/68 and obtained the IFIE values between each amino acid residue in HA and the whole antibody as the sums over the residues contained in the latter. Combining this IFIE data with experimental data for hemadsorption activity of HA mutants, we succeeded in theoretically explaining the mutations in HA observed after the emergence of influenza virus H3N2 A/Aichi/2/68 in an earlier study, except for those of THR83. In the present study, we employ an alternative way of fragment division in the FMO calculation at the carbonyl C site of the peptide bond instead of the C?? site used in the previous work, which provides revised IFIE values consistent with all the historical mutation data in the antigenic region E of HA including the case of THR83 in the present prediction scheme for probable mutations in HA. 相似文献
65.
Improved calculation of band gap of Sr2Bi2O5 crystal using modified Becke–Johnson exchange potential
Yuki Obukuro Shigenori Matsushima Kenji Obata Masao Arai Kenkichiro Kobayashi 《Journal of Physics and Chemistry of Solids》2014
The electronic structure of Sr2Bi2O5 is calculated by the scalar-relativistic full potential linearized augmented plane wave (FLAPW+lo) method using the modified Becke–Johnson potential combined with the local density approximation correlation (MBJ–LDA). Both the valence band maximum (VBM) and conduction band minimum (CBM) exist at the Γ-point, indicating that Sr2Bi2O5 is a direct-band-gap material. The band gap is calculated to be 3.17 eV, which is very close to the experimental value. This result is in great contrast to the underestimation based on the GGA calculation. On the other hand, there is only a small difference in the effective masses of holes and electrons photogenerated near the VBM and CBM for the MBJ–LDA and GGA approaches. The optical properties of Sr2Bi2O5 are calculated from the complex dielectric function ε(ω)=ε1(ω)+iε2(ω). A highly polarized peak is observed at 3.5 eV in the ε2(ω) function. Furthermore, the absorption coefficient estimated from the MBJ–LDA is very similar to that from the experimental result. 相似文献
66.
Shuhei Fujimura Yasuhisa Yamamura Mafumi Hishida Shigenori Nagatomo 《Liquid crystals》2013,40(7):927-932
The appearance of reentrant nematic phase was identified in nCB/8CB (n = 1–6) binary mixtures using differential scanning calorimetry, small-angle X-ray diffraction and polarising microscopy with photomonitor. Phase diagrams can roughly be unified if plotted against the average number of alkyl chain length. Distinction was recognised for the phase boundaries between nematic and smectic A phases of even and odd n of the minor component nCB. The character of 8CB as ‘SmA former’ is briefly discussed. 相似文献
67.
Mamoru Koketsu Akira Seko Lekh Raj Juneja Mujo Kim Naoki Kashimura Takchiko Yamamoto 《Journal of carbohydrate chemistry》2013,32(6):833-841
Abstract Delipidated egg yolk (DEY) was digested with protease. The digest was ultrafiltered using a molecular weight cut-off of 10,000, and the UF permeate was treated with a reverse osmosis membrane. The resulting sialylglycopeptides-rich fraction was purified by the combination of anion exchange and gel filtration chromatography. Two major sialylglycopeptides, A-I and A-II, were characterized as biantennary complex type sialylglycopeptides having one or two N-acetylneuraminic acid and 1 - 3.5 amino acids including one asparagine residue by composition analyses and 1H NMR spectroscopy. 相似文献
68.
Amplitude modulation of laser light is required for resonant sideband extraction employed in gravitational-wave detectors. Amplitude modulation with electro-optic phase modulators is realized by interferometric phase-to-amplitude conversion. Although two outputs modulated at opposite phases to each other are obtained, usually only one of them is utilized and the other is abandoned. The reuse of this abandoned light improves the power efficiency of the modulation. This can be realized by inverting the modulation phase of one output with a delay line and adding it to the other coherently. Moreover, this system selects a high-efficiency operating point and modulates the light in a linear range. We demonstrate that the modulation system can be operated with a power loss that is due only to the losses of the optical components. 相似文献
69.
Akimitsu Ishihara Satoshi Tominaka Shigenori Mitsushima Hideto Imai Osamu Sugino Ken-ichiro Ota 《Current Opinion in Electrochemistry》2020
To obtain an ideal electrocatalysts for hydrogen fuel cells, we investigated group 4 and 5 oxide-based compounds because of their high degree of freedom. First-principles calculations revealed that oxide surfaces such as those of titanium oxide could break down the universal scaling to achieve the ideal state of the oxygen reduction reaction. We experimentally clarified that the active sites were oxygen vacancies for tantalum and zirconium oxides, in addition to doped foreign elements and crystalline structures for titanium oxide. We successfully demonstrated that precious metal-free and carbon-free oxide-based cathodes have high quality active sites and superior durability in 0.1 M sulfuric acid at 80°C. Our strategy was developed as follows: (1) Active sites are created on the oxide surface by modifying the crystalline structure and electronic states and (2) electrons participating in the oxygen reduction reaction are supplied by nanosized oxide particles and oxide films through the tunneling effect of electrons. 相似文献
70.
A Palladium‐Nanoparticle and Silicon‐Nanowire‐Array Hybrid: A Platform for Catalytic Heterogeneous Reactions
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Dr. Yoichi M. A. Yamada Yoshinari Yuyama Dr. Takuma Sato Dr. Shigenori Fujikawa Dr. Yasuhiro Uozumi 《Angewandte Chemie (International ed. in English)》2014,53(1):127-131
We report the development of a silicon nanowire array‐stabilized palladium nanoparticle catalyst, SiNA‐Pd. Its use in the palladium‐catalyzed Mizoroki‐Heck reaction, the hydrogenation of an alkene, the hydrogenolysis of nitrobenzene, the hydrosilylation of an α,β‐unsaturated ketone, and the C‐H bond functionalization reactions of thiophenes and indoles achieved a quantitative production with high reusability. The catalytic activity reached several hundred‐mol ppb of palladium, reaching a TON of 2 000 000. 相似文献