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31.
B. K. Kasenov Zh. I. Sagintaeva Sh. B. Kasenova A. Zh. Abil’daeva S. Zh. Davrenbekov Zh. S. Bekturganov 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2013,87(6):1057-1059
The standard enthalpies of formation of LnMIIMnFeO5.5 manganitoferrites (Ln is a rare-earth element, and MII is an alkali-earth metal) were estimated by the developed method of calculation. Their standard entropies were calculated by the method of ionic increments, and their standard Gibbs energies of formation were determined by the Gibbs-Helmholtz equation. 相似文献
32.
Kasenova S. B. Sagintaeva Zh. I. Tukhmetova Zh. K. Kasenov B. K. Nurmaganbetov Zh. S. Adekenov S. M. 《Russian Journal of Applied Chemistry》2011,84(8):1454-1455
Temperature dependences of the heat capacity of the alkaloid harmine derivatives 9-methoxy-2-phenyl-11H-indolysine[8,7-b]indole (C21H16N2O) and N-(2)-phenacylharminium bromide C21H19N2O2Br wer studied by the experimental calorimetry method. 相似文献
33.
A. Zh. Abil’daeva Zh. K. Tukhmetova Sh. B. Kasenova S. M. Adekenov B. K. Kasenov T. V. Kharlamova B. Zh. Dzhiembaev 《Russian Journal of Applied Chemistry》2008,81(1):30-32
The enthalpies of solution of a series of anthraquinone derivatives in dioxane at various dilutions were determined by isothermal calorimetry. 相似文献
34.
Sh. B. Kasenova B. K. Kasenov Zh. I. Sagintaeva E. E. Kuanyshbekov B. T. Ermagambet A. A. Seisenova D. I. Smagulova 《Russian Journal of Inorganic Chemistry》2014,59(9):1010-1014
Cuprate manganites of the composition LaM 2 II CuMnO6 (MII = Mg, Ca, Sr, Ba) were synthesized from lanthanum, copper(II), and manganese(III) oxides and alkaline-earth metal carbonates by high-temperature solid-phase synthesis. By grinding the produced substances in a ball mill, their nanostructured particles were obtained, the sizes of which were determined with an electron microscope. Indexing the X-ray powder diffraction patterns of the cuprate manganites established that all of them crystallize in the cubic system with the following unit cell parameters: LaMg2CuMnO6: a = 15.523 ± 0.033 Å, Z = 6, V 0 = 3740.48 ± 0.10 Å3, V el.cell 0 = 623.41 ± 0.03Å3, ρX-ray = 5.81 g/cm3, and ρpycn = 5.75 ± 0.06 g/cm3; LaCa2CuMnO6: a = 15.422 ± 0.058 Å, Z = 4, V 0 = 3667.94 ± 0.174 Å3, V el.cell 0 = 916.48 ± 0.04 Å3, ρX-ray = 3.77 g/cm3, and ρpycn = 3.72 ± 0.05 g/cm3; LaSr2CuMnO6: a = 15.275 ± 0.049 Å, Z = 4, V 0 = 3564.05 ± 0.27 Å3, V el.cell 0 = 891.01 ± 0.07 Å3, ρX-ray = 4.31 g/cm3, and ρpycn = 4.25 ± 0.05 g/cm3; and LaBa2CuMnO6: a = 15.589 ± 0.029 Å, Z = 4, V 0 = 3788.39 ± 0.09 Å3, V el.cell 0 = 947.10 ± 0.02 Å3, ρX-ray = 4.74 g/cm3, and ρpycn = 4.70 ± 0.05 g/cm3. The data of an IR spectroscopic study of the cuprate manganites were presented. 相似文献
35.
B. K. Kasenov S. T. Edil’baeva E. S. Mustafin S. M. Sergazina Sh. B. Kasenova S. Zh. Davrenbekov 《Russian Journal of Inorganic Chemistry》2007,52(8):1180-1183
New ferrites ErMFe2O5 (M = Li, Na, K) were synthesized from erbium and iron(III) oxides and lithium, sodium, and potassium carbonates by solid-state annealing. According to X-ray powder diffraction, these compounds crystallize in the orthorhombic system with the following unit cell parameters: ErLiFe2O5, a = 10.510 Å, b = 10.776 Å, c = 14.270 Å, V 0 = 1616.16 Å3; Z = 16, V subcell 0 = 101.01 Å3, ρX = 6.01 g/cm3, ρpycn = 5.97 ± 0.05 g/cm3; ErNaFe2O5, a = 10.519 Å, b = 10.785 Å, c = 15.510 Å, V 0 = 1759.56 Å3, Z = 16, V subcell 0 = 109.90 Å3, ρX = 5.77 g/cm3, ρpycn = 5.72 ± 0.08 g/cm3; ErKFe2O5, a = 10.050 Å, b = 11.320 Å, c = 15.480 Å, V 0 = 1937.33 Å3, Z = 16, V subcell 0 = 121.08 Å3, ρX = 5.46 g/cm3, ρpycn = 5.41 ± 0.04 g/cm3. 相似文献
36.
Kaskenov B. K. Tukhmetova Zh. K. Adekenov S. M. Kasenova Sh. B. Mustafin E. S. Kagarlitskii A. D. Turmukhambetov A. Zh. 《Russian Journal of Applied Chemistry》2003,76(1):29-32
The heats of solution of anabasine hydrochloride C10H14N2HCl and of the reaction of its aqueous solution with crystalline AgNO3 at various dilutions were determined. The standard enthalpies of formation of anabasine hydrochloride and its 36 analogs were calculated. The temperature dependence of the anabasine hydrochloride heat capacity was studied within the 173-448 K range. 相似文献
37.
Sh. B. Kasenova Zh. K. Tukhmetova A. Zh. Abil’daeva I. M. Oskembekov S. M. Adekenov B. K. Kasenov S. D. Fazylov A. M. Gazaliev 《Russian Journal of Applied Chemistry》2008,81(2):272-275
The enthalpies of solution of imidazolidine-2-thione and potassium isopropylxanthate in ethanol and their isobaric heat capacity in the range from 173 to (T m ? 100) K were measured by calorimetry at 298.15 K. The standard enthalpies of formation, combustion, and melting of these compounds were estimated. 相似文献
38.
B. K. Kasenov E. S. Mustafin M. A. Akubaeva Zh. I. Sagintaeva S. T. Edil’baeva Sh. B. Kasenova S. Zh. Davrenbekov 《Russian Journal of Inorganic Chemistry》2008,53(11):1691-1693
Ternary chromites of the composition LaMIMg(CrO3)2 (MI = Li, Na, K) were synthesized for the first time by ceramic technology from stoichiometric amounts of high purity grade La2O3; pure for analysis grade Li2CO3, Na2CO3, K2CO3, and MgCO3; and chemically pure grade Cr2O3. Using X-ray diffractometry, it has been established that compounds are crystallized in cubic and tetragonal crystal systems, and parameters of their crystal lattices have been determined. 相似文献
39.
B. K. Kasenov Sh. B. Kasenova Zh. I. Sagintaeva A. A. Seisenova M. O. Turtubaeva E. E. Kuanyshbekov K. T. Ermaganbetov 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2016,90(4):739-743
Temperature dependences of the heat capacity of new zincate-manganites of LaM2IIZnMnO6 (MII = Mg, Ca, Sr, Ba) composition are studied via experimental calorimetry in the interval of 298.15–673 K. It is found that all compounds have λ-shape effects on the curve of dependence Cp° ~ ?(T) with respect to phase transitions of the second kind. Equations for the temperature dependence of the heat capacity are derived with allowance for phase transition temperatures, and thermodynamic functions H°(T) ? H°(298.15), S°(T) and Φxx(T) are calculated on the basis of experimental data on Cp°(T) and the calculated S°(298.15) value. 相似文献
40.
B. K. Kasenov E. S. Mustafin M. A. Akubaeva S. T. Edil’baeva Sh. B. Kasenova Zh. I. Sagintaeva S. Zh. Davrenbekov 《Russian Journal of Inorganic Chemistry》2010,55(9):1454-1457
Manganites DyM3IMg3Mn4O12 and DyM3IBa3Mn4O12 (MI = Li, Na, K) were synthesized by the solid-state reaction of dysprosium and manganese(III) oxides and magnesium and corresponding alkali metal carbonates. The X-ray powder diffraction studies showed that the crystals
are orthozhombic with the following unit cell parameters and densities: DyLi3Mg3Mn4O12—a = 10.88 ?, b = 10.73 ?, c = 19.63 ?, V
0 = 1656.2 ?3, Z = 8, ρcalc = 5.36 g/cm3, ρpycn = 5.11 ± 0.05 g/cm3; DyNaMg3Mn4O12—a = 10.55 ?, b = 10.72 ?, c = 18.28 ?, V
0 = 2067.4 ?3, Z = 8, ρcalc = 4.60 g/cm3, ρpycn = 4.88 ± 0.09 g/cm3; DyK3Mg3Mn4O12—a = 10.56 ?, b = 10.72 ?, c = 20.89 ?, V
0 = 2206.0 ?3, Z = 8, ρcalc = 4.60 g/cm3, ρpycn = 4.92 ± 0.06 g/cm3; DyLi3Ba3Mn4O12—a = 10.53 ?, b = 10.69 ?, c = 21.28 ?, V
0 = 2395.4 ?3, Z = 8, ρcalc = 5.58 g/cm3, ρpycn = 5.98 ± 0.12 g/cm3; DyNa3Ba3Mn4O12—a = 10.53 ?, b = 10.74 ?, c = 23.00 ?, V
0 = 2602.3 ?3, Z = 8, ρcalc = 5.39 g/cm3, ρpycn = 5.30 ± 0.07 g/cm3; DyK3Ba3Mn4O12—a = 10.52 ?, b = 10.75 ?, c = 25.69 ?, V
0 = 2905.2 ?3, Z = 8, ρcalc = 5.04 g/cm3, ρpycn = 5.00 ± 0.18 g/cm3. 相似文献