14C labelling as a reliable technique to screen soybean genotypes (Glycine max (L.) Merr.) for iron deficiency tolerance

Journal of Radioanalytical and Nuclear Chemistry - Fifty diverse soybean genotypes were screened for their ability to tolerate iron deficiency stress in a hydroponics experiment with low iron...     

Detailed study on reduction of hazardous Cr(VI) at acidic pH using modified montmorillonite Fe(II)-Mt under ambient conditions

Research on Chemical Intermediates - Contamination of groundwater and soil by high levels of hexavalent chromium directly affects the environment and human health as a serious pollutant....     

Horizonless,singularity-free,compact shells satisfying NEC

Gravitational collapse singularities are undesirable, yet inevitable to a large extent in General Relativity. When matter satisfying null energy condition (NEC) collapses to the extent a closed trapped surface is formed, a singularity is inevitable according to Penrose’s singularity theorem. Since positive mass vacuum solutions are generally black holes with trapped surfaces inside the event horizon, matter cannot collapse to an arbitrarily small size without generating a singularity. However, in modified theories of gravity where positive mass vacuum solutions are naked singularities with no trapped surfaces, it is reasonable to expect that matter can collapse to an arbitrarily small size without generating a singularity. Here we examine this possibility in the context of a modified theory of gravity with torsion in an extra dimension. We study singularity-free static shell solutions to evaluate the validity of NEC on the shell. We find that with sufficiently high pressure, matter can be collapsed to arbitrarily small size without violating NEC and without producing a singularity.     

Microwave‐Assisted Synthesis of Novel Spiro Phosphonyl Thiazolo Pyrazole Glycosides as Potential Nematicidal Agents

A series of novel dimethyl 7‐((3aR,5S,6S,6aR)‐6‐((1‐(4‐chlorophenyl)‐1H‐1,2,3‐triazol‐4‐yl)methoxy)‐2,2‐dimethyltetrahydrofuro[2,3‐d][1,3]dioxol‐5‐yl)‐4‐(4‐fluorophenyl)‐9‐oxo‐8‐phenyl‐6‐thia‐1,2,8‐triazaspiro[4.4]non‐2‐en‐3‐ylphosphonate 2a – g were synthesized by the reaction of chalcone derivatives of 2‐((3aR,5S,6S,6aR)‐6‐((1‐(4‐chlorophenyl)‐1H‐1,2,3‐triazol‐4‐yl)methoxy)‐2,2‐dimethyltetrahydrofuro[2,3‐d][1,3]dioxol‐5‐yl)‐3‐phenylthiazolidin‐4‐one 1 with Bestmann–Ohira reagent. The chemical structures of newly synthesized compounds were elucidated by IR, NMR, MS, and elemental analysis. The compounds 2a – g were evaluated for their nematicidal activity against Dietylenchus myceliophagus and Caenorhabditis elegans; compounds 2b , 2c , 2g , and 2f showed appreciable nematicidal activity.     

Sodalite‐type Cu‐based Three‐dimensional Metal–Organic Framework for Efficient Oxygen Reduction Reaction

Inspired by copper‐based oxygen reduction biocatalysts, we have studied the electrocatalytic behavior of a Cu‐based MOF (Cu‐BTT) for oxygen reduction reaction (ORR) in alkaline medium. This catalyst reduces the oxygen at the onset (E_onset) and half‐wave potential (E^1/2) of 0. 940 V and 0.778 V, respectively. The high halfway potential supports the good activity of Cu‐BTT MOF. The high ORR catalytic activity can be interpreted by the presence of nitrogen‐rich ligand (tetrazole) and the generation of nascent copper(I) during the reaction. In addition to the excellent activity, Cu‐BTT MOF showed exceptional stability too, which was confirmed through chronoamperometry study, where current was unchanged up to 12 h. Further, the 4‐electrons transfer of ORR kinetics was confirmed by hydrodynamic voltammetry. The oxygen active center namely copper(I) generation during ORR has been understood by the reduction peak in cyclic voltammetry as well in the XPS analysis.     

Electrochemical Activation of Graphite Nanosheets Decorated with Palladium Nanoparticles for High Performance Amperometric Hydrazine Sensor

Herein, we have demonstrated a preparation of palladium nanoparticles on electroactivated graphite nanosheets modified screen printed carbon electrode (PdNPs‐EGNS/SPCE) by a simple electrochemical method. The well‐prepared electrocatalyst was potentially applied to the high performance electrocatalytic oxidation of hydrazine in neutral medium. The PdNPs‐EGNS novel composite was characterized by scanning electron microscope (SEM) and the average diameter and thickness of PdNPs and EGNS were found to be ～38 nm and 85 nm, respectively. The high performance electrocatalytic determination of hydrazine was performed by the amperometric i‐t method. The fabricated sensor displayed irreversible electrocatalytic oxidation of hydrazine with diffusion‐controlled electrode process. The oxidation of hydrazine at PdNPs‐EGNS/SPCE showed wider linear range 0.05–1415 µM and high sensitivity 4.382 µA µM^?1 cm^?2. The as‐prepared electrocatalyst achieved quick response towards hydrazine with a lower detection limit 4 nM.     

Quasilinear equations with natural growth in the gradients in spaces of Sobolev multipliers

We study the existence problem for a class of nonlinear elliptic equations whose prototype is of the form \(-\Delta _p u = |\nabla u|^p + \sigma \) in a bounded domain \(\Omega \subset \mathbb {R}^n\). Here \(\Delta _p\), \(p>1\), is the standard p-Laplacian operator defined by \(\Delta _p u=\mathrm{div}\, (|\nabla u|^{p-2}\nabla u)\), and the datum \(\sigma \) is a signed distribution in \(\Omega \). The class of solutions that we are interested in consists of functions \(u\in W^{1,p}_0(\Omega )\) such that \(|\nabla u|\in M(W^{1,p}(\Omega )\rightarrow L^p(\Omega ))\), a space pointwise Sobolev multipliers consisting of functions \(f\in L^{p}(\Omega )\) such that

$$\begin{aligned} \int _{\Omega } |f|^{p} |\varphi |^p dx \le C \int _{\Omega } (|\nabla \varphi |^p + |\varphi |^p) dx \quad \forall \varphi \in C^\infty (\Omega ), \end{aligned}$$

for some \(C>0\). This is a natural class of solutions at least when the distribution \(\sigma \) is nonnegative and compactly supported in \(\Omega \). We show essentially that, with only a gap in the smallness constants, the above equation has a solution in this class if and only if one can write \(\sigma =\mathrm{div}\, F\) for a vector field F such that \(|F|^{\frac{1}{p-1}}\in M(W^{1,p}(\Omega )\rightarrow L^p(\Omega ))\). As an important application, via the exponential transformation \(u\mapsto v=e^{\frac{u}{p-1}}\), we obtain an existence result for the quasilinear equation of Schrödinger type \(-\Delta _p v = \sigma \, v^{p-1}\), \(v\ge 0\) in \(\Omega \), and \(v=1\) on \(\partial \Omega \), which is interesting in its own right.

     

Recognition of mandelate stereoisomers by chiral porphyrin hosts: prediction of stereopreference in guest binding a priori using a simple binding model?

Rigid porphyrin hosts that mimic the spatial arrangement of mandelate recognition motifs lead to stereoselective receptors and illustrate how subtle structural differences in host design have significant impact on guest recognition. The porphyrin hosts are obtained with minimal synthetic effort from readily available chiral amine precursors and are modular in design. The chiral recognition properties of the porphyrin-based hosts with chiral carboxylate-containing guests and chiral amines are described. UV/vis and ¹H NMR spectroscopic results indicate some of these porphyrin hosts undergo an induced fit conformational change upon guest binding.