全文获取类型
收费全文 | 105篇 |
免费 | 2篇 |
专业分类
化学 | 64篇 |
晶体学 | 6篇 |
力学 | 2篇 |
数学 | 15篇 |
物理学 | 20篇 |
出版年
2023年 | 1篇 |
2021年 | 1篇 |
2020年 | 3篇 |
2019年 | 8篇 |
2014年 | 2篇 |
2013年 | 12篇 |
2012年 | 3篇 |
2011年 | 4篇 |
2010年 | 3篇 |
2009年 | 1篇 |
2008年 | 4篇 |
2006年 | 2篇 |
2005年 | 1篇 |
2004年 | 4篇 |
2003年 | 1篇 |
2002年 | 8篇 |
2001年 | 1篇 |
1999年 | 1篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1991年 | 1篇 |
1986年 | 2篇 |
1985年 | 4篇 |
1984年 | 5篇 |
1983年 | 3篇 |
1982年 | 2篇 |
1981年 | 3篇 |
1980年 | 1篇 |
1977年 | 2篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1973年 | 5篇 |
1967年 | 3篇 |
1963年 | 1篇 |
1955年 | 1篇 |
1948年 | 1篇 |
1946年 | 1篇 |
1945年 | 2篇 |
1944年 | 1篇 |
1943年 | 4篇 |
排序方式: 共有107条查询结果,搜索用时 0 毫秒
101.
Dr. Kalathil K. Kartha Felix Wendler Dr. Tobias Rudolph Philip Biehl Prof. Dr. Gustavo Fernández Prof. Dr. F. H. Schacher 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(3):606-610
pH-Tunable nanoscale morphology and self-assembly mechanism of a series of oligo(p-phenyleneethynylene) (OPE)-based bolaamphiphiles featuring poly(ethylene imine) (PEI) side chains of different length and degree of hydrolysis are described. Protonation and deprotonation of the PEI chains by changing the pH alters the hydrophilic/hydrophobic balance of the systems and, in turn, the strength of intermolecular interactions between the hydrophobic OPE moieties. Low pH values (3) lead to weak interaction between the OPEs and result in spherical nanoparticles, in which aggregation follows an isodesmic mechanism. In contrast, higher pH values (11) induce deprotonation of the polymer chains and lead to a stronger, cooperative aggregation into anisotropic nanostructures. Our results demonstrate that pH-responsive chains can be exploited as a tool to tune self-assembly mechanisms, which opens exciting possibilities to develop new stimuli-responsive materials. 相似文献
102.
Shashwati Sen DK Aswal Ajay Singh TV Chandrasekhar Rao KP Muthe JC Vyas LC Gupta SK Gupta VC Sahni 《Pramana》2002,58(5-6):867-870
The MgB2 superconductor, synthesized using solid-state and liquid-phase sintering methods, have been characterized for various properties.
The upper critical field, irreversibility line and critical current density have been determined using magnetization data.
The current-voltage characteristics recorded under an applied magnetic field revealed the existence of vortex glass transition.
The surface analysis using X-ray photoelectron spectroscopy shows that MgB2 is sensitive to atmospheric degradation. 相似文献
103.
Manjunath BK Kurein J Rao L Krishna CM Chidananda MS Venkatakrishna K Kartha VB 《Journal of photochemistry and photobiology. B, Biology》2004,73(1-2):49-58
Pulsed laser-induced-fluorescence studies of pathologically certified oral tissues are carried out at different excitations and time delays. Among the several excitations used, 325 nm produced noticeably different spectral profile for normal and malignant tissues. Extensive curve analysis was carried out in order to understand changes in biochemical composition of tissue based on spectral profiles. Curve resolution and principal component analysis (PCA) show that the fluorescence intensity changes from normal to malignant tissue samples are not completely explained in terms of simple collagen and NAD(P)H intensity changes. The spectra require at least five components to be fully accounted for. Several discrimination methodologies based on PCA and intensity differences between different emission peaks (resultant peaks of curve analysis) were also evaluated. The results obtained indicate PCA using Mahalanobis distance and spectral residual as discrimination parameters provides best discrimination and can be used for matching unknown samples to standard calibration sets. Intensity ratio of bound NAD(P)H to collagen seems to be more suitable for discrimination between normal and malignant oral tissue, compared to ratio of collagen to total intensity of all the other components together. 相似文献
104.
105.
106.
107.