全文获取类型
收费全文 | 1184篇 |
免费 | 47篇 |
国内免费 | 4篇 |
专业分类
化学 | 775篇 |
晶体学 | 2篇 |
力学 | 50篇 |
数学 | 168篇 |
物理学 | 240篇 |
出版年
2022年 | 8篇 |
2021年 | 10篇 |
2020年 | 19篇 |
2019年 | 17篇 |
2018年 | 13篇 |
2017年 | 17篇 |
2016年 | 29篇 |
2015年 | 28篇 |
2014年 | 32篇 |
2013年 | 53篇 |
2012年 | 83篇 |
2011年 | 96篇 |
2010年 | 45篇 |
2009年 | 37篇 |
2008年 | 79篇 |
2007年 | 66篇 |
2006年 | 50篇 |
2005年 | 51篇 |
2004年 | 51篇 |
2003年 | 45篇 |
2002年 | 38篇 |
2001年 | 20篇 |
2000年 | 18篇 |
1999年 | 15篇 |
1998年 | 21篇 |
1997年 | 16篇 |
1996年 | 18篇 |
1995年 | 27篇 |
1994年 | 16篇 |
1993年 | 18篇 |
1992年 | 13篇 |
1991年 | 14篇 |
1990年 | 17篇 |
1989年 | 17篇 |
1988年 | 9篇 |
1987年 | 7篇 |
1986年 | 5篇 |
1985年 | 4篇 |
1984年 | 10篇 |
1983年 | 5篇 |
1982年 | 8篇 |
1981年 | 6篇 |
1980年 | 4篇 |
1979年 | 8篇 |
1978年 | 7篇 |
1977年 | 10篇 |
1976年 | 9篇 |
1975年 | 10篇 |
1974年 | 8篇 |
1973年 | 7篇 |
排序方式: 共有1235条查询结果,搜索用时 15 毫秒
101.
102.
103.
Polymeric melaminium sulfate [(LH2)2(SO4)2]n has been synthesized by reaction of melamine L with sulfuric acid in aqueous solution. The compound was characterized by elemental analysis, 1H NMR, ESI MS and a single crystal X‐ray diffraction analysis. The architecture of the assembly formed is based on hydrogen bonded dimers of diprotonated melaminium cations (LH2)2+ which are linked by a hydrogen bonded network with sulfate ions forming 2D sheets. A 3D polymeric structure results from the presence of mutual hydrogen bonds between sulfate ions and melaminium cations in different sheets. Significant π‐π stacking is also present between the aromatic cations in this supramolecular arrangement. 相似文献
104.
105.
106.
107.
Amy F. Mielke Richard G. Seasholtz Kristie A. Elam Jayanta Panda 《Experiments in fluids》2005,39(2):441-454
Measurement of time-averaged velocity, density, temperature, and turbulence velocity fluctuations in sparsely seeded gas flows using a non-intrusive, point-wise technique based on Rayleigh and Mie scattering is discussed. A Fabry-Perot interferometer (FPI) is used to spectrally resolve laser light scattered by molecules and particulates in gas flows. The spectral content of the scattered light provides information about velocity, density, and temperature of the gas. A CCD camera is used to record images of the fringes formed by scattered light passing through the interferometer. Models of the spectral components are used in a least squares fitting routine to estimate the parameters from fringe images. Flow measurements are presented for subsonic and supersonic jet flows. The application range for this technique is mostly for high velocity situations (>25 m/s). Velocity, density, temperature, and turbulence velocity fluctuations were determined with accuracies within 5 m/s, 4%, 2%, and 5 m/s, respectively. 相似文献
108.
109.
David Siegel Karsten Andrae Matthias Proske Cindy Kochan Matthias Koch Marcus Weber Irene Nehls 《Journal of chromatography. A》2010,1217(15):2206-2215
A novel, cost-efficient method for the analytical extraction of the Fusarium mycotoxin zearalenone (ZON) from edible oils by dynamic covalent hydrazine chemistry (DCHC) was developed and validated for its application with high performance liquid chromatography-fluorescence detection (HPLC-FLD). ZON is extracted from the edible oil by hydrazone formation on a polymer resin functionalised with hydrazine groups and subsequently released by hydrolysis. Specifity and precision of this approach are superior to liquid partitioning or gel permeation chromatography (GPC). DCHC also extracts zearalanone (ZAN) but not α-/β-zearalenol or -zearalanol. The hydrodynamic properties of ZON, which were estimated using molecular simulation data, indicate that the compound is unaffected by nanofiltration through the resin pores and thus selectively extracted. The method's levels of detection and quantification are 10 and 30 μg/kg, using 0.2 g of sample. Linearity is given in the range of 10–20,000 μg/kg, the average recovery being 89%. Bias and relative standard deviations do not exceed 7%. In a sample survey of 44 commercial edible oils based on various agricultural commodities (maize, olives, nuts, seeds, etc.) ZON was detected in four maize oil samples, the average content in the positive samples being 99 μg/kg. The HPLC-FLD results were confirmed by HPLC–tandem mass spectrometry and compared to those obtained by a liquid partitioning based sample preparation procedure. 相似文献
110.
Sebastian Gatz Helge Hannebauer Rene Hesse Florian Werner Arne Schmidt Thorsten Dullweber Jan Schmidt Karsten Bothe Rolf Brendel 《固体物理学:研究快报》2011,5(4):147-149
We demonstrate industrially feasible large‐area solar cells with passivated homogeneous emitter and rear achieving energy conversion efficiencies of up to 19.4% on 125 × 125 mm2 p‐type 2–3 Ω cm boron‐doped Czochralski silicon wafers. Front and rear metal contacts are fabricated by screen‐printing of silver and aluminum paste and firing in a conventional belt furnace. We implement two different dielectric rear surface passivation stacks: (i) a thermally grown silicon dioxide/silicon nitride stack and (ii) an atomic‐layer‐deposited aluminum oxide/silicon nitride stack. The dielectrics at the rear result in a decreased surface recombination velocity of Srear = 70 cm/s and 80 cm/s, and an increased internal IR reflectance of up to 91% corresponding to an improved Jsc of up to 38.9 mA/cm2 and Voc of up to 664 mV. We observe an increase in cell efficiency of 0.8% absolute for the cells compared to 18.6% efficient reference solar cells featuring a full‐area aluminum back surface field. To our knowledge, the energy conversion efficiency of 19.4% is the best value reported so far for large area screen‐printed solar cells. (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献