Electric and electrochemical properties of solid LiH2PO4

Electrical and electrochemical properties of solid LiH₂PO₄ conductor were investigated in the temperature range from room temperature to 373 K. It was found that high conductivity throughout the temperature range, with activation energy 17.23 kJ/mol, originates from the movement of hydrogen ions (protons). The movement of protons in the correlation with phosphate groups rotation was considered. The slopes of Tafel lines and exchange current densities both for cathodic hydrogen and anodic oxygen evolution were determined (by means of usual electrochemical kinetic methods) at various temperatures. The energy of activation at the equilibrium potentials both for the cathodic and the anodic processes have been assessed to be 17.23 kJ/mol (0.18 eV) and 2.9 kJ/mol (0.03 eV), respectively.     

Reply to the Comment on¶Low temperature specific heat of blue bronze K0.30MoO3

Eur. Phys. J. B 24, 315 (2001) In our Reply to the Comment [#!1!#] we refute the “straightforward” interpretation of the excess low-temperature specific heat, C_p, contribution we have measured in our study of CDW systems K_0.3MoO₃ and (TaSe₄)₂I [#!2!#] as originating solely from normal phonon modes. The specific sensitivity of the bump in C _p / T ³ at low temperatures to the impurity content is consistent with the increased value of the phason pinning gap while the dispersion of normal phonons remains unaffected. We ascribe at least this part of the anomaly to the phason contribution. As stated in reference [3] that the phonon density of states extracted from neutron scattering measurements is the least reliable in this energy range (<0.5 meV), we conclude that C_p measurements are more accurate for detecting the phason contribution. Received 17 April 2002 Published online 19 July 2002     

Barzilai–Borwein method with variable sample size for stochastic linear complementarity problems

A smoothing method for solving stochastic linear complementarity problems is proposed. The expected residual minimization reformulation of the problem is considered, and it is approximated by the sample average approximation (SAA). The proposed method is based on sequential solving of a sequence of smoothing problems where each of the smoothing problems is defined with its own sample average approximation. A nonmonotone line search with a variant of the Barzilai–Borwein (BB) gradient direction is used for solving each of the smoothing problems. The BB search direction is efficient and low cost, particularly suitable for nonmonotone line search procedure. The variable sample size scheme allows the sample size to vary across the iterations and the method tends to use smaller sample size far away from the solution. The key point of this strategy is a good balance between the variable sample size strategy, the smoothing sequence and nonmonotonicity. Eventually, the maximal sample size is used and the SAA problem is solved. Presented numerical results indicate that the proposed strategy reduces the overall computational cost.     

Extensions of the Fill–Fishkind formula and the infimum – parallel sum relation

Recently, in (Arias ML, Corach G, Maestripieri A. Range additivity, shorted operator and the Sherman–Morrison–Woodburry formula, Linear Algebra Appl. 2015;467), authors gave a generalization of a formula by Fill and Fishkind, regarding the Moore–Penrose inverse of the sum of two matrices, in the setting of arbitrary Hilbert spaces. We consider this formula under some weaker assumptions and derive certain conclusions generalizing the mentioned result. We also extend a formula connecting the infimum of two orthogonal projections and their parallel sum to a formula connecting the star-infimum and the parallel sum of operators which need not be positive, using the concept of parallel sum that was introduced in (Antezana J, Corach G, Stojanoff D. Bilateral shorted operators and parallel sums. Linear Algebra Appl. 2006;414).     

Sums and Limits of Generalized Direct Families of Algebras

In this paper we introduce a generalization of direct families of algebras and we study their limits and sums. In the case of generalized direct families of algebras carried by idempotent algebras we investigate some subdirect decompositions of their sums. The results that we obtain generalize various results given by J.L. Chrislock and T. Tamura [2], M. iri and S. Bogdanovi [3-7], H. Mitsch [13], M. Petrich [14-16], B.M. Schein [23-24] and others.Supported by Grant 04M03B of RFNS through Math. Inst. SANU     

Graphs with Least Eigenvalue −2: The Star Complement Technique

Let G be a connected graph with least eigenvalue –2, of multiplicity k. A star complement for –2 in G is an induced subgraph H = G – X such that |X| = k and –2 is not an eigenvalue of H. In the case that G is a generalized line graph, a characterization of such subgraphs is used to decribe the eigenspace of –2. In some instances, G itself can be characterized by a star complement. If G is not a generalized line graph, G is an exceptional graph, and in this case it is shown how a star complement can be used to construct G without recourse to root systems.     

Zero–One Law for some Brownian Functionals

We prove that for a>0, (B _t) one-dimensional standard Brownian motion and ₀=inf{t>0 : B _t=0} the following zero–one law is valid

Millisecond pulsars with r-modes as steady gravitational radiators

Millisecond pulsars (MSPs) probably achieve their fast rotation by mass transfer from their companion stars in low-mass x-ray binaries (LMXBs). The lack of MSPs and LMXBs rotating near breakup has been attributed to the accretion torque being balanced, at fast rotation, by gravitational radiation, perhaps caused by an unstable oscillation mode. It has been argued that internal dissipation involving hyperons may cause LMXBs to evolve into a quasisteady state, with nearly constant rotation rate, temperature, and mode amplitude. We show that MSPs descending from these LMXBs spend a long time in a similar state, as extremely steady sources of gravitational waves and thermal x rays, while they spin down due to gravitational radiation and the standard magnetic torque. Observed MSP braking torques already place meaningful constraints on this scenario.     

High precision wavelength measurements of QED-sensitive forbidden transitions in highly charged argon ions

We present the results of an experimental study of magnetic dipole (M1) transitions in highly charged argon ions (Ar X, Ar XI, Ar XIV, Ar XV) in the visible spectral range using an electron beam ion trap. Their wavelengths were determined with, for highly charged ions, unprecedented accuracy up to the sub-ppm level and compared with theoretical calculations. The QED contributions, calculated in this Letter, are found to be 4 orders of magnitude larger than the experimental error and are absolutely indispensable to bring theory and experiment to a good agreement. This method shows great potential for the study of QED effects in relativistic few-electron systems.     

The error bounds of Gauss-Kronrod quadrature formulae for weight functions of Bernstein-Szegő type

We consider the Gauss-Kronrod quadrature formulae for the Bernstein-Szeg? weight functions consisting of any one of the four Chebyshev weights divided by the polynomial \(\rho (t)=1-\frac {4\gamma }{(1+\gamma )^{2}}\,t^{2},\quad t\in (-1,1),\ -1<\gamma \le 0\). For analytic functions, the remainder term of this quadrature formula can be represented as a contour integral with a complex kernel. We study the kernel, on elliptic contours with foci at the points ? 1 and sum of semi-axes ρ > 1, for the given quadrature formula. Starting from the explicit expression of the kernel, we determine the locations on the ellipses where maximum modulus of the kernel is attained. So we derive effective error bounds for this quadrature formula. An alternative approach, which has initiated this research, has been proposed by S. Notaris (Numer. Math. 103, 99–127, 2006).