C-N bond formation via ligand-induced nucleophilicity at a coordinated triamidoamine ligand

Reaction of (N(3)N)ZrX complexes (X = amido, Cl(-), CH(3)(-)) with carbodiimide substrates results in insertion into an Zr-N bond of the triamidoamine ligand rather than the Zr-X bond as has been observed for related (N(3)N)ZrX complexes (X = PR(2)(-), AsR(2)(-)).     

On totalization of the Kurzweil-Henstock integral in the multidimensional space

In this paper a full totalization is presented of the Kurzweil-Henstock integral in the multidimensional space. A residual function of the total Kurzweil-Henstock primitive is defined.     

Dietary Flavonoids: Cardioprotective Potential with Antioxidant Effects and Their Pharmacokinetic,Toxicological and Therapeutic Concerns

Flavonoids comprise a large group of structurally diverse polyphenolic compounds of plant origin and are abundantly found in human diet such as fruits, vegetables, grains, tea, dairy products, red wine, etc. Major classes of flavonoids include flavonols, flavones, flavanones, flavanols, anthocyanidins, isoflavones, and chalcones. Owing to their potential health benefits and medicinal significance, flavonoids are now considered as an indispensable component in a variety of medicinal, pharmaceutical, nutraceutical, and cosmetic preparations. Moreover, flavonoids play a significant role in preventing cardiovascular diseases (CVDs), which could be mainly due to their antioxidant, antiatherogenic, and antithrombotic effects. Epidemiological and in vitro/in vivo evidence of antioxidant effects supports the cardioprotective function of dietary flavonoids. Further, the inhibition of LDL oxidation and platelet aggregation following regular consumption of food containing flavonoids and moderate consumption of red wine might protect against atherosclerosis and thrombosis. One study suggests that daily intake of 100 mg of flavonoids through the diet may reduce the risk of developing morbidity and mortality due to coronary heart disease (CHD) by approximately 10%. This review summarizes dietary flavonoids with their sources and potential health implications in CVDs including various redox-active cardioprotective (molecular) mechanisms with antioxidant effects. Pharmacokinetic (oral bioavailability, drug metabolism), toxicological, and therapeutic aspects of dietary flavonoids are also addressed herein with future directions for the discovery and development of useful drug candidates/therapeutic molecules.     

Zirconium-loaded activated charcoal as an adsorbent for arsenic, selenium and mercury

The adsorption of arsenic, selenium and mercury from aqueous solutions onto zirconium-loaded activated charcoal was studied as a function of adsorption time, amount of adsorbent, pH, concentration of adsorbates, sample volume and the oxidation states of the adsorbates. The cross-interference of the analytes was also investigated. Loaded filters were measured by energy-dispersive X-ray fluorescence spectrometry (EDXRF) and the amount of the unadsorbed analytes were determined by vapour generation atomic absorption spectrometry (VGAAS).     

On Banach spaces with few spreading models

If the set of spreading models of a Banach space is countable (up to equivalence), then it cannot contain a strictly increasing infinite chain of spreading models generated by normalized weakly null sequences. Moreover, such a space must have a spreading model which is `close' to or for some .

     

Packing dimension and Ahlfors regularity of porous sets in metric spaces

Let X be a metric measure space with an s-regular measure μ. We prove that if A ì X{A\subset X} is r{\varrho} -porous, then dim_p(A) ￡ s-cr^s{{\rm {dim}_p}(A)\le s-c\varrho^s} where dim_p is the packing dimension and c is a positive constant which depends on s and the structure constants of μ. This is an analogue of a well known asymptotically sharp result in Euclidean spaces. We illustrate by an example that the corresponding result is not valid if μ is a doubling measure. However, in the doubling case we find a fixed N ì X{N\subset X} with μ(N) = 0 such that dim_p(A) ￡ dim_p(X)-c(log\tfrac1r)^-1r^t{{\rm {dim}_p}(A)\le{\rm {dim}_p}(X)-c(\log \tfrac1\varrho)^{-1}\varrho^t} for all r{\varrho} -porous sets A ì X\ N{A \subset X{\setminus} N} . Here c and t are constants which depend on the structure constant of μ. Finally, we characterize uniformly porous sets in complete s-regular metric spaces in terms of regular sets by verifying that A is uniformly porous if and only if there is t < s and a t-regular set F such that A ì F{A\subset F} .     

Cauchy’s residue theorem for a class of real valued functions

Let [a, b] be an interval in ℝ Rand let F be a real valued function defined at the endpoints of [a, b] and with a certain number of discontinuities within [a, b]. Assuming F to be differentiable on a set [a, b] | E to the derivative f, where E is a subset of [a, b] at whose points F can take values ±∞ or not be defined at all, we adopt the convention that F and f are equal to 0 at all points of E and show that KH-vt ∝ _a ^b f = F(b) − F(a), where KH-vt denotes the total value of the Kurzweil-Henstock integral. The paper ends with a few examples that illustrate the theory.     

Oxygen Isotope Labeling Experiments Reveal Different Reaction Sites for the Oxygen Evolution Reaction on Nickel and Nickel Iron Oxides

Nickel iron oxide is considered a benchmark nonprecious catalyst for the oxygen evolution reaction (OER). However, the nature of the active site in nickel iron oxide is heavily debated. Here we report direct spectroscopic evidence for the different active sites in Fe‐free and Fe‐containing Ni oxides. Ultrathin layered double hydroxides (LDHs) were used as defined samples of metal oxide catalysts, and ¹⁸O‐labeling experiments in combination with in situ Raman spectroscopy were employed to probe the role of lattice oxygen as well as an active oxygen species, NiOO^?, in the catalysts. Our data show that lattice oxygen is involved in the OER for Ni and NiCo LDHs, but not for NiFe and NiCoFe LDHs. Moreover, NiOO^? is a precursor to oxygen for Ni and NiCo LDHs, but not for NiFe and NiCoFe LDHs. These data indicate that bulk Ni sites in Ni and NiCo oxides are active and evolve oxygen via a NiOO^? precursor. Fe incorporation not only dramatically increases the activity, but also changes the nature of the active sites.     

Vortex locking in direct numerical simulations of quantum turbulence

Direct numerical simulations are used to examine the locking of quantized superfluid vortices and normal fluid vorticity in evolving turbulent flows. The superfluid is driven by the normal fluid, which undergoes either a decaying Taylor-Green flow or a linearly forced homogeneous isotropic turbulent flow, although the back reaction of the superfluid on the normal fluid flow is omitted. Using correlation functions and wavelet transforms, we present numerical and visual evidence for vortex locking on length scales above the intervortex spacing.     

Underwater speech communications with a modulated laser

A novel speech communications system using a modulated laser beam has been developed for short-range applications in which high directionality is an exploitable feature. Although it was designed for certain underwater applications, such as speech communications between divers or between a diver and the surface, it may equally be used for air applications. With some modification it could be used for secure diver-to-diver communications in the situation where untethered divers are swimming close together and do not want their conversations monitored by intruders. Unlike underwater acoustic communications, where the transmitted speech may be received at ranges of hundreds of metres omnidirectionally, a laser communication link is very difficult to intercept and also obviates the need for cables that become snagged or broken. Further applications include the transmission of speech and data, including the short message service (SMS), from a fixed installation such as a sea-bed habitat; and data transmission to and from an autonomous underwater vehicle (AUV), particularly during docking manoeuvres. The performance of the system has been assessed subjectively by listening tests, which revealed that the speech was intelligible, although of poor quality due to the speech algorithm used. PACS 42.55.Px; 42.60.By; 42.62.-b