全文获取类型
收费全文 | 1180篇 |
免费 | 37篇 |
国内免费 | 6篇 |
专业分类
化学 | 960篇 |
晶体学 | 3篇 |
力学 | 10篇 |
数学 | 125篇 |
物理学 | 125篇 |
出版年
2024年 | 2篇 |
2023年 | 7篇 |
2022年 | 14篇 |
2021年 | 19篇 |
2020年 | 15篇 |
2019年 | 15篇 |
2018年 | 5篇 |
2017年 | 14篇 |
2016年 | 33篇 |
2015年 | 30篇 |
2014年 | 37篇 |
2013年 | 35篇 |
2012年 | 67篇 |
2011年 | 87篇 |
2010年 | 41篇 |
2009年 | 38篇 |
2008年 | 81篇 |
2007年 | 69篇 |
2006年 | 84篇 |
2005年 | 69篇 |
2004年 | 64篇 |
2003年 | 44篇 |
2002年 | 50篇 |
2001年 | 20篇 |
2000年 | 17篇 |
1999年 | 13篇 |
1998年 | 21篇 |
1997年 | 19篇 |
1996年 | 16篇 |
1995年 | 20篇 |
1994年 | 23篇 |
1993年 | 17篇 |
1992年 | 12篇 |
1991年 | 6篇 |
1990年 | 13篇 |
1989年 | 11篇 |
1988年 | 11篇 |
1987年 | 13篇 |
1986年 | 9篇 |
1985年 | 8篇 |
1984年 | 9篇 |
1983年 | 7篇 |
1982年 | 4篇 |
1981年 | 3篇 |
1980年 | 7篇 |
1979年 | 2篇 |
1978年 | 4篇 |
1977年 | 2篇 |
1975年 | 2篇 |
1973年 | 4篇 |
排序方式: 共有1223条查询结果,搜索用时 15 毫秒
821.
Andreas M. Chwatal Günther R. Raidl Karin Oberlechner 《Journal of Mathematical Modelling and Algorithms》2009,8(3):293-334
We present a novel approach for compressing relatively small unordered data sets by means of combinatorial optimization. The
application background comes from the field of biometrics, where the embedding of fingerprint template data into images by
means of watermarking techniques requires extraordinary compression techniques. The approach is based on the construction
of a directed tree, covering a sufficient subset of the data points. The arcs are stored via referencing a dictionary, which
contains “typical” arcs w.r.t. the particular tree solution. By solving a tree-based combinatorial optimization problem we
are able to find a compact representation of the input data. As optimization method we use on the one hand an exact branch-and-cut
approach, and on the other hand heuristics including a greedy randomized adaptive search procedure (GRASP) and a memetic algorithm. Experimental results show that our method is able to achieve higher compression rates for fingerprint (minutiae) data than
several standard compression algorithms. 相似文献
822.
The phase diagram of correlated, disordered electron systems is calculated within dynamical mean-field theory using the geometrically averaged ("typical") local density of states. Correlated metal, Mott insulator, and Anderson insulator phases, as well as coexistence and crossover regimes, are identified. The Mott and Anderson insulators are found to be continuously connected. 相似文献
823.
Karin Erdmann 《Journal of Pure and Applied Algebra》2011,215(7):1747-1768
One of our main results is a classification of all the possible quivers of selfinjective radical cube zero finite-dimensional algebras over an algebraically closed field having finite complexity. In the paper (Erdmann and Solberg, 2011) [5] we classified all weakly symmetric algebras with support varieties via Hochschild cohomology satisfying Dade’s Lemma. For a finite-dimensional algebra to have such a theory of support varieties implies that the algebra has finite complexity. Hence this paper is a partial extension of [5]. 相似文献
824.
Dr. Karin Rettenmaier Dr. Gregor A. Zickler Dr. Günther J. Redhammer Dr. Thomas Berger 《Chemphyschem》2023,24(1):e202200586
Mixed transition metal oxides have emerged as promising electrode materials for electrochemical energy storage and conversion. To optimize the functional electrode properties, synthesis approaches allowing for a systematic tailoring of the materials’ composition, crystal structure and morphology are urgently needed. Here we report on the room-temperature electrodeposition of a ternary oxide based on earth-abundant metals, specifically, the defective cubic spinel ZnMnO3. In this unprecedented approach, ZnO surfaces act as (i) electron source for the interfacial reduction of MnO4− in aqueous solution, (ii) as substrate for epitaxial growth of the deposit and (iii) as Zn precursor for the formation of ZnMnO3. Epitaxial growth of ZnMnO3 on the lateral facets of ZnO nanowires assures effective electronic communication between the electroactive material and the conducting scaffold and gives rise to a pronounced 2-dimensional morphology of the electrodeposit forming – after partial delamination from the substrate – twisted nanosheets. The synthesis strategy shows promise for the direct growth of different mixed transition metal oxides as electroactive phase onto conductive substrates and thus for the fabrication of binder-free nanocomposite electrodes. 相似文献
825.
Under a weak UV irradiation butynediol is selectively hydrogenated to butenediol with IrCl(CO)(PPh3)2 as the catalyst in toluene/trifluroethanol () at 60 °C. 相似文献
826.
827.
828.
Karin Linoh Karl-Heinz Nagel Ilona Lange Oliver Moers Armand Blaschette Peter G. Jones 《无机化学与普通化学杂志》1997,623(7):1175-1182
Polysulfonylamines. LXXXIV. Isotypic Structures in the Dimesylamide Complex Series [M(H2O)4{(CH3SO2)2N}2] (M?Mg, Ca, Ni, Cu, Zn, Cd) and [M(py)4{(CH3SO2)2N}2] (M?Ni, Cu, Zn, Cd) The crystal structures of the trans-octahedral complexes [M(H2O)4{(CH3SO2)2N}2] (M?Ca, Cd), in which the dimesylamide anion acts as a monodentate O-ligand and a tetrafunctional hydrogen bond acceptor, were determined by low-temperature X-ray diffraction. Both belong to an isotypic series (triclinic, space group P1 , Z = 1) that had previously been characterized for M?Mg, Ni, Cu and Zn (Z. Anorg. Allg. Chem. 1996 , 622, 1065). In this structure there exists an extended network of strong hydrogen bonds which is probably the underlying reason why the structure type surprisingly persists across the whole series. To support this explanation by indirect evidence from comparison with suitable structures devoid of strong hydrogen bonding, the analogous trans-octahedral complexes [M(py)4{(CH3SO2)2N}2] (M?Mn, Co, Ni, Cu, Zn, Cd) were prepared by treating M[(CH3SO2)2N]2 with pyridine, and the crystal structures of the Ni, Cu, Zn and Cd compounds were studied by low-temperature X-ray crystallography. As anticipated, the four pyridine complexes do not form an isotypic series but instead two isotypic pairs consisting of the Ni and Zn compounds (monoclinic, space group P21/n, Z =2) and of the Cu and Cd complexes (triclinic, space group P1, Z = 1). All molecules of the aqua and the pyridine complexes display crystallographic centrosymmetry. In the hydrates, the mean M? OH2 and the M? O(anion) distances are 232.6 and 232.7 pm for M ? Ca, 225.5 and 230.3 pm für M ? Cd. The mean M? N and the M? O(anion) bond lengths of the pyridine species amount to 211.8 and 213.1 pm for M ? Ni, 217.0 and 218.5 pm for M ? Zn, 232.8 and 234.4 pm for M ? Cd; the corresponding values for the severely Jahn-Teller distorted Cu complex are 203.6 and 254.5 pm. In the crystals of the pyridine complexes, each methyl group is connected through a weak C? H…?O bond to a sulfonyl oxygen atom of an adjacent molecule. 相似文献
829.
Birgit Siewert Gertraude Koellner Karin Ruhlandt-Senge Fritjof Schmock Ulrich Müller 《无机化学与普通化学杂志》1991,593(1):160-168
Thiohalo Compounds of Niobium and Tantalum: NbSCl3, TaSCl3, [NbSCl5]2?, [TaSCl5]2?, [NbSBr4]?. Crystal Structures of (PPh4)2[NbSCl5] · 2 CH2Cl2 and NEt4[NbCl6] NbSCl3 can be obtained from NbCl5 by reaction with H2S or bistrimethylsilyl sulfide in a suspension of CCl4 or CH2Cl2, respectively; in the latter case the product contains a rest of trimethylsilyl groups. This also applies for TaSCl3, NbSBr3 and TaSBr3, which are formed from the metal pentahalides and S(SiMe3)2. NEt4[NbSCl4] is formed together with NEt4[NbCl6] in the reaction of NbCl5 with NEt4SH in CH2Cl2. PPh4[NbCl6] reacts with S(SiMe3)2 in dichloromethane yielding (PPh4)2[NbSCl5] · 2 CH2Cl2, whereas PPh4[NbSBr4] is obtained from PPh4[NbBr6] and S(SiMe3) under the same conditions. (PPh4)2[TaSCl5] · 2 CH2Cl2 was obtained from TaSCl3 and PPh4Cl in CH2Cl2. According to an X-ray crystal structure determination (PPh4)2[NbSCl5] · 2 CH2Cl2 crystallizes in the β-(AsPh4)2[UCl6] · 2 CH2Cl2 type with positionally disordered, octahedral anions. Crystal data: a = 1 021.7, b = 1120.4, c = 1 243.3 pm, α = 70.77, β = 80.24, γ = 80.54°, space group P1 , Z = 2; 2462 unique observed reflexions, R = 0.036. NEt4[NbCl6] crystallizes isotypic to NEt4[WCl6], a = 723.5, b = 1 018.0, c = 1 174.6 pm, β = 100.07°, space group P21/n, Z = 2; 1 875 reflexions, R = 0.075. 相似文献
830.
Luis Daniel Goyzueta-Mamani Haruna Luz Barazorda-Ccahuana Miguel Angel Chvez-Fumagalli Karla Lucia F. Alvarez Jorge Alberto Aguilar-Pineda Karin Jannet Vera-Lopez Christian Lacks Lino Cardenas 《Molecules (Basel, Switzerland)》2022,27(3)
Background: Despite research on the molecular bases of Alzheimer’s disease (AD), effective therapies against its progression are still needed. Recent studies have shown direct links between AD progression and neurovascular dysfunction, highlighting it as a potential target for new therapeutics development. In this work, we screened and evaluated the inhibitory effect of natural compounds from native Peruvian plants against tau protein, amyloid beta, and angiotensin II type 1 receptor (AT1R) pathologic AD markers. Methods: We applied in silico analysis, such as virtual screening, molecular docking, molecular dynamics simulation (MD), and MM/GBSA estimation, to identify metabolites from Peruvian plants with inhibitory properties, and compared them to nicotinamide, telmisartan, and grapeseed extract drugs in clinical trials. Results: Our results demonstrated the increased bioactivity of three plants’ metabolites against tau protein, amyloid beta, and AT1R. The MD simulations indicated the stability of the AT1R:floribundic acid, amyloid beta:rutin, and tau:brassicasterol systems. A polypharmaceutical potential was observed for rutin due to its high affinity to AT1R, amyloid beta, and tau. The metabolite floribundic acid showed bioactivity against the AT1R and tau, and the metabolite brassicasterol showed bioactivity against the amyloid beta and tau. Conclusions: This study has identified molecules from native Peruvian plants that have the potential to bind three pathologic markers of AD. 相似文献