The distribution of ions and their valencies in manganese ferrites II. Mn1+xFe2-xO4+y ferrites

The influence of the oxygen content on the saturation magnetic moment and the Curie temperature was studied experimentally on non-stoichiometric manganese ferrites having a varying excess of manganese. Taking into consideration the results of studying the electrical conductivity and magnetic relaxation effects, a model was elaborated for the distribution of ions in these ferrites, which starts out from the distribution of ions in stoichiometric manganese ferrite. The experimental results obtained by us and those of other authors confirm the justification of this model.

---

II. Mn_1+xFe_2-xO_4+y

. , . .

---

---

In conclusion the authors thank members of their technological department for preparing the samples and M. Mikulá for carefully carrying out the chemical analyses.     

The distribution of ions and their valencies in manganese ferrites I. MnFe2O4+γ ferrites

A model for the distribution of cations in the spinel lattice of manganese ferrites MnFe₂O₄₊ was elaborated on the basis of the experimental studies of the basic magnetic quantities, electrical conductivity and magnetic relaxation of the given ferrites, taking into consideration their crystallographic properties. The conclusions following from this model are in good agreement with the experimental results obtained by us and by other authors both for stoichiometric manganese ferrite and for a ferrite where 0.

---

I. MnFe₂O₄₊

, MnFe₂O₄₊ . , , , , , 0.

     

Новый метод измерени я магнитокалорическ ого эффекта у ферромагни тных полупроводнико в

, .     

Laser system using a spherical pumping reflector

A solid state laser has been developed which employs a spherical pumping cavity. The rod of the active medium (ruby, neodymium, etc.) and the flash tube are symmetrically placed with respect to a plane passing through the centre of the sphere. With Nd³⁺-doped glass an efficiency of 3% is obtained.     

Fabrication of diamond nanorods for gas sensing applications

Diamond nanorods were fabricated for a sensing device by utilizing reactive ion etching in CF₄/O₂ radio frequency plasma. The length of the nanorods has been controlled by the ion etching time. The obtained morphologies were investigated by scanning electron microscopy. The gas sensing properties of the H-terminated diamond-based sensor structures are indicating that we have achieved high sensitivity to detect phosgene gas. Also, our sensor exhibited good selectivity between humid air and phosgene gas if the measurement is conducted at elevated temperatures, such as 140 °C. Furthermore, such sensor response rating could reach as high value as 4344 for the phosgene gas, which was evaluated for the sample consisting of the longest nanorods (up to 200 nm).     

Error estimates for the finite element solution of elliptic problems with nonlinear newton boundary conditions

The paper is concerned with the study of an elliptic boundary value problem with a nonlinear Newton boundary condition. The existence and uniqueness of the solution of the continuous pioblem is a consequence of the monotone operator theory. The main attention is paid to the investigation of the finite element approximation using numeriral integration for the evaluation of boundary integrals. The error estimates for the solution of the discrete finite element problem are derived     

Gaining insight into student satisfaction using comprehensible data mining techniques

As a consequence of the heightened competition on the education market, the management of educational institutions often attempts to collect information on what drives student satisfaction by e.g. organizing large scale surveys amongst the student population. Until now, this source of potentially very valuable information remains largely untapped. In this study, we address this issue by investigating the applicability of different data mining techniques to identify the main drivers of student satisfaction in two business education institutions. In the end, the resulting models are to be used by the management to support the strategic decision making process. Hence, the aspect of model comprehensibility is considered to be at least equally important as model performance. It is found that data mining techniques are able to select a surprisingly small number of constructs that require attention in order to manage student satisfaction.     

High Performance Liquid Chromatography‐Electrochemistry‐Electrospray Ionization Mass Spectrometry (HPLC/EC/ESI‐MS) for Detection and Characterization of Roscovitine Oxidation Products

On‐line LC‐EC/ESI‐MS has been established as a fast and simple method to mimic some types of oxidation reaction of various drugs and to study the formation and structure of the resulting products. This technique has been applied to a 2,6,9‐trisubstituted purine, R‐roscovitine, which is known to be an inhibitor of some cyclin‐dependent kinases (CDKs) and a potential anticancer drug. Oxidation of R‐roscovitine in an electrochemical cell (EC), operated under various conditions, resulted in appearance of 6 major products. These were further analyzed by high‐resolution mass spectrometry, their structures were elucidated by accurate mass measurement and compared to previously identified R‐roscovitine in vitro/in vivo metabolites. Although none of the observed products was structurally identical to those identified previously in vitro/in vivo, all of them, except for the methoxylated products, resembled similarity due to appearing through the same reaction type. R‐roscovitine in the EC cell underwent N‐dealkylation of the isopropyl moiety, hydroxylation of the aromatic side‐chain, dihydroxylation, methoxylation and dimer formation. The hydroxylation product was identified as Olomoucine II, a R‐roscovitine derivative, which displays 10‐times higher CDK‐inhibiting activity than R‐roscovitine and the occurrence of which, as R‐roscovitine product, has not yet been observed in vitro/in vivo.     

On the stereochemistry of photoaddition between α,β-unsaturated ketones and olefins. III.

The α,β-unsaturated ketone $\text{1}$ yields with allene the photocycloadduct $\text{3}$ predicted by our empirical photoaddition rule and the byproduct 7. The formation of this material may be rationalized by the sequence $\text{1}$ → $\text{4}$ → $\text{5}$ → $\text{6}$ → $\text{7}$. The isomeric ketone $\text{2}$ is unreactive under the same conditions, since α addition is prohibited by the rule and β addition is severely blocked.