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11.
Infrared-to-visible wave-length conversion in the Yb3+−Er3+ doped phosphors system has been described by a simple three level model based on two ions mechanism. The excitation in the
range of 900–1000 nm of an IR-photon is first absorbed by Yb3+ ion as a sensitizer attributed to the resonant energy transition in Er3+ ion from 4
I
3/2 → 4
S
15/2 and 1
F
9/2 → 4
I
15/2, respectively for green and red emission. The essential energy transfer processes in this system i.e. upconversion from 4
I
11/2 and 1
I
13/2, cross-relaxation from 4
S
3/2 and 1
F
9/2 are taken into account. The limitations of the rate-equation approach are examined with a focus on the underlying dynamics
of this rare-earth system. 相似文献
12.
APPLICATION OF GENETIC ALGORITHM IN PARTICLE SIZE ANALYSIS BY MULTISPECTRAL EXTINCTION MEASUREMENTS 总被引:1,自引:0,他引:1
Gerard Grhan 《中国颗粒学报》2004,2(6):235-240
Both dependent and independent model algorithms are designed with genetic algorithm (GA) to retrieve aerosol size data from multispectral extinction measurements. Compared with the traditional dependent model algorithm, e.g., simplex, GA can locate the global optimized solution instead of local ones. As an independent model algonthm, when combined with B-splines, GA gives consistent results with Chahine and Phillip-Twomey-NNLS algorithms. Numerical simulations also show that GA has high stability and good resistance to relatively higher error levels. For a population size of 50 in the present paper, the feasible ranges for genetic operators Pc and pm are found to be [0.01, 0.5] and [0.01, 0.15], respectively, and the generation number Gen_Max should be larger than 250. 相似文献
13.
LI YingQiu HU YangLi & LIU QuanSheng College of Mathematics Computing Sciences Changsha University of Science Technology Changsha China College of Mathematics Computer Sciences Hunan Normal University Changsha LMAM University of Bretgne-Sud BP Vannes France 《中国科学 数学(英文版)》2011,(7)
Let W be the limit of the normalized population size of a supercritical branching process in a varying or random environment. By an elementary method, we find sufficient conditions under which W has finite weighted moments of the form EWpl(W), where p > 1, l 0 is a concave or slowly varying function. 相似文献
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17.
In a search for evidence that a π cloud proximal halogen interaction is of importance to the mode of action of the thyroid hormones, the dipole moments of the 1'-naphthyl (I), (4.29 D), 4'-carboxymethylphenyl (II), (2.90 D), 2'-bromo4'-carboxymethylphenyl (III), (3.56 D), and methyl (IV), (3.24 D) ethers of 2,4dinitro-6-bromophenol were determined in benzene at 25 °C. The moments of (I), (II) and (III) are approximated best by those calculated for the twisted conformation in which the bromine closely approaches the face of the other ring. That of the naphthyl ether (I) can, however, be explained only by inclusion of an intramolecular electron donor-acceptor charge-transfer moment of 1.6 D directed from the π cloud of the naphthyl ring to the proximal nitro group of the other ring, or of 2.8 D to the proximal bromine of that ring. In the preferred conformation of the methyl ether (IV), the methoxy group is coplanar with the ring while the 2-nitro group is twisted 90° from coplanarity to accomodate it. A mesomeric moment of 2.3 D is estimated from this for the 2,4-dinitro-6-bromophenoxy moiety and is used in calculating the expected moments of the other ethers. 相似文献
18.
LI Xiang LI Zhong XI Hongxia LUO Lingai The Institute of Chemical Engineering South China University of Technology Guangzhou China LSGC-CNRS-ENSIC rue Grandville BP Nancy Cedex France 《Chinese Journal of Reactive Polymers》2004,(Z1)
1. INTRODUCTION With the development of municipalization in China, more and more cities are challenged by the problem of how to dispose of the dramatically increased municipal waste. Generally, most of municipal solid waste is landfilled or dumped openly in the suburbs. It causes not only land waste, but also serious environment pollution. In order to solve efficiently the environment pollution caused by municipal solid waste, incineration technique was introduced in some big cities such… 相似文献
19.
Production of laccase by immobilized cells of Agaricus sp. 总被引:1,自引:0,他引:1
Kaluskar VM Kapadnis BP Jaspers C Penninckx MJ 《Applied biochemistry and biotechnology》1999,76(3):161-170
Laccase was produced in the supernatant of culture of a local isolate of Agaricus sp. obtained from decaying Ficus religiosa wood. The enzyme was produced at a constitutive level when growing the fungus in a nitrogenlimited medium supplemented with
either glycerol, glucose, fructose, mannitol, arabinose, maltose, sacch arose, cellulose, or cellobiose. Atwo-to sixfold increase
in enzyme specific activity was observed when growing the strain in the presence of straw, xylan, xylose, lignosulfonate,
veratryl alcohol, and ferulic and veratric acid. Experimentsare consistent with the existence of an induction control on laccase
and the absence of a form of carbon catabolite repression mediated by noninducing carbon sources. Immobilization of the Agaricus sp. on several supports, including polyurethane foam, textilestrips, and straw, resulted in an increase of enzyme production
as compared to cultivation in liquid medium. 相似文献
20.
Virdee S Kapadnis PB Elliott T Lang K Madrzak J Nguyen DP Riechmann L Chin JW 《Journal of the American Chemical Society》2011,133(28):10708-10711
Protein ubiquitination is a post-translational modification that regulates almost all aspects of eukaryotic biology. Here we discover the first routes for the efficient site-specific incorporation of δ-thiol-L-lysine (7) and δ-hydroxy-L-lysine (8) into recombinant proteins, via evolution of a pyrrolysyl-tRNA synthetase/tRNA(CUA) pair. We combine the genetically directed incorporation of 7 with native chemical ligation and desulfurization to yield an entirely native isopeptide bond between substrate proteins and ubiquitin. We exemplify this approach by demonstrating the synthesis of a ubiquitin dimer and the first synthesis of ubiquitinated SUMO. 相似文献