Radical graft polymerization onto composite particles of polydimethylsiloxane and polybutadiene

Submicron-size composite polymer particles consisting of polydimethylsiloxane/core and polybutadiene/shell were synthesized by seeded emulsion polymerization. The morphologies of composite particles were affected by polybutadiene ratio in the composite particles. Highly grafted polymer by poly(styrene-co-acrylonitrile) could be prepared by using the composite particles containing polybutadiene with polymerizable group. The morphologies of the grafted polymer were influenced by the morphologies of composite particles and the kinds of grafting initiators. It was found that surface gloss and lubricity of the graft polymers were influenced by morphologies of composite particles.     

Formation of non-racemic E- and Z-olefins based on discrimination of enantiotopic carbonyl groups in α-diketones by a chiral phosphonate reagent

A chiral HWE reagent reacted with an alternative carbonyl group of meso-α-diketones of bicyclo[2.2.1] system to give non-racemic (Z)- and (E)-olefins, respectively.     

Enantioselective Protonation of Cyclic Carbonyl Ylides by Chiral Lewis Acid Assisted Alcohols

Chiral Lewis acid-catalyzed asymmetric alcohol addition reactions to cyclic carbonyl ylides generated from N-(α-diazocarbonyl)-2-oxazolidinones featuring a dual catalytic system are reported. Construction of a chiral quaternary heteroatom-substituted carbon center was accomplished in which the unique heterobicycles were obtained in good yields with high stereoselection. The alcohol adducts were successfully converted to optically active oxazolidine-2,4-diones by hydrolysis. Mechanistic studies by DFT calculations revealed that alcohols could be activated by Lewis acids, enabling enantioselective protonation of the carbonyl ylides.     

Anonymous and leakage resilient IBE and IPE

We construct identity-based encryption and inner product encryption schemes under the decision linear assumption. Their private user keys are leakage-resilient in several scenarios. In particular,

• In the bounded memory leakage model (Akavia et al., TCC, vol. 5444, pp. 474–495, 2009), our basic schemes reach the maximum-possible leakage rate \(1-o(1)\).
• In the continual memory leakage model (Brakerski et al., Overcoming the hole in the bucket: public-key cryptography resilient to continual memory leakage, 2010; Dodis et al., Cryptography against continuous memory attacks, 2010), variants of the above schemes enjoy leakage rate at least \(\frac{1}{2} -o(1)\). Among the results, we improve upon the work of Brakerski et al. by presenting adaptively secure IBE schemes.

In addition, we prove that our IBE schemes are anonymous under the DLIN assumption, so that ciphertexts leaks no information on the corresponding identities. Similarly, attributes in IPE are proved computationally hidden in the corresponding ciphertexts.

     

Efficient Rabin-type Digital Signature Scheme

Rabin's cryptosystem was proved to be as hard as factorization. However, Rabin's digital signature schemes is probabilistic. This paper shows two efficient Rabin type digital signature schemes, a basic scheme and an improved scheme. Both schemes run much faster than Rabin's scheme. They are deterministic and the size of a signature is much smaller than that of a signature in Rabin's scheme. Furthermore, it is proved that, by applying the technique of Bellare and Rogaway, the proposed scheme is secure against chosen plaintext attack. More precisely, breaking the proposed digital signature scheme by chosen plaintext attack is as hard as factoring N.     

Variations on the theme of slacks-based measure of efficiency in DEA

In DEA, there are typically two schemes for measuring efficiency of DMUs; radial and non-radial. Radial models assume proportional change of inputs/outputs and usually remaining slacks are not directly accounted for inefficiency. On the other hand, non-radial models deal with slacks of each input/output individually and independently, and integrate them into an efficiency measure, called slacks-based measure (SBM). In this paper, we point out shortcomings of the SBM and propose four variants of the SBM model. The original SBM model evaluates efficiency of DMUs referring to the furthest frontier point within a range. This results in the hardest score for the objective DMU and the projection may go to a remote point on the efficient frontier which may be inappropriate as the reference. In an effort to overcome this shortcoming, we first investigate frontier (facet) structure of the production possibility set. Then we propose Variation I that evaluates each DMU by the nearest point on the same frontier as the SBM found. However, there exist other potential facets for evaluating DMUs. Therefore we propose Variation II that evaluates each DMU from all facets. We then employ clustering methods to classify DMUs into several groups, and apply Variation II within each cluster. This Variation III gives more reasonable efficiency scores with less effort. Lastly we propose a random search method (Variation IV) for reducing the burden of enumeration of facets. The results are approximate but practical in usage.     

Past-present-future Intertemporal DEA models

It has been well recognized that to thoroughly evaluate a firm’s performance, the evaluator must assess not only its past and present records but also future potential. However, to the best of our knowledge, there are no data envelopment analysis (DEA)-type models proposed in the literature that simultaneously take past, present and, especially, future performance indicators into account. Hence, this research aims at developing a new type of DEA model referred to as Intertemporal DEA models that can be used to fully measure a firm’s efficiency by explicitly considering its key inputs and outputs involving the past-present-future time span. In this research, the proposed Intertemporal DEA models are applied to the performance evaluation of high-tech Integrated Circuit design companies in Taiwan to demonstrate their advantages over other DEA models that ignore intertemporal efficiency.     

An epsilon-based measure of efficiency in DEA – A third pole of technical efficiency

In DEA, we have two measures of technical efficiency with different characteristics: radial and non-radial. In this paper we compile them into a composite model called “epsilon-based measure (EBM).” For this purpose we introduce two parameters which connect radial and non-radial models. These two parameters are obtained from the newly defined affinity index between inputs or outputs along with principal component analysis on the affinity matrix. Thus, EBM takes into account diversity of input/output data and their relative importance for measuring technical efficiency.     

A slacks-based measure of efficiency in data envelopment analysis

In this paper, we will propose a slacks-based measure (SBM) of efficiency in Data Envelopment Analysis (DEA). This scalar measure deals directly with the input excesses and the output shortfalls of the decision making unit (DMU) concerned. It is units invariant and monotone decreasing with respect to input excess and output shortfall. Furthermore, this measure is determined only by consulting the reference-set of the DMU and is not affected by statistics over the whole data set. The new measure has a close connection with other measures proposed so far, e.g., Charnes–Cooper–Rhodes (CCR), Banker–Charnes–Cooper (BCC) and the Russell measure of efficiency. The dual side of this model can be interpreted as profit maximization, in contrast to the ratio maximization of the CCR model. Numerical experiments show its validity as an efficiency measurement tool and its compatibility with other measures of efficiency.