The Hamiltonian systems on the Poisson structure of the quasi-classical limit of GL q (∞)

We consider the Hamiltonian systems on the Poisson structure of GL() which is introduced from the quantum group GL _q () by the so-called quasi-classical limit of GL _q (). Furthermore, we show that the Toda lattice hierarchy is a Hamiltonian system of this structure.     

Palladium-catalyzed addition of nitrogen pronucleophiles to alkylidenecyclopropanes

The inter- and intramolecular additions of cyclic amides (nitrogen pronucleophiles) to methylenecyclopropanes proceeded smoothly in the presence of catalytic amounts of Pd(PPh(3))(4), affording the corresponding hydroamination products in good to high yields with high regioselectivities. The ring opening of methylenecyclopropanes occurred at the distal position of the cyclopropane ring.     

Selective synthesis of 1,4,5-trisubstituted imidazoles from α-imino ketones prepared by N-heterocyclic-carbene-catalyzed aroylation

An alternative synthetic route to 1,4,5-trisubstituted imidazoles from α-imino ketone, which can be prepared from imidoyl chlorides and aromatic aldehydes via N-heterocycle carbene-catalyzed aroylation was developed. This methodology consists of simple transformations, allowing a rapid access to imidazole derivatives with various aryl substituents at the desired positions.