Principal component and Tucker3 analyses of high performance liquid chromatography with diode-array detection fingerprints of crude extracts of Erythrina speciosa Andrews leaves

Mixtures of ethanol, dichloromethane, hexane and acetone obtained according to a statistical design have been used to extract substances from Erythrina speciosa Andrew leaves for chromatographic fingerprinting. The plant extracts from each mixture were analyzed by HPLC-DAD providing UV–vis spectra for each chromatographic peak. These chromatograms and spectra for the design mixtures were then treated with principal component (PCA), Tucker3 and PARAFAC analyses. PCA indicated the existence of five different chromatographic fingerprints for the leave extracts depending on the solvent mixture composition. Different chromatographic peak areas were strongly correlated with the mixture proportions of acetone, dichloromethane and ethanol. Tucker3 and PARAFAC analyses were very useful for identifying simultaneous correlations between chromatographic peak areas, spectral band absorbances and solvent proportions. The acetone proportion was highly correlated with the area of the 3.69 min retention time peak and the spectral absorbances between 250 and 260 nm, consistent with the presence of natural polyphenols. The dichloromethane mixture proportion was strongly correlated with the 12.19 min chromatographic peak area and a single spectral absorbance at 201 nm. This spectral absorption is characteristic of the electronic structures of terpenes and alkaloids.     

Characterisation of historic plastics using terahertz time-domain spectroscopy and pulsed imaging

Terahertz (THz) time-domain spectroscopy and 3D THz pulsed imaging have been explored with regard to polymer materials, both commodity and historic polymers. A systematic spectroscopic study of a wide range of different polymer materials showed significant differences in their spectra. Polyolefins and polystyrenes generally exhibit lower absorption than other examined polymers, various cellulose derivates, poly(vinyl chloride), poly(methyl methacrylate), polyamide, hard rubber and phenol formaldehyde resin, the last of these exhibiting the most intense absorption over the entire range, 0.15–4.2 THz. It was also examined how the presence of plasticisers in poly(vinyl chloride), the presence of fillers in polypropylene, and the degree of branching in polyethylene and polystyrene affect the spectra; inorganic fillers in polypropylene affected the absorption most. With 3D THz pulsed imaging, features in polymer objects were explored, appearing either as integral parts of the material (coatings and pores in foams) or as a consequence of physical deterioration (cracks, delamination). All of these features of various complexities can be successfully imaged in 3D. Terahertz technology is thus shown to have significant potential for both chemical and structural characterisation of polymers, which will be of interest to heritage science, but also to the polymer industry and development of analytical technologies in general.     

Chlorotrimethylsilane promoted asymmetric Michael reaction of chiral enamines of α-alkyl β-keto esters

By the promotion of chlorotrimethylsilane, asymmetric Michael reaction of the chiral enamines (2) of α-alkyl β-keto esters (1) with methyl vinyl ketone and ethyl acrylate proceeded to afford, after hydrolysis, either enantiomer of the corresponding adducts (4) in a good enantioselectivity.     

Derivatives of Dedekind sums and their reciprocity law

In this paper derivatives of Dedekind sums are defined, and their reciprocity laws are proved. They are obtained from values at non-positive integers of the first derivatives of Barnes’ double zeta functions. As special cases, they give finite product expressions of the Stirling modular form and the double gamma function at positive rational numbers.     

Lipophilic aminimides possessing an additional ligating group as extractants for heavy metal cations

The title compounds were prepared in good yields by Slagel's method. All compounds obtained were used as agents for liquid-liquid extraction. They showed high affinity for certain heavy metal cations and their extractability depended to a great extent on the ligand structure. This dependence is believed to be due to the chelation of the metal cations between the imino nitrogens and the additional ligating site.     

High-pressure Raman study of Ba doped silicon clathrate

Vibrational properties of Ba doped Si clathrate are investigated at high pressures up to 20 GPa by Raman spectroscopy. Vibrations related with Ba encaged in the Si cages are observed below 100 cm(-1) by low-frequency Raman measurements of Ba8Si46 and Ba6.6Si46 clathrates. The high-pressure Raman spectra obtained for both compression and decompression processes reveal a new phase transition at 7 GPa, and the reversibility of the phase transition at 15 GPa. We investigate the mechanisms of these phase transitions, the interaction between the guest and host frame, and the volume dependence of the vibrational modes.     

Rhodium-catalyzed reaction of thiols with polychloroalkanes in the presence of triethylamine

[reaction: see text] RhCl(PPh(3))(3) catalyzes a reaction of thiols with polychloroalkanes in the presence of triethylamine. This reaction serves as a convenient new method to produce formaldehyde dithioacetals, ethylenedithioethers, thioformates, and dithiocarbonic esters under mild conditions.     

Two-channel separable potential model for the low-energy hyperon-nucleon interaction

A two-channel separable potential model is given such that the T-matrix is given in the form of a N/D matrix. This model is used to examine the relationships between the three different definitions for a resonance in the two-channel problem, particularly for a ³S₁ Λp resonance. In order to obtain a phenomenological hyperon-nucleon (YN) scattering T-matrix in the present model, a least-squares fit is performed to the existing available data for the $\text{I =}\text{1}\text{2}\text{YN}$ scattering cross sections and angular distributions at low energies using the s- and p-wave N/D solutions which carry sixteen independent parameters. Several solution sets of potential parameters are found, for which we can obtain good fits to the Λp → Λp, Σ^?p → Λn and ΣN → ΣN data, particularly to the cross-section data for these processes. The p-wave contributions are estimated, and particularly the possibility of p-wave YN resonances is pointed out for the solutions for which we do not assume a ³₁ Λp resonance.