Electrochemical behavior of anthraquinone in aqueous solution in presence of a non-ionic surfactant

Cyclic voltammetric behavior of anthraquinone in aqueous medium has been studied in presence of a non-ionic surfactant, Triton X-100 (TX-100) using sodium salt of anthraquinone-2-sulphonic acid (AQS) as the electro-active species. When cathodic potential is applied, the anthraquinone (AQ) group of AQS is reduced to its dianion. In the reverse scan, the oxidation of AQ²⁻ gives AQ. The electrochemical behavior shows a profound influence from the dissolved state of TX-100 in aqueous media. Spectrophotometric results indicate interaction between AQ and TX-100. A CEC (chemical–electrochemical–chemical) mechanism with the electrochemical reaction coupled with preceding interaction of AQS with TX-100 and following protonation reaction of reduced AQ has been proposed.     

Nonlinear Instability for the Critically Dissipative Quasi-Geostrophic Equation

We prove that linear instability implies non-linear instability in the energy norm for the critically dissipative quasi-geostrophic equation.     

A duality approach to admission and scheduling controls of queues

This paper studies theadmission andscheduling control problem in anM/M/2 queueing system with nonidentical processors. Admission control renders when a newly arrived job should be accepted, whereas scheduling control determines when an available processor should be utilized. The system received a rewardR when a job completes its service and pays a unit holding costC while a job is in the system. The main goal of the paper is to obtain the admission/scheduling policy that maximizes the expected discounted and long-run average profits (reward minus cost). We convert the system into its dual, a stochastically identical system subject toexpulsion/scheduling control, and prove that the individually optimal policy in the dual system is socially optimal in the original system. In contrast with the dynamic programming (DP) technique which considers the system as a whole, we adopt the viewpoint of an individual job and analyze the impact of its behavior on the social outcome. The key properties which simplify the analysis are that under the individually optimal policy the profit of a job under the preemptive last-come first-priority service discipline (LCFP-P) is independent of jobs arrived earlier than itself and that the system is insensitive to service discipline imposed. The former makes possible to bypass complex dynamic programming analyses and the latter serves as a vehicle in connecting the social and individual optimality. We also exploit system operational characteristics under LCFP-P to obtain simple and close approximations of the optimal thresholds.     

The estimation of stochastic cost-quantity frontiers for discretionary cost and budgeted-expenditure systems

Two alternative approximating functions for representing the unknown composite residual density function of a cost-quantity frontier are examined. The frontier is one in which cost is regarded as preselected. This is appropriate for public sector economics and discretionary cost situations. One function requires the estimation of a single distribution parameter, whereas the other makes no a priori assumption on the shape of the density function.     

Inclusive Science Education: Classroom Teacher and Science Educator Experiences in CLASS Workshops

Inclusion is the meaningful participation of students with disabilities in general education classrooms. The CLASS project (Creating Laboratory Access for Science Students) is a unique initiative offering training and resources to help educators provide students with a variety of physical, sensory and learning disabilities equal access in the science laboratory or field. To determine whether participants believed a 2‐week residential workshop sponsored by CLASS raised disability awareness and provided teacher training in inclusive science teaching practice, a multipoint Likert scale survey and questionnaire was completed by all participants (N= 20) in four workshops. Participants reported large gains in their preparedness to teach science to students with disabilities. Participants also reported gains in their familiarity with instructional strategies, curricula, and resources and their ability to design, select, and modify activities for students with disabilities. Finally, shifts in attitudes about teaching science to students with disabilities were noted.     

Dynamic spectral structure specifies vowels for children and adults

When it comes to making decisions regarding vowel quality, adults seem to weight dynamic syllable structure more strongly than static structure, although disagreement exists over the nature of the most relevant kind of dynamic structure: spectral change intrinsic to the vowel or structure arising from movements between consonant and vowel constrictions. Results have been even less clear regarding the signal components children use in making vowel judgments. In this experiment, listeners of four different ages (adults, and 3-, 5-, and 7-year-old children) were asked to label stimuli that sounded either like steady-state vowels or like CVC syllables which sometimes had middle sections masked by coughs. Four vowel contrasts were used, crossed for type (front/back or closed/open) and consonant context (strongly or only slightly constraining of vowel tongue position). All listeners recognized vowel quality with high levels of accuracy in all conditions, but children were disproportionately hampered by strong coarticulatory effects when only steady-state formants were available. Results clarified past studies, showing that dynamic structure is critical to vowel perception for all aged listeners, but particularly for young children, and that it is the dynamic structure arising from vocal-tract movement between consonant and vowel constrictions that is most important.     

Effect of Vibrations on Pore Fluid Distribution in Porous Media

Understanding the role of shuttle vibrations in pore fluid distribution is an essential task in the exploration of plant growth in root modules aboard space flights. Results from experimental investigations are reported in this paper on the distribution of immiscible fluid phases in glass beads under vibrations. Hexadecane, a petroleum compound immiscible with and lighter than water, was used in the experiments. The higher freezing point of Hexadecane (18 °C) allowed the solidification of the entrapped blobs in the presence of water in porous media, so that their size distribution can be obtained. van Genuchten function, commonly used to express moisture retention curves, is found to be an adequate fit for blob size distribution at residual saturation. The effect of vibrations on the fate (mobilization, stranding, or breakup) of a solitary ganglion in porous media was studied using a network model. A mobility criterion considering viscous, gravity, and capillary forces was developed to determine the fate of a solitary ganglion in a porous medium. It is concluded that the effect of vibrations is to increase the likelihood of breakup and mobilization of blobs entrapped in porous media at residual saturation. The pore fluid distributions after vibrations are less uniform than those before vibrations.