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本文运用密度矩阵方程推导了V型三能级系统的荧光量子拍讯号强度,并对其结果进行了分析和讨论。 相似文献
174.
玻色—爱因斯坦凝聚和兰姆位移 总被引:1,自引:0,他引:1
扼要地介绍了BEC研究的近况和研究方向,同时报道了我们在BEC的光散射和兰姆位移方面的研究工作 相似文献
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Toshiki Kono Toshikazo Sakaguchi Yanming Hu Masashi Shiotsuki Fumio Sanda Toshio Masuda 《Journal of polymer science. Part A, Polymer chemistry》2006,44(20):5943-5953
Phenylacetylene (PA) derivatives having two polar groups (ester, 2a – d ; amide, 4) or one cyclic polar group (imide, 5a – c ) were polymerized using (nbd)Rh+[(η6‐C6H5)B?(C6H5)3] catalyst to afford high molecular weight polymers (~1 × 106 – 4 × 106). The hydrolysis of ester‐containing poly(PA), poly( 2a) , provided poly(3,4‐dicarboxyPA) [poly ( 3 )], which could not be obtained directly by the polymerization of the corresponding monomer. The solubility properties of the present polymers were different from those of poly(PA) having no polar group; that is, poly( 2a )–poly( 2d ) dissolved in ethyl acetate and poly( 4 ) dissolved in N,N‐dimethylformamide, while poly(PA) was insoluble in such solvents. Ester‐group‐containing polymers [poly( 2a )–poly( 2d )] afforded free‐standing membranes by casting from THF solutions. The membrane of poly( 2a ) showed high carbon dioxide permselectivity against nitrogen (PCO2/PN2 = 62). © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 5943–5953, 2006 相似文献
178.
Mikaru Ikedo Masanobu Mori Kazumasa Kurachi Wenzhi Hu Kazuhiko Tanaka 《Analytical sciences》2006,22(1):117-121
The selective and simultaneous ion-exclusion chromatography (IEC) with UV-detection on a weakly acidic cation-exchange resin column in the H+ -form (TSKgel Super IC-A/C) was developed and applied for the simultaneous determination of phosphate and silicate ions as the water quality parameters required for optimizing the water-leaching process for ceramics glaze raw materials of natural origin including feldspar, woods-ash, and straw-ash. Phosphate and silicate ions in these water-leaching process water samples were separated selectively from the coexisting anions such as sulfate, chloride, nitrate and carbonate ions, based on the ion-exclusion separation mechanism. They were detected selectively and simultaneously by a postcolumn derivatization with molybdenum-yellow using the UV-detector. Under the optimized separation and detection conditions (eluent, 0-1 mM sulfuric acid; reactant, 10 mM sodium molybdate-25 mM sulfuric acid; detector, UV at 370 nm; temperature, 45 degrees C), the linearity of calibration was in the range 0.1 - 10 ppm for both phosphate and silicate ions, and the detection limits at S/N = 3 were 2.58 ppb for silicate ions and 4.75 ppb for phosphate ions. The effectiveness of this method was demonstrated in practical applications to the water-leaching process for some ceramics glaze raw materials. 相似文献
179.
Solid-phase extraction (SPE) procedure for cleanup followed by HPLC-UV method has been investigated for the determination of pyraflufen-ethyl residues in soil. The pesticide is extracted from the sample with acetone-water (80:20, v/v) and the extract is loaded onto an octadecyl (C(18)) column. The pesticide is eluted with acetonitrile and determined by HPLC with a UV detector. Using an acetone-water extraction followed by a C(18) cleanup, this method is characterized by recovery >90.1%, precision <5.8% RSD and sensitivity of 0.01 mg/kg. The proposed method has been successfully employed for the determination of the degradation dynamics of pyraflufen-ethyl in four agricultural soil samples under laboratory conditions. 相似文献
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In the present work, ferrites with compositions of (Ni0.27Zn0.64Cux)Fe1.98O4 (x=0.1, 0.2) were prepared by conventional ceramic methods. The relationship between the microstructure and the temperature dependence of relative initial permeability was investigated. It was found that intergranular pores in the ferrites generate large demagnetizing fields, reducing the temperature dependence of the effective anisotropy field Heff, and decreasing the temperature dependence of the relative initial permeability accordingly. However, intragranular pores pin the movement of domain walls. Compared with the permeability induced by domain wall motion, the permeability that resulted from the spin rotation is more sensitive to temperature. As a result, the relative initial permeability of ferrites becomes more sensitive to temperature with increasing micropores within grains. 相似文献