Prognostication criterion of potential and practical use of analytical reagents in titrimetria of individual substances

Various possible criterion in titrimetric methods have been discussed in this paper and more informative, visual and universal criterion-the degree of proceeding of individual reaction at the equivalence point have been chosen. The equation for the degree of proceeding of individual analytical reaction suited for any chemical reactions under real conditions with an allowance made for both component and titrant concentration have been deduced. This criterion allows us to make a prognosis of any parametres of a titrimetric procedure of an individual substance determination and the procedure as a whole, not having carried out the experiment.     

Exact solution of a vertex model ind dimensions

We consider a class of vertex models describing directed lines on a lattice in arbitraryd dimensions, and solve the model exactly for the Cartesian lattice and in the case that each loop of lines carries a fugacity - 1. Our analysis, which can be carried out for arbitrary lattices, is based on an equivalence of the vertex model with a dimer problem. The dimer problem is, in turn, solved using the method of Pfaffians. It is found that the system is frozen below a critical temperatureT _cwith the critical exponent = (3 –d)/2.     

Crystal and molecular structure of a new biguanide metal complex, [Cu(AMNH)2]Cl2

The crystal structure of C₆H₁₆N₈O₂·CuCl₂, a biguanide metal complex, has been determined by X-ray diffraction data using MoK radiation. The compound crystallizes in the monoclinic space groupP2₁/a, witha=11.074(4),b=12.061(4),c=5.312(3)Å and=102.8(1)°.The structure was solved by direct methods and refined by full-matrix least-squares to a finalR value 0.037 with 1245 unique reflections. The complex molecule is centrosymmetric, with the Cu atom (0.5,0.5,0.5) on a crystallographic center of symmetry. The complex molecule is rhombic planar with a trans configuration.     

Condensed matter effects on nuclear fusion rates in laboratory and astrophysical environments

Previously overlooked condensed matter effects (CME) can significantly influence nuclear fusion rates in both laboratory and astrophysical environments. In dense plasmas, the ensemble of fusing particles has a significant exchange of kinetic and potential energies. Thus, there are diminished effective flux velocities resulting in a significant selective reduction of fusion rates. Our CME predictions are testable in laboratory experiments and have broad-ranging implications on the fusion rates for stellar media in general. By calculating reaction rates forp(p, e ⁺ v _e ) D and⁷Be(p, )⁸B in the sun, we show that CME help to solve the solar neutrino problem.     

Salting-in of alcohols in aqueous solutions by tetraalkylammonium bromides at the freezing temperature

The freezing-point depression of the ternary systems tetraalkylammonium bromides-t-butanol-water for the first five homologs of R₄NBr was measured. In the case of Bu₄NBr, the effect of size of the alcohol (methahol ton-butanol) was also investigated. From the corresponding freezing-point data for the binary systems the apparent salting constants were calculated. The true salting constantsk _s were obtained by extrapolation to infinite dilution. These are all very close to zero at the freezing temperature. From the corresponding thermochemical data the temperature dependence ofk _s was calculated, and above 5°C all the R₄NBr salts int-butanol; the salting-in increases with temperature and with the size of the hydrophobic cations. The scaled-particle theory is at present the only one which can account semiquantitatively for the temperature dependence of the salting-in effect. On leave of absence from Chemistry Department, The University, Sheffield S3 7HF, England To whom correspondence should be addressed.     

Studies in the chemistry of erythrina alkaloide derivatives—II : Synthesis and stereochemistry of decahydro-3-methyl-6H-pyrido]2,1-i]indole

1,2,3,4,7,7a,8,9,10,11-Decahydro-3-methyl-6$\text{H}$-pyrido[2,1-i]indole was prepared as an example of an erythrinane derivative lacking the aromatic moiety. The stereochemical structure of this compound and its 6-oxo derivative were found to be predominantly cis A/B, trans B/C, axial CH₃ and cis A/B, axial CH₃, respectively.     

Study of occupational health impact of atmospheric pollution on exposed workers at an iron and steel complex by using neutron activation analysis of scalp hair

The occupational health impact of atmospheric pollution on exposed workers at one iron and steel complex was studied by instrumental neutron activation analysis of workers' hair samples and medical examination. The experimental results indicate that there is a positive correlation between the high inhalation amounts of iron and other trace elements by the exposed workers and the symptom of their high blood pressure and hypoglycemia, which implies that the atmospheric environment polluted by iron and steel industry has an adverse health impact on the exposed workers. The measures to relieve and abate the occupational diseases caused by air-borne particulate matter should be taken     

The model U(5) of the triatomic molecule

Rotation-vibration spectra of a triatomic molecule can be classified by the irreducible representations of the group U(5). The dynamical symmetry U(5) ? O(5) ? O(3) is discussed. Its application to the spectrum of HCN is considered.     

Thio-sugars. IV. Synthesis of carbohydrate 1,3-glycol (six-membered) thionocarbonates and their attempted O-S rearrangement

Four six-membered cyclic thionocarbonates (two sec-sec and two prim-sec) were prepared and their radical-promoted O-S rearrangement reaction was examined. The results revealed that the reaction in six-membered rings is difficult compared with the simple rearrangement in five-membered rings. In the course of syntheses of the substrates, interesting acyl migration during the stannylation process occurred.