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301.
Shun Miyano 《Journal of Molecular Spectroscopy》2011,265(1):47-51
Mid-infrared absorption spectroscopy was applied to the detection of the hydroperoxyl radical (HO2) in pulsed laser photolysis combined with a laser absorption kinetics reactor. The transition of the ν3 vibrational band assigned to the O-O stretch mode around 1065 cm−1 was probed with a thermoelectrically cooled, continuous wave, mid-infrared, distributed feedback quantum cascade laser (QCL). The HO2 was generated through 355 nm photolysis of Cl2/1,4-c-C6H8/O2 mixtures. The mid-infrared absorption spectrum of the HO2 radical was recorded between 1064 and 1065.5 cm−1. The absorption line shapes were well represented by the Voigt profile. The nitrogen-broadening coefficients of the HO2 radical at 295 K were determined for four absorption lines around 1065 cm−1. Mid-infrared absorption detection using a QCL as a spectroscopic light source is a powerful method in spectroscopic and kinetics studies of the HO2 radical. 相似文献
302.
Nakai H Uemura S Miyano Y Mizuno M Irie M Isobe K 《Dalton transactions (Cambridge, England : 2003)》2011,40(10):2177-2179
A photoreactive rhodium dithionite complex [(RhCp(Et))(2)(μ-CH(2))(2)(μ-O(2)SSO(2))] (1(Et)) with Cp(Et) (η(5)-C(5)Me(4)Et) ligands was newly synthesized. Upon short-time irradiation with low intensity light, two kinds of stepwise surface morphology changes of the crystal 1(Et) were observed. Prolonged irradiation with high intensity light caused cracking and breaking down of the crystal. 相似文献
303.
The title C, O -dialkylated resorcinols have seldom been prepared. We have developed a practical synthesis of this class of compounds starting with cyclohexane-1,3-dione. The key features of the synthesis are mono-O-alkylation of a 2-alkyl cyclohexane-1,3-dione and Pd-C catalyzed or NBS/DBU annuitization of the resultant O-alkyl-2-alkyl cyclohexane-1,3-dione. The use of cyclohexane-1,3-dione allows regioselective alkylations that would not be possible with resorcinol itself. A convenient synthesis of 2-alkyl resorcinols from cyclohexane-1,3-dione has also been achieved. 相似文献
304.
Nagao D Goto K Ishii H Konno M 《Langmuir : the ACS journal of surfaces and colloids》2011,27(21):13302-13307
A novel method is proposed to create asymmetrically nanoparticle-supported, monodisperse composite dumbbells. The method consists of the three steps of double soap-free emulsion polymerizations before and after a heterocoagulation. In the first step, soap-free emulsion polymerization was conducted to cover silica cores with cross-linked poly(methyl methacrylate) (PMMA) shells. Then, positively or negatively charged silica nanoparticles were heterocoagulated with the silica-PMMA core-shell particles. In the heterocoagulations, the nanoparticles surface-modified with a cationic silane coupling agent, 3-aminopropyltriethoxysilane, were used as the positively charged ones, and silica nanoparticles without any treatment were used as the negatively charged ones. In the third step, soap-free polymerizations at different pH values were performed to protrude a polystyrene (PSt) bulge from the core-shell particles supporting the charged silica nanoparticles. In the polymerization, the core-shell particles heterocoagulated with the positively charged silica nanoparticles were aggregated in an acidic condition whereas the silica nanoparticles supported on the core-shell particles were dissolved in a basic condition. For the negatively charged silica nanoparticle, a PSt bulge was successfully protruded from the core-shell particle in acidic and neutral conditions without aggregation of the core-shell particles. The protrusion of the PSt bulge became distinctive when the number of heterocoagulated silica nanoparticles per core-shell particle was increased. Additional heterocoagulation experiments, in which positively or negatively charged magnetite nanoparticles were mixed with the asymmetrically nanoparticle-supported composite dumbbells, confirmed direct exposure of silica nanoparticles to the outer solvent phase. 相似文献
305.
Shiro Kubuki Hiroshi Sakka Kanako Tsuge Zoltán Homonnay Katalin Sinkó Ernő Kuzmann Hiroki Yasumitsu Tetsuaki Nishida 《Hyperfine Interactions》2008,185(1-3):115-121
Local structure and thermal durability of semiconducting xBaO·(90?? x)V2O5 · 10Fe2O3 glasses (x = 20, 30 and 40), NTA glass TM, before and after isothermal annealing were investigated by 57Fe-Mössbauer spectroscopy and differential thermal analysis (DTA). An identical isomer shift ( $\mathit{\delta}$ ) of 0.39 ± 0.01 mm s???1 and a systematic increase in the quadrupole splitting (Δ) were observed from 0.70 ± 0.02 to 0.80 ± 0.02 mm s???1 with an increasing BaO content, showing an increase in the local distortion of FeIIIO4 tetrahedra. From the slope of the straight line in the T g–Δ plot of NTA glass TM, it proved that FeIII plays a role of network former. Large Debye temperature (Θ D) values of 1000 and 486 K were respectively obtained for 20BaO · 70V2O5 · 10Fe2O3 glass before and after isothermal annealing at 400°C for 60 min, respectively. This result also suggests that FeIII atoms constitute the glass network composed of tetrahedral FeO4, tetrahedral VO4 and pyramidal VO5 units. The electric conductivity of 20BaO · 70V2O5 · 10Fe2O3 glass increased from 1.6 × 10???5 to 5.8 × 10???2 S cm???1 after isothermal annealing at 450°C for 2,000 min. These results suggest that the drastic increase in the electric conductivity caused by heat treatment is closely related to the structural relaxation of the glass network structure. 相似文献
306.
Matsui F Matsushita T Kato Y Hashimoto M Inaji K Guo FZ Daimon H 《Physical review letters》2008,100(20):207201
Up until now there has been no direct method for detecting the electronic and magnetic structure of each atomic layer at the surface, which is an essential analysis technique for nanotechnology. For this purpose, we have developed a new method, diffraction spectroscopy, based on the photon energy dependence of the angular distribution of Auger electron emission. We have applied this method to analyze the magnetic structure of a Ni ultrathin film on a Cu(001) surface around the spin reorientation transition. Atomic-layer resolved x-ray absorption and magnetic circular dichroism spectra were obtained. Surface and interior core-level shifts and magnetic moments are determined for each atomic layer individually. 相似文献