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91.
Choji Kashima Akira Katoh Yuko Yokota Yoshimari Omote 《Journal of heterocyclic chemistry》1981,18(7):1469-1470
1,4,6-Trisubstituted 3,6-dihydro-2-(1H)pyrimidinones (Ia-d) easily underwent the ring opening reaction with hydroxylamine hydrochloride to afford the oximes (IIa-d) in good yields. In the case of 3,6-dihydro-6-methyl-I-phenyl-2-(1H)pyrimidinone (Ie), 2-anilinobutyronitrile (III) was obtained in addition to the oxime (IIe). Dihydro-2-(1H)pyrimidinone (IV) and -thiones (V and VI) did not undergo the ring opening reaction. 相似文献
92.
93.
Size, shape, and density‐controlled metal nanostructure, Au nanodot lattices fabricated by electron beam lithography, were embedded in thin organic solar cell consisting of PC71BM:PCPDTBT. The effects of their size and density on device performance were examined. Even though dipole res‐onances of Au nanodots were consistent with the absorption range of the active materials, there were no improvements in device performance under any sizes and densities. In addition, under high volume density of Au nanodots to PEDOT:PSS layer, the device performance was deteriorated. These results indicated that not only size and density but also other factors which determine light scattering characteristics greatly affect the device performance of solar cells. (© 2015 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim) 相似文献
94.
Yoshifumi Ota Akiko Higurashi Tatsuya Yokota 《Journal of Quantitative Spectroscopy & Radiative Transfer》2010,111(6):878-894
A vector radiative transfer model has been developed for a coupled atmosphere-ocean system. The radiative transfer scheme is based on the discrete ordinate and matrix operator methods. The reflection/transmission matrices and source vectors are obtained for each atmospheric or oceanic layer through the discrete ordinate solution. The vertically inhomogeneous system is constructed using the matrix operator method, which combines the radiative interaction between the layers. This radiative transfer scheme is flexible for a vertically inhomogeneous system including the oceanic layers as well as the ocean surface. Compared with the benchmark results, the computational error attributable to the radiative transfer scheme has been less than 0.1% in the case of eight discrete ordinate directions. Furthermore, increasing the number of discrete ordinate directions has produced computations with higher accuracy. Based on our radiative transfer scheme, simulations of sun glint radiation have been presented for wavelengths of 670 nm and 1.6 μm. Results of simulations have shown reasonable characteristics of the sun glint radiation such as the strongly peaked, but slightly smoothed radiation by the rough ocean surface and depolarization through multiple scattering by the aerosol-loaded atmosphere. The radiative transfer scheme of this paper has been implemented to the numerical model named Pstar as one of the OpenCLASTR/STAR radiative transfer code systems, which are widely applied to many radiative transfer problems, including the polarization effect. 相似文献
95.
Okamoto Y Yokota M Kawazoe S Kubota H Nagaoka H Arakida Y Takeuchi M 《Chemical & pharmaceutical bulletin》2006,54(5):603-610
To discover an orally active thromboxane A(2) (TXA(2)) and leukotriene D(4) (LTD(4)) dual antagonist, we designed and synthesized chloroquinolylvinyl derivatives based on the structures of the TXA(2) antagonist daltroban and the LTD(4) antagonist montelukast. Among these derivatives, 4-{[(2-(4-chlorophenylsulfonylamino)-1-{3-[(E)-2-(7-chloro-2-quinolyl)vinyl]phenyl}ethyl)thio]methyl}benzoic acid (18d) showed potent inhibitory activity against U46619-induced aggregation of guinea pig platelets and LTD(4)-induced contraction in the guinea pig ileum, with IC(50) values of 340 nm and 0.40 nm, respectively. Oral administration of 18 d also inhibited both the LTD(4)-induced acceleration of plasma leakage to skin in guinea pig and the U46619-induced increase in airway resistance in guinea pig with ED(50) values of 0.47 mg/kg and 3.3 mg/kg, respectively. 相似文献
96.
The reaction of internal alkynes 1 with CO and pyridin-2-ylmethanol (2) in the presence of Rh(4)(CO)(12) results in a double-hydroesterification leading to 1,4-dicarboxylate esters 3. The reaction does not proceed via two consecutive hydroesterifications of alkynes, but the intermediacy of ketene intermediates is proposed. The coordination of the pyridine nitrogen in 2 to rhodium is essential for the reaction to proceed. [reaction: see text] 相似文献
97.
Sachiko Ishida Takashi Ono Tomomi Yokota 《Mathematical Methods in the Applied Sciences》2013,36(7):745-760
This paper deals with the quasilinear ‘degenerate’ Keller–Segel system of parabolic–parabolic type under the super‐critical condition. In the ‘non‐degenerate’ case, Winkler (Math. Methods Appl. Sci. 2010; 33:12–24) constructed the initial data such that the solution blows up in either finite or infinite time. However, the blow‐up under the super‐critical condition is left as an open question in the ‘degenerate’ case. In this paper, we try to give an answer to the question under assuming the existence of local solutions. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
98.
We developed capillary zone electrophoresis with transient isotachophoresis (ITP) as an on-line concentration procedure for simultaneous determination of iodide and iodate in seawater. The effective mobility of iodide was decreased by addition of 20 mM cetyltrimethylammonium chloride to an artificial seawater background electrolyte so that transient ITP functioned for both iodide and iodate. Limits of detection for iodide and iodate were 4.0 and 5.0 microg/l (as iodine) at a signal-to-noise ratio of 3. Values of the relative standard deviation of peak area, peak height, and migration times for iodide and iodate were 2.9, 1.3, 1.0 and 2.3, 2.1, 1.0%, respectively. The proposed method was applied to simultaneous determination of iodide and iodate in seawater collected at a pond at our university. 相似文献
99.
100.
Charmonium ( \({c \bar{c}}\) ) bound states in few-nucleon systems, 2H, 4He and 8Be, are studied via Gaussian Expansion Method (GEM). We adopt a Gaussian potential as an effective \({(c \bar{c})}\) –nucleon (N) interaction. The relation between two-body \({(c \bar{c})}\) –N scattering length \({a_{c\bar{c}-N}}\) and the binding energies B of \({(c \bar{c})}\) –nucleus bound states are given. Recent lattice QCD data of \({a_{c\bar{c}-N}}\) corresponds to \({B \simeq 0.5}\) MeV for \({(c \bar{c})-^{4}}\) He and 2 MeV for \({(c \bar{c})-^{8}}\) Be in our results. 相似文献