Various efforts are currently undertaken to raise the relatively low Curie temperature of the otherwise promising Nd?Fe?B type permanent magnet material. The substitution of Fe by several elements was found to increaseTc, which, on the other hand, can be accompanied by a reduction of the magnetocrystalline anistropy. In the present paper a systematic Mössbauer study was carried out, using Co, Ni, Al, Si and Ga as substituents. The specific influence of each element upon the magnetic properties is attributed to its preference for entering a certain Fe lattice site. Simple atomic size considerations are proved to be insufficient for explaining the preferred occupation observed experimentally. Obviously the local electronic structure has to be studied more carefully. Finally, the interplay between magnetism and metallurgy (particularly the formation of precipitations), is found to be of some importance. 相似文献
Abtract Experiments were performed for individual realizations of the vortex shedding process behind a circular disk at Reynolds
numbers of 103–105, at which periodic vortex shedding prevails in the wake. The phase differences regarding the individual vortex shedding structures
detected at multiple circumferential locations in the wake were obtained by analyzing the hot-wire signals with a conditional-sampling
scheme. The phase differences of vortex shedding detected at circumferential positions 90° apart show a wide scatter, but
the anti-phase character is largely preserved in the individual vortex shedding process as detected at circumferential locations
180° apart. The randomness of phase differences involved in the vortex shedding process is noted to be essential in order
to satisfy the axisymmetric property of the global flow.
Received: 4 April 19969/Accepted: 29 January 1997 相似文献
This study examines the influence of textile substrates upon the behavior of wearable screen‐printed electrodes and demonstrates the attractive sensing properties of these sensors towards the detection of nitroaromatic explosives. Compared to electrodes printed on common cotton or polyester substrates, GORE‐TEX‐based electrochemical sensors display reproducible background cyclic voltammograms, reflecting the excellent water‐repellant properties of the GORE‐TEX fabric. The wetting properties of different printed textile electrodes are elucidated using contact angle measurements. The influence of laundry washing and mechanical stress is explored. The GORE‐TEX‐based printed electrodes exhibit favorable detection of 2,4‐dinitrotoluene (DNT) and 2,4,6‐trinitrotoluene (TNT) explosives, including rapid detection of DNT vapor. 相似文献
Mass spectrometry (MS) is a powerful technique for protein identification in proteomic research. Two-dimensional gel electrophoresis (2-DE) combined with MS is a significant method for protein separation and identification. For protein identification, peptide sequencing is usually carried out by an effective but expensive nano-flow liquid chromatographic system combined to tandem mass spectrometry (MS/MS). However, protein identification based on such method is time-consuming, and contamination may occur as a result of column overloading. In this study, we establish an alternative nanoscale system for protein identification using MS/MS. The system consists of several devices that can be purchased from commercial sources and can be connected to an electrospray ionization quadrupole-time of flight (ESI-Q-TOF) MS in order to analyze proteins from 2D gels. This inexpensive strategy provides an attractive alternative method for rapid identification of proteins using a nanospray source. In addition, the device is disposable so that contamination is avoided. It is shown that peptide sequencing based on this device using ESI-Q-TOF MS is accomplished within 10 min. 相似文献
Two new compounds, including petasinoside A and chloridate-[N-chloromethyl-hectorine], were isolated from Senecio nemorensis. The structures of these compounds were elucidated by spectroscopic methods including 1D and 2D NMR experiments. 相似文献
A novel PEGylated biodegradable hyperbranched PEG‐b‐PDMAEMA has been synthesized. The low toxicity, small molecular weight PDMAEMA chains were crosslinked using a biodegradable disulfide‐based dimethacrylate (DSDMA) agent to yield higher molecular weight hyperbranched polymers. PEG chains were linked onto the polymer surface, masking the positive charge (as shown by Zeta potential measurements) and reducing the toxicity of the polymer. The hyperbranched structures were also cleaved under reducing conditions and analyzed, confirming the expected component structures. The hyperbranched polymer was mixed with DNA and efficient binding was shown to occur through electrostatic interactions. The hyperbranched structures could be reduced easily, generating lower toxicity oligomer chains.
A 32 in RGB LED backlight unit is developed. A local dimming algorithm is designed for the backlight, and grid-noise artifacts in the LC driving signal are successfully removed with consideration of the backlight distribution to provide identical intensity from each LED block. The 32 in RGB LED backlight LCD display has achieved a static display contrast of over 20000:1 and an average power reduction of 30%. We have also obtained the color gamut transformation matrix for transferring a cold cathode fluorescent lamp BLU LCD display gamut system to our RGB LED BLU LCD display gamut system, and extended the color saturation by suppositional color expansion method. As a result, the color has been accurately reproduced in RGB LED BLU LCD display with more richness and more saturation. 相似文献