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Russian Chemical Bulletin - 相似文献
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| 1. | Syntheses were reported for 1,2-disubstituted silylcyclopropanes by the reductive cyclization of RCCl2CH2CHClSiMe3 compounds. |
| 2. | The cyclization upon the reduction of ClCH2CH2CCl2CH2CHClSiMe3 using metallic zinc proceeds with involvement of both the CH2C1 and CHC1 groups. The product ratio depends significantly on the solvent. |
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S. V. Safronov A. M. Sheloumov A. Z. Kreindlin A. A. Kamyshova F. M. Dolgushin A. F. Smolyakov P. V. Petrovskii M. G. Ezernitskaya A. A. Koridze 《Russian Chemical Bulletin》2010,59(9):1740-1744
The first ruthenocene- and pentamethylruthenocene-based ruthenium pincer complexes, RuCl(CO)[{2,5-(But
2PCH2)2C5H2}Ru(C5H5)] and RuCl(CO)[{2,5-(But
2PCH2)2C5H2}Ru-(C5Me5)], were synthesized by cyclometallation of {1,3-(But
2PCH2)2C5H2}Ru(C5H5) and {1,3-(But
2PCH2)2C5H2}Ru(C5Me5), respectively, with RuCl2(DMSO)4 in 2-methoxyethanol and characterized by 1H and 31P{1H} NMR spectroscopy, and X-ray diffraction. 相似文献
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