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11.
通过简单的一锅两步法制备了三氟金属(铝,钛,锆)接枝介孔SBA-15 (AlTf/S,TiTf/S,ZrTf/S)固体酸材料,并通过XRD,N2吸附,TGA,FTIR,原位吡啶FTIR和元素分析对这些材料进行了详细的表征.其中,ZrTf/S能够高效催化环氧化物温和条件下被胺或醇开环生成对应β-氨基醇或β-烷氧基醇,并且催化剂能循环利用.ZrTf/S相较于AlTf/S和TiTf/S酸性最强,因而催化活性也最高. 相似文献
12.
Singh P Kumar P Kumari K Sharma P Mozumdar S Chandra R 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2011,78(2):909-912
In the present work, we report a novel method for the synthesis of palladium and lead nanoparticles by the reduction method in tetrazolium ring based ionic liquid. Palladium and lead nanoparticles so-prepared were well characterized by powder X-ray diffraction measurements (pXRD), transmission electron microscopy (TEM) and quasi elastic light scattering (QELS) techniques. Powder X-ray diffraction (pXRD) analysis revealed all relevant Bragg's reflection for crystal structure of palladium and lead. Powder X-ray diffraction plots also revealed no oxidized material of palladium and lead nanoparticles. TEM showed nearly uniform distribution of the particles in methanol and confirmed by QELS. Typical applications of palladium nanoparticles include in vitro use and sensor design applications. Palladium nanoparticles is also ideal for spin coating, self-assembly and monolayer formation. Palladium nanoparticles can also be considered as potential new catalysts. 相似文献
13.
This paper discusses a class of nonlinear knapsack problems where the objective function is quadratic. The method is a branch and search procedure which includes an efficient algorithm to find the continuous (relaxed) solution and a reduction rule which computes tight lower and upper bounds on the integer variables. 相似文献
14.
Madhusudanan KP Kumar B Tiwari P Madhusudan SK Misra AK 《Journal of mass spectrometry : JMS》2005,40(1):25-35
The effect of metal cationization on the tandem mass spectra of glycosyl dithioacetals of glucose, mannose, galactose, rhamnose, arabinose and xylose was studied by electrospray ionization mass spectrometry under ammonium and metal (Li, Na, Ag and Cu) ion cationization conditions. The ammonium-cationized glycosyl dithioacetals fragment by loss of ammonia followed by either two molecules of EtSH or one molecule of EtSH and one molecule of H2O. Lithium cationization leads to additional eliminations such as EtSEt and EtSSEt and C-C cleavages. Elimination of EtSH is not observed under sodium cationization. Silver cationization, on the other hand, leads to additional fragmentations involving the elimination of silver as AgOH and AgSEt. Copper cationization results in adducts where copper has undergone a change of oxidation state from II to I. Li+, Ag+ and Cu+ cationization seem to favour cyclization resulting in elimination of EtSH. However, the mechanisms seem to be differently affected by different metal ions. Li+ and Ag+ cationization appear to be non-specific and favour cyclization involving C2-, C4- and C5-hydroxyl hydrogens, whereas Cu+ cationization seems to favour cyclization involving C4-hydroxyl hydrogen. 相似文献
15.
16.
Kamlesh Parwani 《Topology and its Applications》2006,153(18):3413-3419
Let S be a compact, oriented surface with negative Euler characteristic and let be a homeomorphism isotopic to the identity. If there exists a periodic orbit with a non-zero rotation vector , then there exists a simple braid with the same rotation vector. 相似文献
17.
Kamlesh Pandey Mrigank Mauli Dwivedi Mridula Tripathi Markandey Singh S. L. Agrawal 《Ionics》2008,14(6):515-523
Development and characterisation of polyethylene oxide (PEO)-based nanocomposite polymer electrolytes comprising of (PEO-SiO2): NH4SCN is reported. For synthesis of the said electrolyte, polyethylene oxide has been taken as polymer host and NH4SCN as an ionic charge supplier. Sol–gel-derived silica powder of nano dimension has been used as ceramic filler for development
of nanocomposite electrolytes. The maximum conductivity of electrolyte ∼2.0 × 10−6 S/cm is observed for samples containing 30 wt.% silica. The temperature dependence of conductivity seems to follow an Arrhenius-type,
thermally activated process over a limited temperature range. 相似文献
18.
A facile method for the synthesis of silver-silica(Ag-SiO2) Janus particles with functionalities suitable for textile applications is reported.Silica nanoparticles prepared by the Stober method were functionalized with epoxy,amine,and thiol groups,which were confirmed by Fourier transform infrared analysis.The functionalized silica nanoparticles were used to produce Pickering emulsions,and the exposed surface was used for the attachment of silver nanoparticles(AgNPs) via the low-temperature chemical reduction method.The morphology and structure of the Ag-SiO2 Janus particles were characterized by scanning electron microscopy,scanning transmission electron microscopy,high-resolution transmission electron microscopy,energy-dispersive X-ray analysis,and UV-vis spectroscopy.Because of their specific functionalities,these Ag-SiO2 Janus particles are proposed for applications on textile substrates,as they can overcome several drawbacks of direct application of AgNPs on textiles,such as leaching,agglomeration,and instability during storage. 相似文献
19.
Dr. Samarthya Bhagia Dr. Kamlesh Bornani Dr. Soydan Ozcan Dr. Arthur J. Ragauskas 《ChemistryOpen》2021,10(8):830-841
There is a need for high-performance applications for terephthalic acid (TPA) polyesters with high heat resistance, impact toughness, and optical clarity. Bisphenol A (BPA) based polycarbonates and polyarylates have such properties, but BPA is an endocrine disruptor. Therefore, new TPA polyesters that are less hazardous to health and the environment are becoming popular. Tetramethylcyclobutanediol (TMCD) is a difunctional monomer that can be polymerized with TPA and other diols to yield copolyesters with superior properties to conventional TPA polyesters. It has a cyclobutyl ring that makes it more rigid than cyclohexanedimethanol (CHDM) and EG. Thus, TMCD containing TPA copolyesters can have high heat resistance and impact strength. TPA can be made from abundantly available upcycled polyethylene terephthalate (PET). Therefore, this review discusses the synthesis of monomers and copolyesters, the impact of diol composition on material properties, molecular weight, effects of photodegradation, health safety, and substitution of cyclobutane diols for future polyesters. 相似文献
20.
Balinge Kamlesh Rudreshwar Khiratkar Avinash Ganesh Muskawar Prashant Narayan Thenmozhi K. Bhagat Pundlik Rambhau 《Research on Chemical Intermediates》2018,44(3):2075-2097
Research on Chemical Intermediates - The synthesis of polymer supported zinc–salen complex (PS-Zn–salen) is described. The mononuclear zinc(II)–salen complex was characterized by... 相似文献