Synthesis of the Benzoate Intercalated Layered Double ­Hydroxide of Nickel and Aluminum: Application of Mering's Rule

Homogeneous precipitation from a mixed metal nitrate solution using benzamide as a hydrolysis agent results in the formation of a benzoate‐intercalated layered double hydroxide of nickel and aluminum with a basal spacing of 15.6 Å. The alternation in the line widths of the basal reflections has been shown to arise by the random interstratification of a 8.8 Å phase with an altered orientation of the benzoate ions. This work is an illustration of the application of Mering's rules to model disorder in layered double hydroxides.     

Second-Order Nonlinear Optical Properties of a Polymer Exhibiting Optical Transparency Down to 340 nm

Abstract

The synthesis and characterization of an epoxy-based nonlinear optical (NLO) polymer exhibiting optical transparency down to 340 nm is reported. The synthesized polymers show spectroscopic properties (NMR, IR, UV) in accordance with the proposed structures. A glass transition temperature (T_g) of 92°C and a thermal degradation temperature (T_d) of 322°C were recorded. The poled polymer film exhibits stable second-order nonlinear optical activity (d₃₃ = 4.2 pm/V) over a period of 800 hours as characterized by the temporal response of the second harmonic signal at room temperature.     

Effect of Nanoscale Confinement on Freezing of Modified Water at Room Temperature and Ambient Pressure

Understanding the phase behavior of confined water is central to fields as diverse as heterogeneous catalysis, corrosion, nanofluidics, and to emerging energy technologies. Altering the state points (temperature, pressure, etc.) or introduction of a foreign surface can result in the phase transformation of water. At room temperature, ice nucleation is a very rare event and extremely high pressures in the GPa–TPa range are required to freeze water. Here, we perform computer experiments to artificially alter the balance between electrostatic and dispersion interactions between water molecules, and demonstrate nucleation and growth of ice at room temperature in a nanoconfined environment. Local perturbations in dispersive and electrostatic interactions near the surface are shown to provide the seed for nucleation (nucleation sites), which lead to room temperature liquid–solid phase transition of confined water. Crystallization of water occurs over several tens of nanometers and is shown to be independent of the nature of the substrate (hydrophilic oxide vs. hydrophobic graphene and crystalline oxide vs. amorphous diamond‐like carbon). Our results lead us to hypothesize that the freezing transition of confined water can be controlled by tuning the relative dispersive and electrostatic interaction.     

Limited proteolysis of human histone deacetylase 1

Background  

Histone deacetylase (HDAC) proteins are associated with cell proliferation, differentiation, apoptosis, and cancer. Specifically, HDAC1 is linked with cell growth, a hallmark of cancer formation. HDAC1 is a phosphoprotein and phosphorylation at S421 and S423 promotes HDAC1 enzymatic activity and protein association. While single and double point mutants of HDAC1 at S421 and S423 appear functionally similar, the evidence suggests that HDAC1 is phosphorylated simultaneously at both S421 and S423 in vivo. Additional experiments are necessary to probe the role of double phosphorylation of HDAC1 at S421 and S423.     

The energy—momentum tensor, the trace identity and the Casimir effect

The trace identity associated with the scale transformation x^Μ → x′^Μ = e^-ρx^Μ on the Lagrangian density for the noninteracting electromagnetic field in the co-variant gauge is shown to be violated on a single plate on which the Dirichlet boundary conditionA ^Μ(t, x¹, x², x³ = -a) = 0 is imposed. It is however respected in free space, i.e. in the absence of the plate. These results reinforce our assertions in an earlier paper where the same exercise was carried out using the Lagrangian density for the free, massive, real scalar field in 2 + 1 dimensions.     

Routing and Admission Control in General Topology Networks with Poisson Arrivals

Emerging high-speed networks will carry traffic for services such as video-on-demand and video teleconferencing that require resource reservation along the path on which the traffic is sent. High bandwidth-delay product of these networks prevents circuit rerouting, i.e., once a circuit is routed on a certain path, the bandwidth taken by this circuit remains unavailable for the duration (holding time) of this circuit. As a result, such networks will need effectiveroutingandadmission controlstrategies. Recently developed on-line routing and admission control strategies have logarithmic competitive ratios with respect to theadmission ratio(the fraction of admitted circuits). Such guarantees on performance are rather weak in the most interesting case where the rejection ratio of the optimum algorithm is very small or even 0. Unfortunately, these guarantees cannot be improved in the context of the considered models, making it impossible to use these models to identify algorithms that are going to perform well in practice. In this paper we develop routing and admission control strategies for a probabilistic model, where the requests for virtual circuits between any two points arrive according to a Poisson process and where the circuit holding times are exponentially distributed. Our model is close to the one that was developed to analyze and tune the (currently used) strategies for managing traffic in long-distance telephone networks. We strengthen this model by assuming that the rates of the Poisson processes (the “traffic matrix”) are unknown to the algorithm and are chosen by the adversary. Our strategy is competitive with respect to the expectedrejection ratio. More precisely, it achieves an expected rejection ratio of at mostR* + ?, whereR* is the optimum expected rejection ratio. The expectations are taken over the distribution of the request sequences, and, whereris the maximum fraction of an edge bandwidth that can be requested by a single circuit. Our result should be viewed in the context of the previous competitive routing and admission control strategies that requirer ≤ 1/log n, but are not able to formally analyze the (intuitively clear) relation betweenrand the performance achievable in realistic situations.     

Projection methods for the numerical solution of non-self-adjoint elliptic partial differential equations

We compare the relative performances of two iterative schemes based on projection techniques for the solution of large sparse nonsymmetric systems of linear equations, encountered in the numerical solution of partial differential equations. The Block–Symmetric Successive Over-Relaxation (Block-SSOR) method and the Symmetric–Kaczmarz method are derived from the simplest of projection methods, that is, the Kaczmarz method. These methods are then accelerated using the conjugate gradient method, in order to improve their convergence. We study their behavior on various test problems and comment on the conditions under which one method would be better than the other. We show that while the conjugate-gradient-accelerated Block-SSOR method is more amenable to implementation on vector and parallel computers, the conjugate-gradient accelerated Symmetric–Kaczmarz method provides a viable alternative for use on a scalar machine.     

Electrochemical synthesis of ZnO coatings from water–isopropanol mixed baths: control over oriented crystallization

Electroreduction of an aqueous solution of a soluble Zn salt results in the deposition of ZnO crystallites with hexagonal columnar morphology. The crystallites grow with their long axes normal to the substrate resulting in adherent coatings with a strong c-axis orientation. This phenomenon is on account of the polarity of the 001 crystal face combined with the high dielectric constant of water. When the dielectric constant of the solvent is changed by making a mixture of water and isopropanol, there is a change in the direction of orientation of the coating. The switch takes place in the sequence [001] → [102], [103] → unoriented → [100], [110] as the isopropanol concentration is raised in a step-wise manner to 60% (v/v). The switch in orientation is caused by the tilt of the long axes of the hexagonal columns of ZnO with respect to the normal to the substrate. Above 60% isopropanol concentration, ZnO deposition is suppressed. This work demonstrates solution-mediated control over oriented crystallization.     

Analysis of the allergenic proteins in black tiger prawn (Penaeus monodon) and characterization of the major allergen tropomyosin using mass spectrometry

Crustaceans are the third most prevalent cause of food‐induced anaphylaxis after peanuts and tree nuts. The severity of the allergenic proteins depends mainly on the amino acid sequence that induces production of IgE antibodies. In black tiger prawn (Penaeus monodon), the crude protein extract was profiled and its allergenic potency was examined against patient's sera. Proteins having strong immunoreactivity with patient's IgE were characterized using peptide mass fingerprinting (PMF). Tropomyosin (TM) (33 kDa), myosin light chain (20 kDa), and arginine kinase (40 kDa) were identified as allergenic proteins. Tropomyosin, the most abundant and potent allergen, was purified using ion‐exchange chromatography for de novo sequencing experiments. Using bottom up tandem mass spectrometry, the full amino acid sequence was achieved by a combination of matrix‐assisted laser desorption/ionization (MALDI) and electrospray ionization (ESI) tandem mass spectrometry (QqToF). Myosin light chain and arginine kinase were also characterized, and their related peptides were de novo sequenced using the same approach. The immunological reactivity of the crude prawn extracts and purified TM samples were analyzed using a large number of patients' sera. A signature peptide was assigned for the TM protein for future quantification work of black tiger prawn TM levels in different matrices (i.e. water, air, food) in the seafood industry. Copyright © 2010 John Wiley & Sons, Ltd.     

Polytype Transformations in the SO42– Containing Layered Double Hydroxides of Zinc with Aluminum and Chromium: The Metal Hydroxide Layer as a Structural Synthon

Solid–solid inter‐polytype transformations are observed during the thermal dehydration of sulfate‐containing layered double hydroxides (LDHs). The metal hydroxide layer behaves as a “structural synthon” and the interconversion of polytypes of rhombohedral and hexagonal symmetries takes place by rigid translations of successive layers by (± 1/3, ± 2/3) relative to one another in the ab plane. These translations are selected among the many possible, as they preserve the coincidence of the symmetry elements of the individual layers and thereby conserve the threefold symmetry of the crystal across the inter‐polytype conversions. As a result, these transformations are enthalpically not expensive. These translations are facilitated at near ambient temperatures (30–60 °C) by the reversible dehydration of the LDH, which involves the deinsertion/insertion of water molecules within the restricted space of the interlayer region.