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11.
Abe K Abe K Abe R Adachi I Ahn BS Aihara H Akatsu M Alimonti G Asai K Asai M Asano Y Aso T Aulchenko V Aushev T Bakich AM Banas E Behari S Behera PK Beiline D Bondar A Bozek A Browder TE Casey BC Chang P Chao Y Chen KF Cheon BG Chistov R Choi SK Choi Y Dong LY Dragic J Drutskoy A Eidelman S Eiges V Enari Y Enomoto R Everton CW Fang F Fujii H Fukunaga C Fukushima M Gabyshev N Garmash A Gershon TJ Gordon A Gotow K Guler H Guo R Haba J Hamasaki H Hanagaki K Handa F Hara K Hara T Hastings NC 《Physical review letters》2001,87(9):091802
We present a measurement of the standard model CP violation parameter sin2 phi(1) based on a 29.1 fb(-1) data sample collected at the Upsilon(4S) resonance with the Belle detector at the KEKB asymmetric-energy e(+)e(-) collider. One neutral B meson is fully reconstructed as a J/psi K(S), psi(2S)K(S), chi(c1)K(S), eta(c)K(S), J/psi K(L), or J/psi K(*0) decay and the flavor of the accompanying B meson is identified from its decay products. From the asymmetry in the distribution of the time intervals between the two B meson decay points, we determine sin2 phi(1) = 0.99+/-0.14(stat)+/-0.06(syst). We conclude that we have observed CP violation in the neutral B meson system. 相似文献
12.
13.
Samir Kumar Sarkar Meenakshi Pegu Santosh Kumar Behera Siva Krishna Narra Pakkirisamy Thilagar 《化学:亚洲杂志》2019,14(24):4588-4593
Typically, molecules with a twisted donor–acceptor (D‐A) architecture have been exploited for constructing thermally activated delayed fluorescence (TADF) materials. Herein, we report the first example of a thiophene‐based thermally activated delayed fluorescent molecule without a D‐A architecture. Compound 1 (2,5‐bis(2,2‐di(thiophen‐2‐yl)vinyl)thiophene) is conformationally flexible and shows weak fluorescence in the solution state but displays bright TADFin both condensed and solid states. Compound 1 crystallized in two different polymorphs ( 1 a and 1 b ). Interestingly, both polymorphs show distinctly different TADF features. The broad spectral features and the TADF characteristics of 1 have been explored for the time‐dependent multicolor (green, yellow and red) imaging of living cells. 相似文献
14.
Samir Kumar Sarkar Meenakshi Pegu Santosh Kumar Behera Siva Krishna Narra Pakkirisamy Thilagar 《化学:亚洲杂志》2019,14(24):4431-4431
15.
We put forth a dynamic computing framework for scale‐selective adaptation of weighted essential nonoscillatory (WENO) schemes for the simulation of hyperbolic conservation laws exhibiting strong discontinuities. A multilevel wavelet‐based multiresolution procedure, embedded in a conservative finite volume formulation, is used for a twofold purpose. (i) a dynamic grid adaptation of the solution field for redistributing grid points optimally (in some sense) according to the underlying flow structures, and (ii) a dynamic minimization of the in built artificial dissipation of WENO schemes. Taking advantage of the structure detection properties of this multiresolution algorithm, the nonlinear weights of the conventional WENO implementation are selectively modified to ensure lower dissipation in smoother areas. This modification is implemented through a linear transition from the fifth‐order upwind stencil at the coarsest regions of the adaptive grid to a fully nonlinear fifth‐order WENO scheme at areas of high irregularity. Therefore, our computing algorithm consists of a dynamic grid adaptation strategy, a scale‐selective state reconstruction, a conservative flux calculation, and a total variation diminishing Runge‐Kutta scheme for time advancement. Results are presented for canonical examples drawn from the inviscid Burgers, shallow water, Euler, and magnetohydrodynamic equations. Our findings represent a novel direction for providing a scale‐selective dissipation process without a compromise on shock capturing behavior for conservation laws, which would be a strong contender for dynamic implicit large eddy simulation approaches. 相似文献
16.
We address a model study which includes the co-existence of the charge density wave (CDW) and ferromagnetic interactions in order to explain the colossal magnetoresistance (CMR) in manganites. The Hamiltonian consists of the ferromagnetic Hund's rule exchange interaction between eg and t2g spins, Heisenberg core spin interactions and the CDW interaction present in the eg band electrons. The core electron magnetization, induced eg electron magnetization and the CDW gap are calculated using Zubarev's Green's function technique and determined self-consistently. The effect of core electron magnetization and the CDW interaction on the induced magnetization as well as on the occupation number in the different spin states of the eg band electrons are investigated by varying the model parameters of the system like the CDW coupling, the exchange coupling, the Heisenberg coupling and the external field. It is observed that the induced magnetization exhibits re-entrant behaviour and exists within a narrow temperature range just below the Curie temperature. This unusual behaviour of the eg band electrons will throw some new insights on the physical properties of the manganite systems. 相似文献
17.
The ceramic oxide Na2Pb2Gd2W2Ti4Ta4O30 (NPGWT) was synthesized by the solid solution route. The formation of compound was checked by using X-ray diffraction and scanning electron microscope study. It is observed from both the studies that the material is a single phase and highly dense. The preliminary temperature variation of the dielectric study reveals ferroelectric to paraelectric phase transition much above the room temperature. The polarization study of the material further confirms the presence of ferroelectricity in the studied compound. The transport property of the material was carried out by using the impedance spectroscopy technique. From both impedance and modulus analysis, it is confirmed that conduction mechanism in the material is due to the hopping motion of charge carrier. To strengthen the hopping motion of charge carrier in the material frequency dependence, ac conductivity is carried out. 相似文献
18.
Shyam Sundar Mondal Namita Jaiswal Partha Sarathi Bera Ranjay K. Tiwari Jogendra Nath Behera Nripen Chanda Subhas Ghosal Tanmoy Kumar Saha 《应用有机金属化学》2021,35(1)
A series of copper (II) ( 1 and 3 ) and cobalt (II/III) ( 2 , 4 and 5 ) complexes comprising different imino‐phenolate ligands DCH , DTH and DBH 2 (where DCH = 2,4‐dichloro‐6‐((mesitylimino)methyl)phenol, DTH = 2,4‐di‐tert‐butyl‐6‐((mesitylimino)methyl) phenol and DBH 2 = 2,4‐dibromo‐6‐((mesitylimino)methyl)phenol) have been prepared with excellent yield and high purity. By utilizing different spectroscopic tools such as UV–visible, electrospray ionization (ESI)‐mass, Fourier‐transform infrared (FTIR) spectrometry and elemental analysis, the prepared complexes ( 1 – 5 ) were thoroughly characterized. The molecular structure of the synthesized complexes was ascertained by using single‐crystal X‐ray diffraction studies (SCXRDs). The experiment reveals that Complexes 1 – 5 bind to calf thymus DNA (CT‐DNA) through non‐intercalative way with good interacting abilities. However, 1 – 5 are excellent quenchers of the fluorescence intensity of bovine serum albumin (BSA) following the static pathway. Additionally, they had shown remarkable cytotoxic potential against MCF‐7 (mammary gland adenocarcinoma) and A549 (lung adenocarcinoma) cell lines. The IC50 values associated with these complexes were much lower than the conventional drug cisplatin. Apoptosis‐induced cell death was confirmed from the DNA fragmentation studies and Hoechst 33342 staining. The 2′,7′‐dichlorofluorescein diacetate (DCFDA) assay indicates that the complex mediated reactive oxygen species (ROS) generation is accountable for governing the apoptosis mechanism via oxidative cell distress. Apart from these studies, by carrying out density functional theory (DFT) method, highest occupied molecular orbital–lowest unoccupied molecular orbital (HOMO–LUMO) energy gap calculations and optimized structures of the synthesized complexes were accomplished. 相似文献
19.
Generation of a surface-confined redox mediator (RM) by an electrochemically triggered Michael addition reaction and the electrocatalytic properties of the mediator are described. Electrogenerated o-quinone undergoes Michael addition reaction with the self-assembled monolayer (SAM) of 4-thiouracil (4-TU) on a gold (Au) electrode and yields a surface-confined RM, 1-(3,4-dihydroxyphenyl)-4-mercapto-1H-pyrimidin-2-one (DPTU). The Michael addition reaction depends on the electrolysis potential and time, solution pH, and concentration of catechol (CA) used in the reaction. The redox mediator, DPTU, exhibits reversible redox response, characterstic of a surface-confined species at approximately 0.22 V in neutral pH. The anodic peak potential of DPTU shifts by 58+/-2 mV while changing the solution pH by one unit, suggesting that protons and electrons taking part in the redox reaction are in the ratio of 1:1. The apparent rate constant (ksapp) for the heterogeneous electron-transfer reaction of the RM was determined to be 114+/-5 s-1. The surface coverage (Gamma) of DPTU on the electrode surface was 8.2+/-0.1x10(-12) mol/cm2. DPTU shows excellent electrocatalytic activity toward oxidation of reduced nicotinamide adenine dinucleotide (NADH) with activation overpotential, which is approximately 600 mV lower than that observed at the unmodified Au electrode. The dipositive cations in the supporting electrolyte solution amplify the electrocatalytic activity of DPTU. A 2.5-fold enhancement in the catalytic current was observed in the presence of Ca2+ or Ba2+ ions. The sensitivity of the electrode toward NADH in the presence and absence of Ca2+ ions was 0.094+/-0.011 and 0.04+/-0.0071 nA cm-2 nM-1, respectively. A linear increase in the catalytic current was obtained up to the concentration of 0.8 mM, and the electrode can detect amperometrically as low as 25 nM of NADH in neutral pH. 相似文献
20.
Modification of important physicochemical properties of aqueous surfactant solutions can be achieved by addition of environmentally benign room temperature ionic liquids (ILs). While low aqueous solubility of "hydrophobic" ILs limits the amount of IL that may be added to achieve desired changes in the physicochemical properties, hydrophilic ILs do not have such restrictions associated to them. Alterations in the key physicochemical properties of aqueous solutions of a common nonionic surfactant Triton X-100 (TX100) on addition of up to 30 wt % hydrophilic IL 1-butyl-3-methylimidazolium tetrafluoroborate ([bmim][BF4]) are reported. The presence of micellar aggregates in as high as 30 wt % [bmim][BF4]-added aqueous TX100 solutions is established by dynamic light scattering and fluorescence probe behavior. Increasing the concentration of [bmim][BF4] results in decrease in average micellar size and aggregation number and increase in critical micelle concentration, indicating an overall unfavorable aggregation process. Increase in the dipolarity and the microfluidity of the probe cybotactic region within the palisade layer of the micellar phase upon [bmim][BF4] addition implies increased water penetration and the possibility of TX100-[bmim][BF4] interactions. While the changes in some of the physicochemical properties indicate the role of [bmim][BF4] to be similar to a cosurfactant, the IL acts like a cosolvent as far as changes in other properties are concerned. Effectiveness of IL [bmim][BF4] in modifying physicochemical properties of aqueous TX100 is demonstrated. 相似文献