Indirect synthesis of multidegree-of-freedom transient systems

It is shown that an indirect synthesis method can be used in the efficient optimal design of multidegree-of-freedon, multidesignelement, nonlinear, transient systems. The technique begins with a limiting performance analysis which requires linear programming for a kinematically linear system, following which the system is selected using system identification methods such that the designed system responds as closely as possible to the limiting performance. The efficiency is a result of the method avoiding the repetitive systems analyses accompanying other numerical optimization methods.This investigation was supported by the NASA Langley Research Center, Grant No. NGR-47-005-145.     

Nonsymmetric Kaluza-Klein and Jordan-Thiry theory in a general non-Abelian case

This paper is devoted to an (n+4)-dimensional unification of NGT (nonsymmetric gravitation theory) and Yang-Mills theory in a Jordan-Thiry manner. We find interference effects between gravitational and Yang-Mills fields which appear to be due to the skew-symmetric part of the metric on the (n+4)-dimensional manifold (nonsymmetrically metrized principal fiber bundle). Our unification, called the nonsymmetric-non-Abelian Jordan-Thiry theory, becomes classical if the skew-symmetric part of the metric is zero. We find the Yang-Mills field Lagrangian up to the second order of approximation inh =g – . We also deal with the Lagrangian for the scalar field (connected to the gravitational constant). We consider the spin content of the theory and a relationship between the cosmological constant and the coupling constant between the skewon field and the gauge field in the first order of approximation. We show how to derive a dielectric model of a confinement from interference effects in these theories. We underline some similarities between the nonsymmetric Jordan-Thiry Lagrangian in the flat space limit and the soliton bag model Lagrangian.     

Isotopic perturbation of a degenerate valence isomerization. A 13C NMR study of deuterio-1,5-dimethylsemibullvalene

Mono deuterio-1,5-dimethylsemibullvalene is studied by the isotopic perturbation method with respect to the equilibrium of the valence isomerization. It emerges that deuterium prefers the cyclopropane position. From the temperature dependence of the splittings in the ¹³C NMR spectra the ground state enthalpy difference in mono deuterio-1,5-dimethylsemibullvalene is calculated to be 484 J mol^?1.     

Interconversion and preparative separation of enantiomeric enamides

Barriers to rotation about the CN single bond of enamides (Table 1) are rationalised. The barriers of $\text{7}$ and $\text{8}$ allow separations of the enantiomers.     

Polarographic behaviour of phenothiazine

Summary Phenothiazine oxidizes at the dropping mercury electrode in waterethanolic solutions, containing 7 N sulphuric acid, giving a wave corresponding to the formation of free cation radicals.The normal potential of the system phenothiazine/radical, against the reference electrode formed from mercuric sulphate in the presence of 10 N H₂SO₄ and 30% ethanol, is –240±20 mV.In alkaline solutions of pH 12.5 phenothiazine also gives a polarographic wave. This wave corresponds to the insoluble anions of compounds formed with mercury. The conditions for the quantitative polarographic determination of phenothiazine are also given.

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Zusammenfassung Es wurde bewiesen, daß in äthanolisch-wäßrigen Lösungen, die 7 n H₂SO₄ enthalten, Phenothiazin an der Quecksilber-Tropfelektrode oxydiert wird. Als Reaktionsprodukt entsteht ein freies Kation-Radikal. Das Normalpotential des Systems Phenothiazin/Radikal gegen die gesättigte Quecksilbersulfatelektrode, die 10 n H₂SO₄ und 30% C₂H₅OH enthält, beträgt –240 ± 20 mV.In alkalischen Lösungen bei pH 12,5 konnte man eine polarographische Welle registrieren, deren Eigenschaften schwerlöslichen Anionen einer Quecksilberverbindung entsprechen.Die Bedingungen für eine quantitative polarographische Phenothiazinbestimmung werden angegeben.

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Dedicated to Prof. Dr. M. von Stackelberg on his 70th birthday.     

A review of the developments of radioxenon detectors for nuclear explosion monitoring

Journal of Radioanalytical and Nuclear Chemistry - Developments in radioxenon monitoring since the implementation of the International Monitoring System are reviewed with emphasis on the most...     

Spontaneous Symmetry Breaking and Higgs' Mechanism in the Nonsymmetric Jordan-Thiry Theory

In the paper we construct the nonsymmetric Jordan-Thiry theory unifying Moffat's theory of gravitation, the Yang-Mills' field, the Higgs' fields and scalar forces in a geometric manner. We discuss spontaneous symmetry breaking, the Higgs' mechanism and mass generation in the theory. The scalar field Ψ (as in classical Jordan-Thiry theory) is connected to the effective gravitational constant. This field is massive and has Yukawa-type behavior. We discuss the relation between R₊ invariance and U(1)_F from G. U. T. within Einstein λ-transformation, and fermion number conservation. In this way we connect W _μ-field from nonsymmetric theory of gravitation with a gauge field A from G. U. T. We derive the equation of motion for a test particle from conservation laws in the hydrodynamic limit.