全文获取类型
收费全文 | 379篇 |
免费 | 8篇 |
国内免费 | 1篇 |
专业分类
化学 | 237篇 |
晶体学 | 5篇 |
力学 | 16篇 |
数学 | 35篇 |
物理学 | 95篇 |
出版年
2024年 | 7篇 |
2023年 | 1篇 |
2022年 | 6篇 |
2021年 | 6篇 |
2020年 | 11篇 |
2019年 | 18篇 |
2018年 | 10篇 |
2017年 | 20篇 |
2016年 | 18篇 |
2015年 | 17篇 |
2014年 | 14篇 |
2013年 | 32篇 |
2012年 | 30篇 |
2011年 | 29篇 |
2010年 | 16篇 |
2009年 | 17篇 |
2008年 | 24篇 |
2007年 | 17篇 |
2006年 | 17篇 |
2005年 | 11篇 |
2004年 | 12篇 |
2003年 | 9篇 |
2002年 | 6篇 |
2001年 | 1篇 |
2000年 | 1篇 |
1998年 | 1篇 |
1997年 | 3篇 |
1996年 | 1篇 |
1994年 | 2篇 |
1993年 | 2篇 |
1992年 | 2篇 |
1991年 | 3篇 |
1990年 | 1篇 |
1989年 | 2篇 |
1987年 | 3篇 |
1986年 | 1篇 |
1985年 | 2篇 |
1984年 | 3篇 |
1983年 | 2篇 |
1981年 | 4篇 |
1980年 | 1篇 |
1977年 | 2篇 |
1975年 | 1篇 |
1971年 | 1篇 |
1964年 | 1篇 |
排序方式: 共有388条查询结果,搜索用时 0 毫秒
71.
We report a feedback control method to precisely target the number of colloidal particles in quasi-2D ensembles and their subsequent assembly into crystals in a quadrupole electrode. Our approach relies on tracking the number of particles within a quadrupole electrode, which is used in a real-time feedback control algorithm to dynamically actuate competing electrokinetic transport mechanisms. Particles are removed from the quadrupole using DC-field mediated electrophoretic-electroosmotic transport, while high-frequency AC-field mediated dielectrophoretic transport is used to concentrate and assemble colloidal crystals. Our results show successful control of the size of crystals containing 20 to 250 colloidal particles with less than 10% error. Assembled crystals are characterized by their radius of gyration, crystallinity, and number of edge particles, and demonstrate the expected size-dependent properties. Our findings demonstrate successful ensemble feedback control of the assembly of different sized colloidal crystals using multiple actuators, which has broad implications for control over nano- and micro- scale assembly processes involving colloidal components. 相似文献
72.
73.
Hydrogen peroxide activated by boric acid in the presence of sulfuric acid has been shown to be an efficient oxidizing system for direct conversion of aromatic aldehydes and ketones to phenols. 相似文献
74.
India is looking at the renewable alternative sources of energy to reduce its dependence on import of crude oil. As India imports 70?% of the crude oil, the country has been greatly affected by increasing cost and uncertainty. Biodiesel fuel derived by the two step acid transesterification of mixed non-edible oils from Jatropha curcas and Pongamia (karanja) can meet the requirements of diesel fuel in the coming years. In the present study, different proportions of Methanol, Sodium hydroxide, variation of Reaction time, Sulfuric acid and Reaction Temperature were adopted in order to optimize the experimental conditions for maximum biodiesel yield. The preliminary studies revealed that biodiesel yield varied widely in the range of 75–95?% using the laboratory scale reactor. The average yield of 95?% was obtained. The fuel and chemical properties of biodiesel, namely kinematic viscosity, specific gravity, density, flash point, fire point, calorific value, pH, acid value, iodine value, sulfur content, water content, glycerin content and sulfated ash values were found to be within the limits suggested by Bureau of Indian Standards (BIS 15607: 2005). The optimum combination of Methanol, Sodium hydroxide, Sulfuric acid, Reaction Time and Reaction Temperature are established. 相似文献
75.
An experimental and theoretical study of the response of aflexible cantilever beam to an external harmonic excitation nearthe beam's third natural frequency is presented. For a certain range ofthe excitation frequency, we observed experimentally that the responseincludes a large contribution due to the first mode of the beamaccompanied by a slow modulation of the amplitude and phase of the thirdmode. In addition, we noted that the energy transfer between the thirdand first modes is very much dependent upon the closeness of themodulation (or Hopf bifurcation) frequency to the first-mode naturalfrequency. In earlier studies by Nayfeh and coworkers, the modulationfrequency was close to the first-mode natural frequency, and thereforelarge first-mode swaying was observed. But for higher forcingamplitudes, the present experiments show that the modulation frequencytends to shift away from the first-mode natural frequency, andsubsequently very little swaying is observed. We also developed areduced-order analytical model by discretizing the integralpartial-differential equation of motion, derived by Crespo daSilva and Glenn, using the Galerkin procedure with a four-modeapproximation. The reduced-order model demonstrates the energy transferfrom the third mode to the first mode. 相似文献
76.
Ajit Chaturvedi N. D. Shukla Pramod S. Shukla 《Annals of the Institute of Statistical Mathematics》1992,44(1):157-167
The sequential procedure developed by Bhargava and Srivastava (1973, J. Roy. Statist. Soc. Ser. B, 35, 147–152) to construct fixed-width confidence intervals for contrasts in the means is further analyzed. Second-order approximations for the first two moments of the stopping time and the coverage probability associated with the sequential procedure, are obtained. A lower bound for the number of additional observations after stopping is derived, which ensures the mxact probability of coverage. Moreover, two-stage, three-stage and modified sequential procedures are proposed for the same estimation problem. Relative advantages and disadvantages of these sampling schemes are discussed and their properties are studied. 相似文献
77.
Pradeep K. Muwal Aradhana Nayal Manish K. Jaiswal Pramod S. Pandey 《Tetrahedron letters》2018,59(1):29-32
A novel dipyrromethane based receptor has been synthesized. It works as a highly selective colorimetric sensor for F? and Cu2+ ions, which can be used for their necked eye detection with evident colour change of its solution. 相似文献
78.
The preparation and Rh-mediated cyclization of the alpha-diazoester 1 are outlined, and its utility in determining the elements that contribute to the reactivity of the intermediate Rh-carbenoid is presented. The rate of disappearance of diazo ester 1 catalyzed by several representative Rh(II) complexes was determined. The observed relative rate constants for the reaction of the Rh(II) complexes with 1 varied over a range of >10(7). The reactivity of the Rh-carbenoid intermediate was explored using the ratio of the sum of (3 + 4 + 5) to 2 (cyclization vs elimination), the ratio of 3 to the sum of (4 + 5) (chemoselectivity), and the ratio of 4 to 5 (diastereoselectivity). It is striking that these four measures of reactivity were found to be independent of each other. 相似文献
79.
Saraf Madhusudan N. Birajdar Pramod G. Loya Punnamchand Mukherjee Siddharth A. 《平面色谱法杂志一现代薄层色谱法》2007,20(3):203-207
JPC – Journal of Planar Chromatography – Modern TLC - Epalrestat is a new drug for diabetic neuropathy. A new, simple, rapid very sensitive, and accurate high performance thin-layer... 相似文献
80.
Penicillin acylase ofE. coli NCIM 2400 has been purified to homogeneity using a combination of hydrophobic interaction chromatography and DEAE-cellulose
treatment. A variety of substituted matrices were synthesized using D- or DL-phenylglycine, norleucine, ampicillin, or amoxycillin
as ligands, all of which retained penicillin acylase at high concentrations of ammonium sulfate or sodium sulfate. The enzyme
could be eluted nonbiospecifically by buffer of lower ionic strength with over 95% recovery of the activity. Ammonium chloride,
ammonium nitrate, sodium chloride, sodium nitrate, and potassium chloride were ineffective in either adsorption or elution
of the enzyme on these columns. Further purification of this partially pure enzyme with DEAE-cellulose at pH 7.0–7.2 yielded
an enzyme preparation of very high purity according to electrophoretic and ultracentrifugal analyses, its specific activity
being as high as 37 U/mg protein. The purifiedf enzyme has a molecular weight of 67,000 a sedimentation coefficient of 4.0S,
and resolves into two forms upon isoelectric focusing. Overall recoveries ranged between 75 and 85%. Ease of operation, high
recoveries, high purity of the enzyme and prolonged reuse of the conjugates make the process economically feasible and possibly
of great commercial importance. 相似文献