Reactions of NH(a 1Δ) with propane in the gas phase

Reactions of electronically excited NH(a ¹Δ) with propane have been investigated in the gas phase at room temperature. Pressure dependence of the yields of insertion and fragmentation products was measured. The relative secondary/primary CH bond reactivities (per bond) are determined to be 1.5 for insertion and 7.5 for abstraction.     

The synthesis of 2-ethoxy-6,11-dimethyl-7,9-bisdehydroaza[14]annulene and its benzannelated derivatives

Title azaannulenes were synthesized starting from annulenones, and the ¹H-NMR spectra are discussed in connection with tropicity of these annulenes.     

Weak coupling perturbative calculations of the Wilson loop in lattice gauge theory

Weak coupling perturbative calculations of the Wilson loop in lattice gauge theory are carried out numerically up to order g⁴. Comparison of the results with those of the Monte Carlo calculations shows that there exists a non-perturbative contribution of an essential singularity type which may be identified as the string tension.     

Odd-even effect of the methylene chain number in the template polymerization of alpha,beta-diacetylenecarboxylates incorporated in layered double hydroxide clay

The present investigation reports on the significant differences observed in the efficiency of the polymerization depending on the odd- or even-numbered methylene chains of diacetylenecarboxylates, CH3(CH2)(m-1)C[triple bond]C-C[triple bond]C(CH2)(n-1)CO2- (mono-[m,n]), incorporated in layered double hydroxide (LDH) clay. Upon gamma-ray irradiation of the diacetylenecarboxylates, or mono-[m,n], in LDH clay, polymer hybrids or poly-[m,n]/LDH, which exhibited coloring from light orange to violet, were obtained. The color of the poly-[m,n]/LDH hybrids was strongly dependent on the extent of the polymerization degrees. Moreover, the polymerization degrees were controlled by the number of methylene spacers n between the carboxyl and diacetylene groups. An odd-numbered n for the methylene chain of mono-[m,n] was found to be the determining factor in the efficient polymerization of these self-assembling aggregates within the interlayers of LDH clay.     

Synthesis of possible metabolites of chlorpromazine. I. 7-hydroxy derivatives of chlorpromazine,nor1-chlorpromazine and nor2-chlorpromazine

The title compounds and various derivatives have been prepared as analytical standards for the identification of chlorpromazine metabolites in biological materials. Additional evidence is presented for the existence of a halogen-induced Smiles rearrangement in the phenothiazine series.     

A finite size scaling test of an SU(2) gauge-spin system

We calculate the correlation functions in the SU(2) gauge-spin system with spin in the fundamental representation. We analyze the result making use of finite size scaling. There is a possibility that there are no second order phase transition lines in this model, contrary to previous assertions.