全文获取类型
收费全文 | 985篇 |
免费 | 47篇 |
国内免费 | 3篇 |
专业分类
化学 | 797篇 |
晶体学 | 8篇 |
力学 | 10篇 |
综合类 | 1篇 |
数学 | 75篇 |
物理学 | 144篇 |
出版年
2023年 | 11篇 |
2022年 | 8篇 |
2021年 | 20篇 |
2020年 | 12篇 |
2019年 | 22篇 |
2018年 | 14篇 |
2017年 | 7篇 |
2016年 | 21篇 |
2015年 | 28篇 |
2014年 | 29篇 |
2013年 | 49篇 |
2012年 | 57篇 |
2011年 | 69篇 |
2010年 | 40篇 |
2009年 | 35篇 |
2008年 | 73篇 |
2007年 | 83篇 |
2006年 | 81篇 |
2005年 | 64篇 |
2004年 | 50篇 |
2003年 | 50篇 |
2002年 | 31篇 |
2001年 | 11篇 |
2000年 | 13篇 |
1999年 | 12篇 |
1998年 | 13篇 |
1997年 | 12篇 |
1996年 | 6篇 |
1995年 | 4篇 |
1994年 | 8篇 |
1993年 | 7篇 |
1992年 | 8篇 |
1991年 | 8篇 |
1990年 | 6篇 |
1989年 | 2篇 |
1987年 | 3篇 |
1986年 | 2篇 |
1985年 | 14篇 |
1984年 | 14篇 |
1982年 | 7篇 |
1981年 | 6篇 |
1980年 | 2篇 |
1979年 | 3篇 |
1978年 | 3篇 |
1977年 | 4篇 |
1976年 | 2篇 |
1974年 | 4篇 |
1973年 | 1篇 |
1970年 | 1篇 |
1966年 | 2篇 |
排序方式: 共有1035条查询结果,搜索用时 15 毫秒
51.
Tomoyuki Tajima Yukie Yamaguchi Yo-hei Shiomoto Yutaka Takaguchi 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1):2-11
Abstract We succeeded in the synthesis of a novel poly(amidoamine) dendrimer having diphenyl diselenide at the core. Modification of the dendrimer diselenide by the reaction with glucono-δ-lactone in methanol gave a water-soluble dendrimer diselenide having chiral terminal groups. The structures of dendrimers were satisfactorily confirmed by MAIDI-TOF MS spectrometry, elemental analysis, and NMR spectroscopy. Interestingly, induced circular dichroism (ICD) of the interaction between the diphenyl diselenide core and D-gluconamide periphery of the dendrimer was observed at 300 nm. Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file. GRAPHICAL ABSTRACT 相似文献
52.
Abstract The photopolymerization of vinyl monomers by metal salt-saccharide system was investigated in various solvents. The rate of polymerization in the presence of a iron(III) salt in aqueous media was remarkably accelerated by the addition of saccharides. The acceleration caused by a series of saccharides was found to be in the following order: glucose > fructose > lactose maltose. α-Methyl-d-glucoside and sucrose exhibited very little effect. The overall activation energy for the photopolymerization of acrylonitrile in the presence of glucose was found to be 2.7 kcal/mole, about half of the value obtained in the absence of glucose. 相似文献
53.
Ryo Satoh Takaaki Goto Seon Hwa Lee Tomoyuki Oe 《Analytical and bioanalytical chemistry》2013,405(25):8001-8010
54.
A new bis(terpyridine) derivative with a phenylacetylene framework was synthesized via a stepwise terpyridine construction strategy. The addition of ZnCl2 to a solution of the bis(terpyridine) in chloroform resulted in UV/vis and 1H NMR spectral changes because of complex formation. 相似文献
55.
56.
Lin SW Chang P Abe K Abe K Adachi I Aihara H Anipko D Aulchenko V Aushev T Bahinipati S Bakich AM Barberio E Bedny I Bitenc U Bizjak I Blyth S Bondar A Bozek A Bracko M Browder TE Chang MC Chao Y Chen A Chen KF Chen WT Cheon BG Chistov R Choi SK Choi Y Choi YK Dalseno J Dash M Dragic J Drutskoy A Eidelman S Fratina S Gabyshev N Garmash A Go A Golob B Ha H Haba J Hara T Hayashii H Hazumi M Heffernan D Hokuue T Hoshi Y Hou WS Hsiung YB Iijima T Ikado K Imoto A Inami K Ishikawa A Ishino H Itoh R 《Physical review letters》2007,99(12):121601
We report measurements of branching fractions for B --> K pi and B --> pi pi decays based on a data sample of 449 x 10(6) BB[over] pairs collected at the Upsilon(4S) resonance with the Belle detector at the KEKB asymmetric-energy e(+)e(-) collider. We also measure the ratios of partial widths for B-->Kpi decays, namely R(c) identical with 2Gamma(B(+) --> K(+) pi(0))/Gamma(B(+) --> K(0) pi(+)) = 1.08+/-0.06+/-0.08 and R(n) identical with Gamma(B(0) --> K(+) pi(-))/2 Gamma(B(0) --> K(0) pi(0)) = 1.08+/-0.08+/-0.08, where the first and the second errors are statistical and systematic, respectively. These ratios are sensitive to enhanced electroweak penguin contributions from new physics; the new measurements are, however, consistent with standard model expectations. 相似文献
57.
58.
59.
Dai Kato Atsumu Oda Mutsuo Tanaka Seiichiro Iijima Tomoyuki Kamata Masami Todokoro Yasuo Yoshimi Osamu Niwa 《Electroanalysis》2014,26(3):618-624
We developed an electrochemical system for detecting lipopolysaccharide (LPS) that uses an ultraflat nanocarbon film electrode modified with poly‐ε‐lysine with a high affinity to LPS. LPS was captured on the modified electrode, and then ferrocene labeled polymyxin B (FcPMB) was captured on the LPS adsorbed electrode via the LPS‐PMB affinity interaction. The adsorbed FcPMB provided an amplified response with Fe2+ ions, and the current response was dependent on the amount of captured LPS (LOD=2.0 ng/mL). This was due to the efficient accumulation of the obtained current for LPS and the very low noise made possible by the ultraflat surface. 相似文献
60.
Synergistic Spin Transition between Spin Crossover and Spin‐Peierls‐like Singlet Formation in the Halogen‐Bonded Molecular Hybrid System: [Fe(Iqsal)2][Ni(dmit)2]⋅CH3CN⋅H2O
下载免费PDF全文
![点击此处可从《Angewandte Chemie (International ed. in English)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Kappei Fukuroi Prof. Dr. Kazuyuki Takahashi Prof. Dr. Tomoyuki Mochida Dr. Takahiro Sakurai Prof. Dr. Hitoshi Ohta Dr. Takashi Yamamoto Prof. Dr. Yasuaki Einaga Prof. Dr. Hatsumi Mori 《Angewandte Chemie (International ed. in English)》2014,53(7):1983-1986
To introduce halogen‐bond interactions between a cation and an anion, a novel FeIII complex from iodine‐substituted ligands involving a paramagnetic nickel dithiolene anion was prepared and characterized. The compound exhibited the synergy between a spin‐crossover transition and a spin‐Peierls‐like singlet formation. The halogen‐bond interactions between the iodine and the sulfur atoms stabilized the paramagnetic state of π‐spins and played a crucial role in the synergistic magnetic transition between d‐ and π‐spins. In addition, the compound showed the light‐induced excited spin state trapping effect. 相似文献