Spatiotemporal dynamics of a Leslie–Gower predator–prey model incorporating a prey refuge

In this paper, we investigate the spatiotemporal dynamics of a two-dimensional predator–prey model, which is based on a modified version of the Leslie–Gower scheme incorporating a prey refuge. We establish a Lyapunov function to prove the global stability of the equilibria with diffusion and determine the Turing space in the spatial domain. Furthermore, we perform a series of numerical simulations and find that the model dynamics exhibits complex Turing pattern replication: stripes, cold/hot spots-stripes coexistence and cold/hot spots patterns. The results indicate that the effect of the prey refuge for pattern formation is tremendous. This may enrich the dynamics of the effect of refuge on the predator-prey systems.     

Dynamical behaviors of a biological management model with impulsive stocking juvenile predators and continuous harvesting adult predators

In this work, a biological management model with impulsive stocking juvenile predators and continuous harvesting adult predators is investigated. By the stroboscopic map of the discrete dynamical system, the prey-extinction periodic solution of the investigated system is proved to be globally asymptotically stable. By the theory of impulsive differential equation, the investigated system is also proved to be permanent. Finally, the numerical analysis is inserted to illustrate the results. Our conclusions provide reliable tactical basis for the practical biological management.     

Complete q-Moment Convergence of Moving Average Processes under -mixing Assumption

In this paper,we study the complete q-moment convergence of moving average processes under -mixing assumption.The results obtained not only extend some previous known results,but also improve them.     

Modeling on an ecological food chain with recycling

We propose two nutrient-phytoplankton models with instantaneous and time delayed recycling, investigate the dynamics and examine the responses to model complexities. Instead of the familiar specific uptake rate and growth rate functions, we assume only that the nutrient uptake and phytoplankton growth rate functions are positive, increasing and bounded above. We use geometrical and analytical methods to find conditions for the existence of none, one, or at most two positive steady states and analyze the stability properties of each of these equilibria. With the variation of parameters, the system may lose its stability and bifurcation may occur. We study the occurrence of Hopf bifurcation and the possibility of stability switching. Numerical simulations illustrate the analytical results and provide further insight into the dynamics of the models, biological interpretations are given.     

Global synchronization of weighted cellular neural network with time-varying coupling delays

New sufficient conditions are derived to guarantee the global synchronization of the weighted cellular neural network with multiple time delays. Based on Lyapunov theory, this paper proposes an adaptive feedback controlling method to identify the exact topology of a rather general weighted cellular neural network system with time-varying delays and then considers the synchronization of the neural network with different nodes dynamics. The parameters in this paper are very few and experiments show that the methods presented in this paper are of high application in global synchronization.     

Amplification of Lipid Peroxidation by Regulating Cell Membrane Unsaturation To Enhance Chemodynamic Therapy

Lipid peroxidation (LPO) is one of the most damaging processes in chemodynamic therapy (CDT). Although it is well known that polyunsaturated fatty acids (PUFAs) are much more susceptible than saturated or monounsaturated ones to LPO, there is no study exploring the effect of cell membrane unsaturation degree on CDT. Here, we report a self-reinforcing CDT agent (denoted as OA@Fe-SAC@EM NPs), consisting of oleanolic acid (OA)-loaded iron single-atom catalyst (Fe-SAC)-embedded hollow carbon nanospheres encapsulated by an erythrocyte membrane (EM), which promotes LPO to improve chemodynamic efficacy via modulating the degree of membrane unsaturation. Upon uptake of OA@Fe-SAC@EM NPs by cancer cells, Fe-SAC-catalyzed conversion of endogenous hydrogen peroxide into hydroxyl radicals, in addition to initiating the chemodynamic therapeutic process, causes the dissociation of the EM shell and the ensuing release of OA that can enrich cellular membranes with PUFAs, enabling LPO amplification-enhanced CDT.     

Sulfur Poisoning and Self-Recovery of Single-Site Rh1/Porous Organic Polymer Catalysts for Olefin Hydroformylation

Sulfur poisoning and regeneration are global challenges for metal catalysts even at the ppm level. The sulfur poisoning of single-metal-site catalysts and their regeneration is worthy of further study. Herein, sulfur poisoning and self-recovery are first presented on an industrialized single-Rh-site catalyst (Rh₁/POPs). A decreased turnover frequency of Rh₁/POPs from 4317 h⁻¹ to 318 h⁻¹ was observed in a 1000 ppm H₂S co-feed for ethylene hydroformylation, but it self-recovered to 4527 h⁻¹ after withdrawal of H₂S, whereas the rhodium nanoparticles demonstrated poor activity and self-recovery ability. H₂S reduced the charge density of the single Rh atom and lowered its Gibbs free energy with the formation of inactive (SH)Rh(CO)(PPh₃-frame)₂, which could be regenerated to active HRh(CO)(PPh₃-frame)₂ after withdrawing H₂S. The mechanism and the sulfur-related structure–activity relationship were highlighted. This work provides an understanding of heterogeneous ethylene hydroformylation and sulfur-poisoned regeneration in the science of single-atom catalysts.     

Access to Disentangled Ultrahigh Molecular Weight Polyethylene via a Binuclear Synergic Effect

Disentangled ultrahigh molecular weight polyethylene (dis-UHMWPE) has excellent processability but can be achieved under extreme conditions. Herein, we report ethylene polymerization with the binuclear half-sandwich scandium complexes C1-Sc₂ and C2-Sc₂ to afford UHMWPE . C1-Sc₂ bearing a short linker shows higher activity and gives higher molecular weight PEs than C2-Sc₂ containing a flexible spacer and the mononuclear Sc₁ . Strikingly, all UHMWPEs isolated from C1-Sc₂ under broad temperature range (25–120 °C) and wide ethylene pressures (2–13 bar) feature very low degree of entanglement as proved by rheological test, DSC annealing study and SEM. These dis-UHMWPEs are facilely mediated solid-state-process at 130 °C and their tensile strength and modulus reach up to 149.2 MPa and 1.5 GPa, respectively. DFT simulations reveal that the formation of dis-UHMWPE is attributed to the binuclear synergic effect and the agostic interaction between the active center and the growing chain.     

Xyloketal H from the mangrove endophytic fungus Xylaria sp. 2508

(3R*,3aR*,9aR*)-3,9a-Dimethyl-2,3,3a,9a-tetrahydro-4H-furo[2,3-b]chromene-5,7-diol (xyloketal H), a representative of a new family of xyloketals, was isolated from the marine-derived mangrove fungus Xylaria sp. 2508. Its structure was elucidated by spectroscopic data and single-crystal X-ray diffraction analysis. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1051–1052, June, 2006.     

Effects of Preparation Method on the Performance of Ni/Al2O3 Catalysts for Hydrogen Production by Bio-Oil Steam Reforming

Steam reforming of bio-oil derived from the fast pyrolysis of biomass is an economic and renewable process for hydrogen production. The main objective of the present work has been to investigate the effects of the preparation method of Ni/Al₂O₃ catalysts on their performance in hydrogen production by bio-oil steam reforming. The Ni/Al₂O₃ catalysts were prepared by impregnation, co-precipitation, and sol?Cgel methods. XRD, XPS, H₂-TPR, SEM, TEM, TG, and N₂ physisorption measurements were performed to characterize the texture and structure of the catalysts obtained after calcination and after their subsequent use. Ethanol and bio-oil model compound were selected for steam reforming to evaluate the catalyst performance. The catalyst prepared by the co-precipitation method was found to display better performance than the other two. Under the optimized reaction conditions, an ethanol conversion of 99% and a H₂ yield of 88% were obtained.