Influence of the Structure of Cetyltrimethylammonium Bromide Based Microemulsions on Base Hydrolysis of Carboxylic Acid Esters

The structure of water/cetyltrimethylammonium bromide/n-butanol/hexane microemulsions was studied by conductometry, viscometry, and Fourier transform ¹H NMR spectroscopy with pulse magnetic field gradient. The regions of phase inversion from inverse micelles in hexane through a bicontinual structure to a dispersion of normal micelles in water were determined. The influence of the structure of the microemulsions on the rate of hydrolysis of carboxylic acid p-nitrophenyl esters was analyzed. The hydrolysis rate constants considerably increase in going from inverse to normal microemulsions.     

High-Sensitivity Determination of Hydrocarbon Impurities in Arsine by Reaction Gas Chromatography

It is shown that the results of determining methane in high-purity arsine by reaction gas chromatography can be overestimated by more than two orders of magnitude. This overestimation is caused by the formation of methane as a side product of the reaction. Cryogenic preconcentration at the injection stage is proposed to improve the accuracy of determination of methane, and the cryofocusing of impurity hydrocarbons is proposed to improve separation. Detection limits of (3–10) × 10^–6 vol % are achieved for C₁–C₅ hydrocarbons.     

Polyfluoroalkylthiotrifluoroacetylketenes

A procedure was developed for the synthesis of polyfluoroalkylthiotrifluoroacetylketenes, and their reactions with nucleophilic reagents were studied. The resulting compounds were demonstrated to act as heterodienes in reactions with unsaturated compounds.     

Effect of Design Parameters of the Centrifuge Rotor on Separation of Supensions

Centrifugal separation of low-concentration suspension in a biconical rotor of a centrifuge was modeled numerically. A system of equations describing the motion of solid particles in a fluid flow was constructed and solved. The effect of geometric parameters of the centrifuge rotor on the separation efficiency was demonstrated.     

Magnetic phase transitions in nanostructures induced by shear stress under high pressure

Magnetic phase transitions of the first and second order were revealed by Mössbauer spectroscopy in nanosystems of - and -ferric oxides and metallic europium subjected to shear stress (240°) under high pressure (20 kbar). For - and -ferric oxide nanoclusters, the Curie (Neel) points decreased to 300 K, whereas for nanostructured europium the Neel point increased from 90 to 100 K. The thermodynamic model of magnetic phase transitions predicting a change in the character of magnetic phase transitions and a decrease (increase) in the critical Neel (Curie) points in nanoclusters was developed. The type of magnetic phase transitions and the change in the critical points were caused by defects in nanoclusters, whose maximum concentration was observed for the clusters with the 20—50 nm size range.     

Structure of 2-Amino-4-phenyl-9H-pyrimido[4,5-b]indole and Its Nitrate in Crystal and Solution

The crystal structures of 2-amino-4-phenyl-9H-pyrimido[4,5-b]indole and its nitrate were determined by XRD analysis. ¹³C NMR, XRD, and quantum-chemical data indicate that the acid proton is predominantly localized at the N(3) atom of the pyrimidine ring in both isolated nitrate molecules and in molecules in crystal and solution.     

Effect of Mechanochemical Activation on the Catalytic Properties of Ferrites with the Spinel Structure

It was found experimentally that stacking defects formed in the mechanochemical activation of zinc ferrite enhanced the specific catalytic activity in the reaction of CO oxidation. The specific rate of CO oxidation was a linear function of defect concentration, which was determined using Mössbauer spectroscopy and X-ray diffraction. A conclusion was drawn that the same centers are responsible for an increase in the catalytic activity, the sorption capacity for hydrogen sulfide, and the reactivity of zinc ferrite in the interaction with hydrochloric acid. It was assumed that analogous factors caused an increase in the catalytic activity and reactivity of magnesium ferrite.     

Synthesis of Aryl Ethers by Nonactivated Aromatic Nucleophilic Substitution Reactions

The results of a kinetic study of model reactions between substituted phenols and bromobenzene in the presence of potassium carbonate and the copper(I) chloride–8-hydroxyquinoline catalytic complex in N,N-dimethylformamide are presented. The reactions were found to obey a first-order rate law. Both orbital and charge interactions should be taken into account in a consideration of the effect of the structural characteristics of reactants on the rate of reaction. The kinetics of substitution of the phenoxide anion for an aromatically bound halogen atom in activated and nonactivated systems with the formation of practically valuable aryl ethers were comparatively studied. The results presented provide an opportunity to distinguish the common features and regularities of activated and nonactivated aromatic substitution in the test systems.     

Indirect laser photoacoustic detection for trace samples on membranes

An indirect laser photoacoustic technique is described. The basic principle, the experimental set-up and the influencing factors are discussed in detail. This method was used to quantify phenylamine, arginine and methylene blue on membranes. The linear ranges of the calibration curve are up to two orders of magnitude. With 1 microliter of sample solution, the detection limits are 0.25, 1.52 and 0.14 pmol for phenylamine, arginine and methylene blue, respectively.