氧络双四苯骈卟啉铁（Ⅲ）的合成及氧络二聚反应的热力学研究

合成了氧络双四苯骈卟啉铁（Ⅲ），其结构经红外光谱、紫外光谱和元素分析确证．同时用分光光度法研究了在ＤＭＦ－Ｈ２Ｏ体系中四苯骈卟啉铁（Ⅲ）的氧络二聚反应的热力学平衡，并由此计算出该反应的有关热力学常数．     

离子束刻蚀技术研究

本文介绍了离子束刻蚀技术的原理,讨论了刻蚀速率与离子束流密度、离子能量和离子束入射角度的关系。实验结果与理论分析有较好的一致性。     

High pulse energy mode-locked multicore photonic crystal fiber laser

A high pulse energy passively mode-locked fiber laser operating in the all-normal dispersion regime is demonstrated. The gain material is an Yb-doped multicore photonic crystal fiber with 18 cores in array-type geometry. Robust and self-starting mode locking is achieved using a fast semiconductor saturable absorber mirror. The laser generates 180?nJ chirped pulses at a 14.48?MHz repetition rate for an average power of 2.6?W. The 1.15?ps output pulses are compressed to 690?fs outside the cavity.     

A novel hyperchaotic system and its circuit implementation

A four-dimensional hyperchaotic system with five parameters is proposed. Its dynamical properties such as dissipativity, equilibrium points, Lyapunov exponent, Lyapunov dimension, bifurcation diagrams and Poincare maps are analyzed theoretically and numerically. Theoretical analyses and simulation tests indicate that the new system's dynamics behavior can be periodic attractor, chaotic attractor and hyperchaotic attractor as the parameter varies. Finally, the circuit of this new hyperchaotic system is designed and realized by Multisim software. The simulation results confirm that the chaotic system is different from the existing chaotic systems and is a novel hyperchaotic system. The system is recommendable for many engineering applications such as information processing, cryptology, secure communications, etc.     

Experimental characterization and correction of non-equivalence of Solar Irradiance Absolute Radiometer

We experimentally evaluate and correct the non-equivalence between electrical and radiative heating of solar irradiance absolute radiometer to compensate the systematic error of radiant power measurement at ambient pressure. A relative difference of the order of 0.08%-0.27% between electrical and radiative heating sensitivities is shown, and the resulting non-equivalence correction factor is calculated. The radiant power measurement equation is modified using the non-equivalence correction factor, a systematic deviation of 0.19% of radiant power measurement is hence eliminated.     

Electrochemical performance of a nonaqueous rechargeable lithium-air battery

Nonaqueous rechargeable lithium-air battery has so high specific capacity and specific energy that it is being widely researched by academia, corporation, and different research institutes. When used in dried air and absorbing oxygen form the air, this battery is called lithium-air battery, and its specific capacity based on cathode active material (oxygen) is infinite. However, its cycle performance is very limited as reported by the state-of-the-art researches. This cycle problem is mainly caused by instability of electrolyte. Based on electroanalysis of materials’ electrochemical property, a stable electrolyte solvent (sulfolane) and a lithium salt LiBF₄ are selected as electrolytes in this work. Coupled with other eligible battery materials and careful assembly, the lithium-air battery exhibits favorable cycle performance. Above all, this lithium-air system is evaluated objectively in this paper.     

Protocol for multi-party superdense coding by using multi-atom in cavity QED

We present a protocol for multi-party superdense coding by using multi-atom in cavity quantum electrodynamics (QED). It is shown that, with a highly detuned cavity mode and a strong driving field, the protocol is insensitive to both cavity decay and thermal field. It is even certain to identify GHZ states via detecting the atomic states. Therefore we can realize the quantum dense coding in a simple way in the multiparty system.     

超重核294118及其α衰变链的基态性质

用形变约束的相对论平均场理论系统研究了超重核²⁹⁴118及其α衰变链的基态性质, 给出了这些原子核的每核子结合能和α衰变能以及基态形变, 并与实验结果进行了比较, 发现理论计算和实验结果符合得很好, 表明相对论平均场理论对超重核基态性质的描述是合理有效的.     

单偏振控制器环形腔光纤激光器实验研究

理论分析了非线性偏振旋转环形腔作为类饱和可吸收体获得脉冲的物理机理。在光纤环形腔结构中,采用单个偏振控制器实现了非线性偏振旋转锁模,直接获得了脉冲宽度为131 fs的超短脉冲输出。实验中,采用性能稳定的976 nm半导体二极管激光器作为抽运源,使用高掺杂浓度的Er3 光纤为增益介质,通过调节偏振控制器,获得了光谱谱宽(3 dB带宽处)为23.5 nm的稳定锁模脉冲输出。脉冲中心波长为1535.9 nm,平均功率为5.91 mW,脉冲重复率为11.20 MHz。