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51.
Yang Zhao Yue‐Jiao Zhang Jin‐Hui Meng Shu Chen Rajapandiyan Panneerselvam Chao‐Yu Li Sain Bux Jamali Xia Li Zhi‐Lin Yang Jian‐Feng Li Zhong‐Qun Tian 《Journal of Raman spectroscopy : JRS》2016,47(6):662-667
Silver nanoparticles (Ag NPs) enjoy a reputation as an ultrasensitive substrate for surface‐enhanced Raman spectroscopy (SERS). However, large‐scale synthesis of Ag NPs in a controlled manner is a challenging task for a long period of time. Here, we reported a simple seed‐mediated method to synthesize Ag NPs with controllable sizes from 50 to 300 nm, which were characterized by scanning electron microscopy (SEM) and UV–Vis spectroscopy. SERS spectra of Rhodamine 6G (R6G) from the as‐prepared Ag NPs substrates indicate that the enhancement capability of Ag NPs varies with different excitation wavelengths. The Ag NPs with average sizes of ~150, ~175, and ~225 nm show the highest SERS activities for 532, 633, and 785‐nm excitation, respectively. Significantly, 150‐nm Ag NPs exhibit an enhancement factor exceeding 108 for pyridine (Py) molecules in electrochemical SERS (EC‐SERS) measurements. Furthermore, finite‐difference time‐domain (FDTD) calculation is employed to explain the size‐dependent SERS activity. Finally, the potential of the as‐prepared SERS substrates is demonstrated with the detection of malachite green. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
52.
A contrastive study on the influences of radial and three-dimensional satellite gravity gradiometry on the accuracy of the Earth's gravitational field recovery 下载免费PDF全文
The accuracy of the Earth’s gravitational field measured from the gravity field and steady-state ocean circulation explorer(GOCE),up to 250 degrees,influenced by the radial gravity gradient V zz and three-dimensional gravity gradient V ij from the satellite gravity gradiometry(SGG) are contrastively demonstrated based on the analytical error model and numerical simulation,respectively.Firstly,the new analytical error model of the cumulative geoid height,influenced by the radial gravity gradient V zz and three-dimensional gravity gradient V ij are established,respectively.In 250 degrees,the GOCE cumulative geoid height error measured by the radial gravity gradient V zz is about 2 1/2 times higher than that measured by the three-dimensional gravity gradient V ij.Secondly,the Earth’s gravitational field from GOCE completely up to 250 degrees is recovered using the radial gravity gradient V zz and three-dimensional gravity gradient V ij by numerical simulation,respectively.The study results show that when the measurement error of the gravity gradient is 3×10 12 /s 2,the cumulative geoid height errors using the radial gravity gradient V zz and three-dimensional gravity gradient V ij are 12.319 cm and 9.295 cm at 250 degrees,respectively.The accuracy of the cumulative geoid height using the three-dimensional gravity gradient V ij is improved by 30%-40% on average compared with that using the radial gravity gradient V zz in 250 degrees.Finally,by mutual verification of the analytical error model and numerical simulation,the orders of magnitude from the accuracies of the Earth’s gravitational field recovery make no substantial differences based on the radial and three-dimensional gravity gradients,respectively.Therefore,it is feasible to develop in advance a radial cold-atom interferometric gradiometer with a measurement accuracy of 10 13 /s 2-10 15 /s 2 for precisely producing the next-generation GOCE Follow-On Earth gravity field model with a high spatial resolution. 相似文献
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A polymer volume grating-based four-channel coarse wavelength division multiplexer (WDM) for inter- and intra-satellite optical communication application is reported for the first time. This compact four-channel WDM device working at 0.83, 1.06, 1.34 and 1.55 μm is designed to build a complete optical link between two satellites, where wavelengths of 0.83 and 1.55 μm are used for data stream channels, 1.06 and 1.34 μm are used for inter- and intra-satellite connection. It is for the first time reported that a WDM device can cover such a large wavelength range in a single substrate. For transverse electric (TE) wave, the channel efficiencies at 0.83, 1.06, 1.34 and 1.55 μm are 55%, 40%, 35% and 45%, respectively. Channel efficiencies for transverse magnetic (TM) waves are 20% lower than those of TE waves on average. Wavelength shifts due to Doppler effect, temperature variations and radiation effects in space can be adequately accommodated. 相似文献
56.
小波变换在载频条纹相位分析法中的应用研究 总被引:6,自引:8,他引:6
为了克服在非平稳信号分析中傅里叶变换的全局性缺陷,以及窗口傅里叶分析的单一分辨率和伸缩窗口傅里叶分析的尺度不确定性问题,采用伽博解析小波变换技术对空间载频光栅条纹进行相位分析,有效地提取出相对于载频条纹基频的完整相位信息,从本质上解决了上述问题。以三维轮廓术为例,与傅里叶分析进行了对比研究,给出了小波分析应用在空间载频条纹相位分析中详细而完整的理论推导证明、计算机模拟以及实验验证结果。 相似文献
57.
典型的光谱角色散技术中,由于光束带宽受限于高效三倍频,因而无法通过增大带宽来进一步改善焦斑均匀性.结合对四色打靶方案和多级相位调制技术的综合分析,提出了多频、多色光谱角色散束匀滑新方案.该方案能在保持高效三倍频基础上,获得带宽有所加宽,光谱包络近似连续的光源,且在远场匀滑上具有更为独特的优势.结果表明,采用束匀滑新方案后,虽然焦斑会有所增大,但其均匀性却得到明显改善;与典型的束匀滑方案相比,该方案能更为有效地抑制热斑,且达到最佳匀滑效果所需的时间有所减短.此外,通过对阵列光栅中子光栅刻线方向的自由组合可以实现多维光谱角色散的效果. 相似文献
58.
针对高功率板条激光器核心工作器件——板条Nd:YAG晶体的超精密加工开展研究,分析了具有特殊构型的板条Nd:YAG晶体元件的加工性能及工艺难点,提出了一种新的基于合成盘抛光的板条Nd:YAG晶体加工工艺,并对规格为100mm×30mm×3mm的板条Nd:YAG晶体进行了加工实验。实验结果表明,合成盘抛光可以很好地控制元件的塌边现象;通过磨料的优化选择,在合成盘抛光工艺中匹配合适粒度的Al2O3磨料能够实现元件的低缺陷加工,元件下盘后的全反射面平面度达0.217λ(1λ=632.8nm),端面平面度达到0.06λ,表面粗糙度达0.55nm(RMS),端面楔角精度可达2″。 相似文献
59.
A tunable infrared plasmonic polarization filter is proposed and investigated in this paper. The filter is based on the sandwich absorption structure which consists of three layers. The top layer is an array of asymmetrical cross resonator.The middle and bottom layers are dielectric spacer and metal film respectively. By absorbing specific wavelength of the incident light perfectly, the reflection spectrum of the structure shows filter performance. The calculated results show that the absorption wavelength is strongly dependent on the length of branch of the asymmetrical cross resonator which is parallel to the light polarization and independent of the length of the vertical one. Therefore, the asymmetrical cross resonator filter structure opens the way for freely tuning the filtering wavelength for a different light polarization. We can fix a resonant wavelength(absorption wavelength) corresponding to one polarization and change the resonant wavelength for the other polarization by adjusting the corresponding branch length of the asymmetrical cross resonator, or change the two resonant wavelengths of both two polarizations at the same time. 相似文献
60.
提出了同时考虑通孔效应和边缘传热效应的互连线温度分布模型,获得了适用于单层互连线和多层互连线温度分布的解析模型,并基于65 nm互补金属氧化物半导体(CMOS)工艺参数计算了不同长度单层互连线和多层互连线的温度分布.对于单层互连线,考虑通孔效应后中低层互连线的温升非常低,而全局互连线几乎不受通孔效应的影响,温升仍然很高.对于多层互连线,最上层互连线的温升最高,温升和互连介质层厚度近似成正比,而且互连介质材料热导率越低,温升越高.所提出的互连线温度分布模型,能应用于纳米级CMOS计算机辅助设计.
关键词:
通孔效应
边缘传热效应
纳米级互连线
温度分布模型 相似文献