混凝土抗折动强度及其极值研究

混凝土类不均匀脆性材料的率敏感性主要是由于混凝土的不均匀性造成的,不均匀性使得不同速率的动裂纹发展路径不同,决定了不同速率的抗折动强度不同。基于此,提出混凝土抗折动强度由砂浆与骨料的抗折静强度的加权平均值再加上惯性项组成的代数表达式,并预测混凝土材料在爆炸冲击荷载条件下的极限抗折动强度。最后通过特殊设计的单一菱形净浆骨料三点弯实验, 验证了不同加载速率时破坏裂纹的发展路径及抗折动强度变化规律。     

The ordinary quiver of a weight three block of the symmetric group is bipartite

Suppose F is a field of characteristic p?5, and that B is a p-block of the symmetric group Sn of defect 3. We prove that the Ext¹-quiver of B is bipartite, with the bipartition being described in a simple way using the leg-lengths of p-hooks of partitions.     

Three‐Phase Barker Arrays

A 3‐phase Barker array is a matrix of third roots of unity for which all out‐of‐phase aperiodic autocorrelations have magnitude 0 or 1. The only known truly two‐dimensional 3‐phase Barker arrays have size 2 × 2 or 3 × 3. We use a mixture of combinatorial arguments and algebraic number theory to establish severe restrictions on the size of a 3‐phase Barker array when at least one of its dimensions is divisible by 3. In particular, there exists a double‐exponentially growing arithmetic function T such that no 3‐phase Barker array of size with exists for all . For example, , , and . When both dimensions are divisible by 3, the existence problem is settled completely: if a 3‐phase Barker array of size exists, then .     

添加钒对Pd/Al2O3-TiO2 催化剂上醇醛催化氧化性能及表面特性的影响

采用浸渍法分别制备了Pd/Al₂O₃-TiO₂、V/Al₂O₃-TiO₂和不同钒含量的V-Pd/Al₂O₃-TiO₂催化剂,并对乙醇、乙醛的完全催化氧化性能进行了测试。结果表明,添加适量的钒组分(1%~3%)能够有效地提高催化剂的深度氧化活性。采用XRD、NH₃-TPD、N₂吸附等技术分析研究催化剂的表面特性与催化活性之间的关系,发现Pd/Al₂O₃-TiO₂催化剂添加适量钒组分后,调变了催化剂的表面酸性、比表面积和孔容,使得V组分和Pd组分与载体之间产生较强的相互作用,双金属组分的协同效应提高了催化剂对乙醇、乙醛的深度氧化活性。     

Layered Double Hydroxide as Cordycepin Delivery Nanocarrier

Layered double hydroxides (LDHs), also called “anionic clays”, have received considerable attention due to their technological importance in catalysis, adsorption, optics, nanocomposite engineering materials and medical science1-5. LDHs are layered mate…     

CVD Reactions of TiCl4 with Ammonia： a Quantum Chemical Study

Based on density functional calculations, the mechanism and the energetic course of the chemical vapor deposition （CVD） reaction of TiCl4 with NH3 were studied at the level of B3LYP with 6-311g（d） basis set. Furthermore, the polymerization processes of dimerization, trimerization and tetramerization were investigated. The calculation results indicate that the formation of polymers is favored at the elimination reaction. On the basis of the calculated energetics, a possible mechanism of the reduction reaction has been proposed.     

免疫亲和柱净化/柱前衍生化-高效液相色谱荧光检测法测定粮谷中的T-2毒素

建立了免疫亲和柱净化/柱前衍生化-高效液相色谱荧光检测器测定粮谷中T-2毒素含量的方法。样品经甲醇-水(体积比为80∶20)混合溶剂提取,通过免疫亲和柱(IAC)净化,以氰酸蒽(1-AN)为衍生化试剂、4-二甲基氨基吡啶(DMAP)为催化剂进行衍生,以ZORBAX Eclipse XDB-C18 柱为分离柱,乙腈-水(体积比为80∶20)为流动相进行高效液相色谱分离及荧光检测，荧光检测的激发波长为381 nm，发射波长为470 nm。T-2毒素的质量浓度为0.01~1.5 mg/L时与峰高呈良好的线性,相关系数为0.9985。在0.01~1.5 μg/g添加水平下，回收率为79.7%~94.5%,相对标准偏差小于7%；检出限（S/N＝3）为0.01 μg/g。该方法净化效果好,灵敏度高,操作简便快速。     

边孔弧形闸门水流脉动压力特性研究

弧形泄水闸是水利枢纽工程中常见的挡水、泄水建筑物,其在关闭或开启过程中或者局部开启运行时,在水流脉动压力作用下会产生振动,容易引起闸门结构破坏。本文针对边孔闸门与中孔闸门不同的水流边界条件特点,制作了带导流墙与无导流墙两个弧形闸门模型。在实验室内开展了不同库水位、不同闸门开度下的物理模型试验,并对两个模型上大量测点的水流脉动压力数据进行比较分析。试验表明,导流墙的存在对脉动压力主频的影响较小,但对脉动压力均方根值影响较大;在较高库水位下相对开度位于0.2至0.3区间内时,导流墙的存在不但不会改善闸门的受力状况,反而还会导致受力增强。     

人造金刚石的微观结构模型

将静态超高压高温合成的人造金刚石晶粒利用RTO包埋法制备成适合TEM观察的样品,发现这些金刚石晶粒是由多根细长的纳米多晶棒沿一定取向规则地以捆束状堆叠、聚集而成,而这些纳米多晶棒之间填充了无定型碳。也就是说,人造金刚石晶粒是由结晶碳素和无定型碳组成的。由此,提出并绘制了人造金刚石晶粒的微观结构模型示意图,可用于解释人造金刚石的各向异性及其他宏观性能特征。在以上结论的基础上,笔者认为业界经常提及的"单晶"金刚石称谓可能并不严谨,可能并不是纯粹由结晶金刚石材料组成。     

Controlled kinetics of non-enzymatic chemiluminescence reactions for simple imaging of DNA and protein

A robust and sensitive non-enzymatic chemiluminescence (CL) imaging method is presented. In the method a fast-emitting CL reaction is tuned to furnish a slower-emitting reaction suitable for simple CL imaging. Typically, non-enzymatic CL reactions between luminol or fluorescein and oxygen species generated by KCN as catalyst, were rather fast and unsuitable for CL imaging; the speed of the reactions could, however, be reduced substantially by changing KCN for CH(3)CN or benzonitrile. Light emission from the tuned CL reaction was intense and long-lived, and even with a simple arrangement high sensitivity could be achieved. The maximum CL peak was reached after approximately 1.5 min in the presence of 25% acetonitrile, and as little as 16 fmol commercial isoluminol-labeled streptavidin was detected and visualized on either microplate or membrane. The approach was further illustrated by imaging of DNA on a membrane and of antibody on a microplate by use of biotin-streptavidin chemistry. Overall, this simple, economical, and sensitive CL imaging system is expected to be very useful in biochemical analysis, and greatly complements currently used enzyme-based CL imaging methods, especially in routine applications.