全文获取类型
收费全文 | 119629篇 |
免费 | 7658篇 |
国内免费 | 5427篇 |
专业分类
化学 | 53236篇 |
晶体学 | 1374篇 |
力学 | 9337篇 |
综合类 | 329篇 |
数学 | 36565篇 |
物理学 | 31873篇 |
出版年
2024年 | 164篇 |
2023年 | 895篇 |
2022年 | 1511篇 |
2021年 | 1608篇 |
2020年 | 1803篇 |
2019年 | 1680篇 |
2018年 | 11563篇 |
2017年 | 11343篇 |
2016年 | 7965篇 |
2015年 | 2929篇 |
2014年 | 2756篇 |
2013年 | 3450篇 |
2012年 | 7420篇 |
2011年 | 14157篇 |
2010年 | 8176篇 |
2009年 | 8507篇 |
2008年 | 9273篇 |
2007年 | 11087篇 |
2006年 | 2634篇 |
2005年 | 3174篇 |
2004年 | 3011篇 |
2003年 | 3181篇 |
2002年 | 2167篇 |
2001年 | 1179篇 |
2000年 | 1249篇 |
1999年 | 1061篇 |
1998年 | 954篇 |
1997年 | 866篇 |
1996年 | 914篇 |
1995年 | 764篇 |
1994年 | 625篇 |
1993年 | 548篇 |
1992年 | 498篇 |
1991年 | 405篇 |
1990年 | 362篇 |
1989年 | 306篇 |
1988年 | 280篇 |
1987年 | 234篇 |
1986年 | 225篇 |
1985年 | 213篇 |
1984年 | 159篇 |
1983年 | 113篇 |
1982年 | 114篇 |
1981年 | 79篇 |
1980年 | 68篇 |
1979年 | 65篇 |
1978年 | 42篇 |
1914年 | 45篇 |
1909年 | 42篇 |
1908年 | 40篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
2.
3.
4.
5.
Christiane Albrecht 《Analytical and bioanalytical chemistry》2008,390(5):1223-1224
6.
7.
Chengzhi Qi Mingyang Wang Qihu Qian Jianjie Chen 《Moscow University Mechanics Bulletin》2008,63(5):113-121
The formation mechanisms for the structural hierarchy in geological media are discussed. It is shown that the formation of such a hierarchy is caused by certain external and internal circumstances. The first ones consist in the fact that, because of external actions, the Earth’s poles continuously execute the translational and rotational motions responsible for a regular structure of rock fracture and for the appearance of the scale factor √2. The second ones consist in the fact that, under the action of many random factors and because of external actions, during the formation of geological media there appear dissipative structures and, hence, some self-similar fractal structures are formed. 相似文献
8.
Howard Robinson 《Acta Analytica》2005,20(3):7-10
Nicholas Nathan tries to resist the current version of the causal argument for sense-data in two ways. First he suggests that,
on what he considers to be the correct re-construction of the argument, it equivocates on the sense of proximate cause. Second
he defends a form of disjunctivism, by claiming that there might be an extra mechanism involved in producing veridical hallucination,
that is not present in perception. I argue that Nathan’s reconstruction of the argument is not the appropriate one, and that,
properly interpreted, the argument does not equivocate on proximate cause. Furthermore, I claim that his postulation of a
modified mechanism for hallucinations is implausibly ad hoc. 相似文献
9.
Zhaoqiang Lu Lin Cheng Jun Li Kai Zhang Song Yi Jingui Qin 《Journal of polymer science. Part A, Polymer chemistry》2004,42(4):925-932
The synthesis and structural characterization of a series of novel, fluorinated poly(phthalazinone ether)s containing perfluorophenylene moieties are described. The monomers, 4‐(4′‐hydroxyaryl)phthalazin‐1(2H)‐ones ( 2a – 2d ), were conveniently and efficiently synthesized from phenols and phthalic anhydride in two steps via 2‐(4′‐hydroxybenzoyl)benzoic acids, which were first obtained by the Friedel–Crafts reaction in good yields and with high stereoselectivity and were then converted into 2a – 2d by fusion with hydrazine. All the polymers were prepared by nucleophilic aromatic substitution (SNAr) polycondensation between the compounds perfluorobiphenyl and 4‐(4′‐hydroxyaryl)phthalazin‐1(2H)‐ones ( 2a ‐ 2d ). The resulting fluorinated polymers were readily soluble in common organic solvents (e.g., CHCl3, tetrahydrofuran, dimethylformamide, dimethyl sulfoxide, N‐methylpyrrolidone, etc.) at room temperature. Their weight‐average molecular weights and the polydispersities ranged from (7.96–18.25) × 103 to 1.31–2.71, respectively. Their glass‐transition temperatures varied from 213 to 263 °C. They were all stable up to 390 °C both in air and in argon. The 5% weight‐loss temperatures of these polymers in air and argon ranged from 393–487 to 437–509 °C, respectively. Wide‐angle X‐ray diffraction studies indicated they were all amorphous and could be attributed to the presence of kink nonplanar moiety, phenyl phthalazinone along the polymer backbone. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 925–932, 2004 相似文献
10.
Qi Wang Huaxiang Yang Zhiqiang Fan Hong Xu 《Journal of polymer science. Part A, Polymer chemistry》2004,42(5):1093-1099
Ethylisobutylaluminoxane (EBAO) and its analogues were synthesized by a reaction between an triethylaluminum (Et3Al)/triisobutylaluminum (i‐Bu3Al) mixture and 4‐fluorobenzeneboronic acid, phenylboronic acid, or n‐butaneboronic acid and subsequent hydrolysis with water. They were used as cocatalysts in ethylene polymerization catalyzed by an iron complex {[(ArN?C(Me))2C5H3N]FeCl2, where Ar is 2,6‐diisopropylphenyl}. Polyethylene with a high molecular weight and a narrow molecular weight distribution was prepared with modified EBAOs, and the performance of the iron complex at high polymerization temperatures was greatly improved. The activators for the iron complex also affected the polymerization activity and the molecular weight of the resultant polyethylene. It was suggested that the stereo and electronic effects of the substitute groups of aluminoxane contributed to the improved performance of the new activators. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 1093–1099, 2004 相似文献