全文获取类型
收费全文 | 152篇 |
免费 | 3篇 |
专业分类
化学 | 115篇 |
力学 | 3篇 |
数学 | 16篇 |
物理学 | 21篇 |
出版年
2022年 | 7篇 |
2021年 | 10篇 |
2020年 | 3篇 |
2019年 | 5篇 |
2018年 | 2篇 |
2017年 | 2篇 |
2016年 | 7篇 |
2015年 | 8篇 |
2014年 | 5篇 |
2013年 | 10篇 |
2012年 | 5篇 |
2011年 | 13篇 |
2010年 | 6篇 |
2009年 | 3篇 |
2008年 | 5篇 |
2007年 | 5篇 |
2006年 | 4篇 |
2005年 | 6篇 |
2004年 | 5篇 |
2003年 | 2篇 |
2002年 | 1篇 |
2001年 | 1篇 |
2000年 | 1篇 |
1999年 | 1篇 |
1998年 | 7篇 |
1997年 | 6篇 |
1994年 | 2篇 |
1993年 | 2篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1989年 | 2篇 |
1987年 | 1篇 |
1984年 | 6篇 |
1983年 | 2篇 |
1982年 | 1篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1979年 | 2篇 |
1972年 | 1篇 |
1962年 | 1篇 |
排序方式: 共有155条查询结果,搜索用时 15 毫秒
41.
Series of hydrates of the most stable glycine-H+/2H2+ in the gas phase are presented at the B3LYP level. The results show that only the amino hydrogens and hydroxyl hydrogens can be monohydrated for the glycine-H+, and the amino hydrogens are preferred. The H6(O4) of glycine-2H2+ is the best site for a water molecule to attach, i.e., the corresponding hydrate is the most stable one among its isomers. Calculations reveal that the binding energies of hydrated hydrogens decrease relative to their counterparts in the isolated glycine-H+/2H2+ complexes and they are positive values and without proton transfer except those of monohydrated glycine-2H2+ complexes with the combination modes of H3O+...(glycine-H+). The complex H3O+...(glycine-H+) is formed by the combination of a H2O molecule and one hydroxyl-site proton of glycine-2H2+, and with the proton transfer to H2O. Here the interaction between the proton of H3O+ and the glycine-H+ mainly depends on an electronic one instead of an initial covalent one of the isolated glycine-2H2+. The generation of the bond between the H3O+ and the glycine-H+ makes the energy of the complex higher than the energy sum of its two separated species (or two reactants of the complex), just like the case of M+...(glycine-H+) bond (M = Li,Na). The observation can explain satisfactorily why the combinations of both a proton and an alkali ion or two alkali ions to a glycine molecule can make the corresponding complex hold reservation energy bond(s), while the combination of two protons and a glycine in our previous work cannot [H. Ai et al., J. Chem. Phys. 117, 7593 (2002)]. For the glycine-2H2+, monohydration at the any site of its amino hydrogens can make the binding strength of any other neighboring proton (hydrogens) stronger relative to its counterpart in the isolated glycine-2H2+. Further hydration, especially at the site of either of hydroxyl hydrogens, would disfavor the reservation energy of the system. 相似文献
42.
43.
44.
45.
Ahmad Fawzi Alameddine 《Journal of Graph Theory》1980,4(4):417-422
Let p and C4 (G) be the number of vertices and the number of 4-cycles of a maximal planar graph G, respectively. Hakimi and Schmeichel characterized those graphs G for which C4 (G) = 1/2(p2 + 3p - 22). This characterization is correct if p ≥ 9. However, for p = 7 or 8, there is exactly one other graph which violates the theorem in the sense that the upper bound of C4 (G) is also attained. 相似文献
46.
Xiaolin Cai Bernard Riedl A. Ait‐Kadi 《Journal of Polymer Science.Polymer Physics》2003,41(17):2022-2032
The influence of the surface chemistry of the cellulose fiber and polymer matrix on the mechanical and thermal dynamic mechanical properties of cellulose‐fiber‐reinforced polymer composites was investigated. The cellulose fiber was treated either with a coupling agent or with a coupling‐agent treatment followed by the introduction of quaternary ammonium groups onto the fiber surface, whereas the polymer matrix, with opposite polar groups such as polystyrene incorporated with sulfonated polystyrene and poly(ethylene‐co‐methacrylic acid), was compounded with the fiber. The grafting of the fiber surface was investigated with Fourier transform infrared spectroscopy and X‐ray photoelectron spectroscopy. Experimental results showed that an obvious improvement in the mechanical strength could be achieved for composites with an ionic interface between the fiber and the polymer matrix because of the adhesion enhancement of the fiber and the matrix. The improved adhesion could be ascribed to the grafted ionic groups at the cellulose‐fiber surface. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 2022–2032, 2003 相似文献
47.
Mostafa Gamal A. E. Mahajumi Abu Syed AlRabiah Haitham Kadi Adnan A. Lu Yang Rahman A. F. M. Motiur 《Journal of fluorescence》2021,31(5):1489-1502
Journal of Fluorescence - Fluorescein (1), a known fluorescent tracer in microscopy with high photophysical properties, was esterified to have fluorescein ethyl ester (2) and O-ethyl-fluorescein... 相似文献
48.
49.
A C
0 continuity isoparametricfinite-element formulation is presented for the dynamic analysis of arotating or nonrotating beam with or without nonlinear boundaryconditions subject to a moving load. The nonlinear end conditions arisefrom nonlinear rolling bearings (both the nonlinear stiffness andclearance(s) are accounted for) supporting a rotating shaft. The shaftfinite-element model includes shear deformation, rotary inertia, elasticbending, and gyroscopic effect. Lagrange's equations are employed toderive system equations of motion which, in turn, are decoupled usingmodal analysis expressed in the normal coordinate representation. Theanalyses are implemented in the finite-element program DAMRO 1.Dynamic deflections under the moving load of rotating and nonrotatingsimply supported shafts are compared with those obtained using exactsolutions and other published methods and a typical coincidence isobtained. Samples of the results, in both the time and frequencydomains, of a rotating shaft incorporating ball bearings are presentedfor different values of the bearing clearance. And the results show thatsystems incorporating ball bearings with tight (zero) clearance have thesmallest amplitude-smoothest profile dynamic deflections. Moreover, fora system with bearing clearance, the vibration spectra of the shaftresponse under a moving load show modulation of the system naturalfrequencies by a combination of shaft rotational and bearing cagefrequencies. However, for a simply supported rotating shaft, the firstnatural frequency in bending dominates the response spectrum. The paperpresents the first finite-element formulation for the dynamic analysisof a rotating shaft with or without nonlinear boundary conditions underthe action of a moving load. 相似文献
50.
Issa M. El Nahhal Shehata M. Zourab Fawzi S. Kodeh 《Journal of Dispersion Science and Technology》2013,34(3):379-383
Encapsulation of bromothymol blue (BTB) into a polysiloxane network was prepared using sol-gel method without using a catalyst. The co-entrappment of the bromothymol blue (BTB) and surfactant cetyltrimethyl ammonium bromide (CTAB) was used to modify the properties of the sol-gel matrixes which may provide a highly porous materials and made the polysiloxane network an excellent host for sensing molecules. Monolithic disks of trapped BTB were obtained with no leaching. Polarized light microscopy shows that a almost unique particle sizes distributions were formed. The immobilized BTB shows a response for various pH solutions, the feature of absorption spectra of the immobilized BTB was almost the same as that of the solutions. 相似文献