Challenges to develop single-column MA(III) separation from HLLW using R-BTP type adsorbents

In order to directly separate trivalent minor actinides(MA:Am,Cm) from fission products(FP) containing rare earths(RE) in high level radioactive liquid waste(HLLW),the authors have challenged to develop a simplified MA separation process by extraction chromatography using a single column.Attention has been paid to a new type of nitrogen-donor ligands,R-BTP(2,6-bis(5,6-dialkyl-1,2,4-triazin-3-yl) pyridine,R:alkyl group) as an extractant because it shows high extraction selectivity for Am(Ⅲ) over RE(Ⅲ).It is known that the R-BTP ligands show different properties such as adsorbability and stability by having different alkyl groups.Therefore,some novel adsorbents were prepared by impregnating different types of R-BTP ligands(isohexyl-,isoheptyl-and cyheptyl-BTP) and a similar ligand to the R-BTP,ATP(2,6-bis(1-aryl-1H-tetrazol-5-yl)pyridines),into the porous silica/polymer support(SiO2-P particles).This work deals with comparison in adsorption and desorption properties of Am and some FP in HNO 3 solution onto such R-BTP type adsorbents,as well as chemical and radiolytic stability of the adsorbents.Then the possibility of a single-column separation of MA from main FP was pursued by evaluating the results of column experiments using the most promising adsorbent(isohexyl-BTP/SiO2-P) under temperature control.In addition,elution behaviors of U and Pd were also estimated.     

沙粒粒径在水平水流中对湍流调制及减阻效应的影响作用

运用基于欧拉-欧拉方法的混合欧拉多相流模型结合雷诺应力湍流模型,对较大雷诺数下的水平固液两相湍流进行了数值计算,主要考察了以Kolmogorov尺度(约为2v/ur)为临界值的细小沙粒颗粒在5％的固相体积分数下对湍流场的调制及其减阻效应.研究发现,无量纲颗粒直径dp+≤2的小颗粒减小了固液两相湍流的雷诺应力,并且三个方向上的速度脉动也被不同程度地削弱;而dp+=4的大颗粒使缓冲层区域的雷诺应力稍增大,在增强法向速度脉动的同时对流向脉动有抑制作用,并且值得关注的是,较大颗粒的存在导致缓冲层中的部分区域出现了流变现象.在减阻方面,较小的颗粒(dp+≤2)有大致相同的减阻表现,而大颗粒(dp+=4)已经失去了减阻性能,总体上看,在所研究的情形下微颗粒的减阻性能随着其粒径的增大而降低.     

柔性透明石墨烯膜制备及导电性能研究

本文通过液相化学还原和热还原联合作用制备了柔性透明导电石墨烯膜.阳极氧化铝(AAO)模板在制备过程中既作为抽滤的滤网,又作为热还原处理时支撑石墨烯膜的衬底,制成的柔性透明石墨烯膜对波长为540—840 nm的可见光透光率为80%,面电阻为850 Ω/平方,这与化学气相沉积法制备的石墨烯膜(280—770 Ω/平方)相近,而低于溶液法制备的石墨烯膜(通常是10³—10⁴ Ω/平方).     

Highly Concise Synthesis of 3'-"Up"-ethynyl-5'-methylbicyclo-[3.1.0]-hexyl Purine and Pyrimidine Nucleoside Derivatives Using Rhodium(II) Carbenoid Cycloaddition and Highly Diastereoselective Grignard Reaction

Synthesis of north‐5'‐methylbicyclo[3.1.0]hexyl purine and pyrimidine nucleosides with an ethynyl group at C‐3' position has been successfully accomplished by a facile method. Methylbicyclo[3.1.0]hexanone (±)‐ 5 having three contiguous chiral centers was remarkably simply constructed only by four steps containing a carbenoid insertion reaction in the presence of rhodium(II) acetate dimer and CuSO₄, giving a correct relative stereochemistry of the generated three chiral centers. Upon Grignard reaction of (±)‐ 5 with ethynylmagnesium bromide, exclusive diastereoselectivity was observed. Condensation of glycosyl donor (±)‐ 9 with purine nucleobase afforded only the desired N⁹‐alkylated nucleoside, while condensation with pyrimidine, N³‐benzoylated uracil gave the desired N¹‐alkylated nucleoside (±)‐ 13 with the undesired O²‐alkylated nucleoside (±)‐ 14 . Probably, (±)‐ 14 would be formed due to steric hindrance caused upon approaching for N¹‐alkylation.     

浦项中子装置上209Bi中子全截面测量(英文)

在浦项中子装置(PNF) 的100 MeV电子直线加速器上利用透射法和飞行时间法测量了209Bi 的0.1~100 eV的中子全截面。文中对于实验装置特点、用吸收片法拟合本底、拟合中子飞行距离和时间零点的处理过程做了较为详细的描述。测量结果与以前发表的实验数据以及评价数据ENDF/B-VII.1 做了比较,比较结果符合得较好。     

Atomic Diffusion in Cu/Si （111） and Cu/SiO2/Si （111） Systems by Neutral Cluster Beam Deposition

The Cu films are deposited on two kinds of p-type Si （111） substrates by ionized duster beam （ICB） technique. The interface reaction and atomic diffusion of Cu/Si （111） and Cu/SiO2/Si （111） systems are studied at different annealing temperatures by x-ray diffraction （XRD） and Rutherford backscattering spectrometry （RBS）. Some significant results are obtained： For the Cu/Si （111） samples prepared by neutral dusters, the interdiffusion of Cu and Si atoms occurs when annealed at 230℃. The diffusion coefficients of the samples annealed at 230℃ and 500℃ are 8.5 ×10^-15 cm^2.s^-1 and 3.0 ×10^-14 cm^2.s^-1, respectively. The formation of the copper-silicide phase is observed by XRD, and its intensity becomes stronger with the increase of annealing temperature. For the Cu/SiO2//Si （111） samples prepared by neutral dusters, the interdiffusion of Cu and Si atoms occurs and copper silicides are formed when annealed at 450℃. The diffusion coefficients of Cu in Si are calculated to be 6.0 ×10^-16 cm^2.s^-1 at 450℃, due to the fact that the existence of the SiO2 layer suppresses the interdiffusion of Cu and Si.     

Direct Observation of Tunnelling through 100-nm-Wide All Metal Magnetic Junction into Si

Nanoscaled spin-dependent tunnelling lines were patterned on doped Si and studied for tunnelling from the SDT ferromagnetic layer through an insulating barrier into Si. The injection contacts have the form of long strips with width and separation, ranging from 100 nm to 2 μm, and are patterned using e-beam lithography. The measured I-V characteristics versus temperature （80 to 300K） on the 100 nm scaled devices between the layered-magnetic metals and the semiconductor clearly showed ballistic tunnelling, with weak dependence on the temperature. This is qualitatively different, at elevated temperatures, from 2-μm-wide scaled-up spin-dependent tunnelling structures, where thermal-ionic emission was observed to dominate carrier transport.     

SOUND TRANSMISSION THROUGH PERIODICALLY STIFFENED CYLINDRICAL SHELLS

A relatively long circular cylindrical shell stiffened by periodically deployed stiffeners is found in many practical applications such as the aircraft fuselage. For the sound transmission analysis of such a system, not only structural interactions between the shell and stiffeners but also vibro-acoustic interactions between the structure and acoustic media have to be considered. By idealizing the system as an infinitely long cylinder subjected to a plane wave incidence, an exact solution is obtained for the first time for this type of problem. In the analysis, the solution is obtained in a series form by expanding the system responses in terms of the space harmonics of the stiffener spacing. Characteristics of the system responses and effects of important design parameters are studied using the transmission losses calculated from the analysis.