金属羰基化合物（CpFe（CO）2）2与金属氧化物表面作用的傅里叶变…

用漫反射红外光谱和光声红外光谱研究了金属羰基化合物（ＣｐＦｅ（ＣＯ）２）２Ｃｐ＝η＾５－Ｃ５Ｈ５与酸性，中性和碱性Ａｌ２Ｏ３及ＴｉＯ２的相互作用，结果表明，在Ａｌ２Ｏ３表面生成的洗生物种类及浓度与Ａｌ２Ｏ３的酸碱度明显相关，在酸性Ａｌ２Ｏ３表面，主要存在衍生物（ＣｐＦｅ（ＣＯ）２Ｆｅ－Ｈ－Ｆｅ（ＣＯ２Ｃｐ）＾＋及少量的ＣｐＦｅ（ＣＯ）２（－Ｏ－）；在中性Ａｌ２Ｏ３表面存在的ＣｐＦｅ（ＣＯ）２（－Ｏ     

类金钢石非晶碳薄膜的光吸收和光致发光研究

我们用激光轰击石墨靶成功地制备出类金刚石无氢非晶碳薄膜.测量了光学吸收、光致发光及其随入射光强度的变化关系.结果表明,这种薄膜具有类金刚石的性质,光学带隙在1.67-2.25eV,发光在可见光区呈宽带结构.低激发强度下发光强度超线性变化,而在高激发强度下则为线性发光.我们用非成对载流子复合的模型对结果给出了合理的解释.用带尾态饱和的模型解释了发光峰值随激发光强增加而蓝移的现象.     

用激活性非线性介质Nd：MgO：LiNbO3产生二次谐波

以Nd:MgO:LiNbO_3同时兼作激活介质和非线性光学材料,研究自倍频激光器。用小型氙灯泵浦,在室温下获得二次谐波激光(0.547μm) 阈值小于4.8'J,最大输出400μJ/shot,工作温度范围大于20℃～45℃,无光损伤。     

Analysis of dispersion characteristics of groove guides with mode-matching method

Groove guide is widely recognized as one of the most promising millimeter wave transmission structures. In this paper, the mode-matching method is used to analyse the dispersion characteristics of single and asymmetrical double groove guides, and the unified formulae of Nth-order approximation dispersion equations are presented. Based on this analysis, a general program for calculating the dispersion characteristrics of single and asymmetrical double groove guides has been completed. Some comparisons between the results obtained by present method and published data show that very good agreement has been seen. The effectiveness and the reliability of the given formulae and program are thus verified.     

钴（Ⅱ）—丁二酮单肟烟酰腙—亚硝酸盐体系的伏安行为及其应用

在氨性介质中(pH=9.0),钴(Ⅱ)-丁二酮单肟烟酰腙(DMNH)-亚硝酸盐体系可产生灵敏度很高的催化波。从体系的伏安行为可知,吸附于汞电极上的是混配的配盐NH_4[Co(Ⅱ)(DMNH)·(NO_2)_2],在-1.0 V(相对SCE)处,Co(Ⅱ)被还原至Co(0),DMNH被还原成自由基,由于NO_2~-的存在,自由基可参与再生反应而形成催化波。羟氨的存在可使产生催化波的最佳pH值移至8.2.用此体系进行了生物样品中钴的测定,其检出限为1×10~(-10)mol/L。     

叶绿素A较高激发态的发光

采用激发样品表层和样品中心两种激发方式,在300K和77K温度下研究叶绿素A(Chla)的较高激发行为,观测到峰值位于493、520和580nm三条新的荧光发射带.分别测量它们的荧光激发光谱,证明这三条新的荧光带属于Chla的第二激发单线态向基态的不同振动能级的辐射跃迁发光.最后提出电子跃迁模型,同时进行了讨论.     

Four-wave mixing based 10-Gb/s tunable wavelength conversion in dispersion-flattened microstructure fibers

All-optical wavelength conversion of 10-Gb/s signal based on four-wave mixing is experimentally demonstrated in a 30-m-long dispersion-flattened microstructure fiber with small positive dispersion. For an average pump power of 26 dBm, the conversion efficiency was around -19.5 dB with the fluctuation less than ±1.4 dB, covering a conversion bandwidth of 20 nm. The eye diagram of the converted signal shows good eye opening.     

Growth and optical properties of a new self-Q-switched laser crystal: Cr:Yb3Al5O12

Cr⁴⁺:YbAG (Cr⁴⁺:Yb₃Al₅O₁₂) crystal with a size up to Φ24 mm×30 mm was grown by the Czochralski method. In the absorption spectrum, there are two absorption bands at 939 and 969 nm, respectively, which are suitable for InGaAs diode laser pumping, and there is an absorption band at 1030 nm, which is suitable for passive Q-switched laser output at 1.03 μm. A broad emission spectrum from 970 to 1100 nm was exhibited from 940 nm wavelength pumping. This crystal is promising as a self-Q-switched laser crystal used for compact, efficient, highly stable, passive self-Q-switched thin chip solid-state lasers.     

Transfer matrix approach of vibration isolation analysis of periodic composite structure

The transmission properties of elastic waves propagating in a three-dimensional composite structure embedded periodically with spherical inclusions are analyzed by the transfer matrix method in this paper. Firstly, the periodic composite structures are divided into many layers, the transfer matrix of monolayer structure is deduced by the wave equations, and the transfer matrix of the entire structure is obtained in the case of boundary conditions of displacement and stress continuity between layers. Then, the effective impedance of the structure is analyzed to calculate its reflectivity and transmissivity of vibration isolation. Finally, numerical simulation is carried out; the experiment results validate the accuracy and feasibility of the method adopted in the paper and some useful conclusions are obtained. Project (No. 50075029) supported by the National Natural Science Foundation of China.