Determination of Mercury by Inductively Coupled Plasma—Mass Spectrometry

To control the amount of mercury polluting our environment, mercury has to be monitored in all areas of modern life. This requires fast and easy-to-use methods that permit the determination of mercury at levels of micrograms per liter. Up to now mercury ultratrace determination has required preconcentration or amalgamation in order to improve detection limits. This decreases accuracy of determination, introducing a longer manipulation of the sample. Inductively coupled plasma—mass spectrometry (ICP-MS) allows a direct determination of ultratrace mercury, due to the choice of interference free isotopes by the mass spectrometer detector. In fact, the detection limit for mercury by ICP-MS is 0.001 ppb. In the present work results of Hg determinations in different matrices by ICP-MS are reported. ICP-MS technique results are better than those of FIMS-100. This technique is applicable to different solid (minerals and atmospheric particulate) and liquid matrices with elimination of interferences. For solid matrices methods of attack and dissolution are reported.     

Superscaling in charged current neutrino quasielastic scattering in the relativistic impulse approximation

Superscaling of the quasielastic cross section in charged-current neutrino-nucleus reactions at energies of a few GeV is investigated within the framework of the relativistic impulse approximation. Several approaches are used to describe final-state interactions and comparisons are made with the plane-wave approximation. Superscaling is very successful in all cases. The scaling function obtained using a relativistic mean field for the final states shows an asymmetric shape with a long tail extending towards positive values of the scaling variable, in excellent agreement with the behavior presented by the experimental scaling function.