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101.
Determination of Organophosphorus Pesticides in Soil by MMSPD-GC-NPD and Confirmation by GC-MS 总被引:1,自引:0,他引:1
A novel method, modified matrix solid-phase dispersion (MMSPD), has been developed for quantitative analysis of organophosphorus
pesticide residues in soil. It was based on matrix solid-phase dispersion (MSPD) and continuous liquid-solid extraction (continuous
LSE), using Florisil as sorbent and dichloromethane as the recycling solvent. Two soils with different texture and physicochemical
properties were studied to validate the method. The effect of residence time of pesticides in soil was also studied. MMSPD
was compared with MSPD and continuous LSE respectively. Determination was carried out by gas chromatography with nitrogen-phosphorus
detection (GC-NPD). The method gave recoveries ranging from 72–105% with relative standard deviations (RSDs) lower than 15%
for the pesticides studied. The limits of detection (LODs) ranged from 0.1 to 0.6 ng g−1. Two pesticide residues have been detected in real soil samples from Fujian, China, using MMSPD. The pesticides were confirmed
by gas chromatography-mass spectrometry (GC-MS) in a selected-ion monitoring (SIM) mode.
Revised: 4 and 9 April 2006 相似文献
102.
Yongsong Luo Xiaohong Xia Yonggang Zhang Jialin Li Zhijie Jia 《Journal of solid state chemistry》2007,180(6):1928-1933
Luminescence of the short multiwalled carbon nanotubes (MWNTs) conjugated with carboxylic acid groups has been studied. The results show that the carboxyl-functionalized short MWNTs could emit luminescence and the emission peak appears at 500 nm with a corresponding optimal excitation wavelength centering at 310 nm. When the short MWNTs are filtered through 0.15 μm polytetrafluoroethylene (PTFE) membrane, the ultrashort MWNTs are obtained from the filtrate. An interesting feature for the ultrashort MWNTs is that the emission intensity is strengthened and the peak is slightly blue shifted to 460 nm. This result indicates that the luminescence properties of MWNTs are strongly affected by the tube length. After chemical oxidization cutting, defects and carboxylic acid groups at the tube end and/or sidewall can be produced; the more shorten of MWNTs, the better dispersion and carboxylic passivation of the nanotubes, and the more intense luminescence emissions. The broad emissions are logically attributed to the trapping of excitation energy by defect sites in the carboxyl-functionalized nanotube structure. 相似文献
103.
In the present paper, we describe a microfluidics-based sensing system for nonelectroactive anions under negative separation electric field by mounting a single carbon fiber disk working electrode (WE) in the end part of a poly(dimethylsiloxane) microchannel. In contrast to work in a positive separation electric field described in our previous paper (Anal. Chem. 2004, 76, 6902-6907), here the electrochemical reduction reaction at the WE is not coupled with the separation high-voltage (HV) system, whereas the electrochemical oxidation reaction at the WE is coupled with the separation HV system. The electroactive indicator is the carbon fiber WE itself but not dissolved oxygen. This provides a convenient and sensitive means for the determination of nonelectroactive anions by amperometry. The influences of separation voltage, detection potential, and the distance between the WE and the separation channel outlet on the response of the detector have been investigated. The present detection mode is successfully used to electrochemically detect F-, Cl-, SO4(2-), CH3COO-, H2PO4-. Based on the preliminary results, a detection limit of 2 microM and a dynamic range up to three orders of magnitude for Cl- could be achieved. 相似文献
104.
钯(Ⅱ)-芳香氮碱-氨基酸三元配合物中的电子效应和芳环堆积作用 总被引:3,自引:0,他引:3
用pH-电位滴定法测定了Pd(L)(Aa)+三元配合物及相应的二元配合物,在25±0.5℃,30%的乙醇水溶液(体积分数),I=0.1(KNO3)条件下的稳定常数及表征常数。其中L=邻菲罗啉(phen)、苯并咪唑邻菲罗啉(PIP)、邻菲罗啉-5,6-二酮(dophen)、2,9-二甲基邻菲罗啉(dmphen)和联吡啶3,3′-二羧酸(BDA);Aa为甘氨酸(gly)、苯丙氨酸(phe)、酪氨酸(tyr)、S-苄基-半胱氨酸(bcys)、谷氨酰胺(glu)和γ-谷氨酰-α-萘胺(gnapa)。从配合物配体间的电子效应和芳环堆积等观点对配合物的附加稳定性进行了讨论,并计算了电子效应和芳环堆积效应各自对三元配合物附加稳定性的贡献。 相似文献
105.
A simple and sensitive fluorimetric method for the determination of ascorbic acid (AA) is described. The method is based on the condensation reaction between AA and o-phenylenediamine (OPDA) in the absence of the oxidant. The fluorescence intensity is measured at excitation and emission wavelengths of 360 and 430 nm, respectively. Under optimum condition, a linear relationship is obtained between the fluorescence intensity and the concentration of AA in the range of 0.05-40 μg ml−1. The detection limit is 0.006 μg ml−1, which is obviously lower than that of other fluorimetric methods reported. 相似文献
106.
Raman spectroscopic analysis of supersaturated aqueous solution of MgO.B2O3-32%MgCl2-H2O during acidification and dilution 总被引:1,自引:0,他引:1
Zhihong L Bo G Shuni L Mancheng H Shuping X 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2004,60(13):3125-3128
Raman spectra of supersaturated aqueous solution of MgO.B2O3-32%MgCl2-H2O during acidification/alkalization and dilution have been studied. The assignments of the recorded Raman shift are given. The main existing forms of polyborate anions and their interaction in borate aqueous solution have been proposed through spectroscopic analysis. The experimental results indicate that the higher concentration of cation are beneficial not only to the dissolution of boric acid but also to the polymerization of polyborate anions. The existing forms and interaction among them also depend on the concentration of boron and the pH value in solution. 相似文献
107.
ShuXiaCAO JianChenZHANG JunXU XinChengLIAO YuFenZHAO 《中国化学快报》2004,15(7):817-820
Hydrolysis procedure of N-phosphoryl phenylalanine (DIPP-Phe) was studied by HPLC-ESI-MS/MS. The results showed that (HO)(i-PrO)P(O)Phe was the main intermediate and the hydrolysis of DIPP-Phe also occurred through a penta-coordinate transition state. 相似文献
108.
微乳液介质—1—(2—吡啶偶氮)—2—萘酚光度法测定汽油中环烷酸铁的含量 总被引:8,自引:2,他引:8
本研究了微乳液为介质时,铁与1-(2-吡啶偶氮)-2-萘酚(PAN)的显色反应。选择730nm处为测定波长,ε为1.4×10^4L.mol^-^1.cm^-^1,铁量在0-50μg/25ml范围内符合比耳定律,该法适用于汽油中环烷酸铁的测定。 相似文献
109.
Chen Xia DU Zhi Qiang WANG Qi XIN Yang Jie WU Wen Lian LI Department of Chemistry Zhengzhou University Zhengzhou Changchun institute of optics Fine Mechanics Physics Chinese Academy of Sciences Changchun 《中国化学快报》2005,(5)
In recent years, the interest in developing luminescent lanthanide complexes has been greatly stimulated by their potential use in electroluminescent displays1. Europium complexes appear most attractive in view of the high photoluminescent efficiency and the high monochromatic red light that are widely exploited in full-color displays2. It has been approved that the second ligand plays an important role in europium complexes, the synergistic complexation of the second ligand can not only lead … 相似文献
110.
有机磷配位铐或钴联基配合物是生产难或醇的工业催化剂,一般公认金属氢化物是反应的催化活性物种.通常反应活性物种仅存在干反应状态下,其结构表征非常困难,在许多研究中只能关联催化剂母体与其活性的关系[‘1;而未能揭示出催化的本质,给催化剂设计造成很大困难,因而对催化剂活性物种的直接表征受到普遍关注.B。wn问、Morrista]及本文作者研究组*均采用加压原位红外光谱方法,在烯烃氢甲酸化反应条件下捕捉到HCO(CO)3L存在的信息·但用相同方法在反应条件下,在RhH键特征吸收谱带195O-2200Cm‘内未观测到错氢化物的Rh-… 相似文献