Pr_(0.15)Tb_(0.85)Fe_(1.9)B_x内禀磁致伸缩的测量与分析

利用电弧熔炼法制备了Pr_(0.15)Tb_(0.85)Fe_(1.9)B_x系列样品,通过X射线衍射法对粉末样品的(440)衍射峰进行精细步进扫描并拟合数据,分析获得样品的内禀磁致伸缩λ_(111),通过电阻应变片法测得块状样品在外加磁场下的磁致伸缩值变化趋势,外推得到宏观饱和磁致伸缩值λ_s,并从Laves相晶体结构特性出发对两者进行详细比较对照和进一步深化分析.结果表明,常温下Pr在Laves相化合物中对磁致伸缩具有较大的贡献,适量B的掺入可以增加Pr在Laves相化合物中的含量且不降低材料的磁致伸缩性能.     

磁性Fe3O4纳米晶制备及应用

磁性Fe₃O₄纳米晶由于其独特的磁性能,已在许多领域得到了广泛的应用,并且在不同的应用领域其制备方法也不尽相同。本文综述了近年来磁性Fe₃O₄纳米晶的液相制备方法,如沉淀法、溶剂热法、溶胶-凝胶法、微乳液法、微波超声法等研究进展,对这些制备方法的特点进行了归纳概括,并详细分析了制备工艺中不同影响因素对Fe₃O₄纳米晶结构与性能的影响。同时,对磁性Fe₃O₄纳米晶在磁流体、微波吸收、污水处理、催化、药物载体、生物酶固定、生物传感器等方面的应用及发展趋势进行了评述,以期对Fe₃O₄纳米晶的制备及应用有较全面的认识。     

Thermoelectric and topological properties of half-Heusler compounds ZrIrX(As,Sb, Bi)

The strain dependent electronic structures, thermoelectric and topological properties of the half-Heusler compounds ZrIrX(X=As, Sb, Bi) are investigated by the first-principle calculations. At the equilibrium lattice constants, all the three compounds are trivial insulators and good thermoelectric materials with the Seebeck coefficient S and the power factor over relaxation time $S^2\sigma /\tau$ as large as 1180 (μV/K) and 4.1 (${10}^{11}W{m}^{?1}{K}^{?2}{s}^{?1}$), respectively. The compressive strain enhances the band gap, while the tensile strain decreases the band gap. At some specific tensile strains, the compounds become Dirac-semimetals, with the s-type band ${\mathrm{\Gamma }}_6$ below p-type band ${\mathrm{\Gamma }}_8$, in the cubic phase. When we compress the a(b)-axis and elongate the c-axis of the compounds, they become the type-I Weyl semimetals. For ZrIrAs, the eight Weyl-Points (WPS) locate at (± K_x, 0, ± K_z), (0, ± K_y, ± K_z), ${\mathrm{K}}_x={\mathrm{K}}_y=0.008{\mathrm{\AA }}^{?1}$, ${\mathrm{K}}_z=0.043{\mathrm{\AA }}^{?1}$.     

低速冲击下纤维/金属层合板抗分层性能研究

论文采用内聚力模型,对纤维/金属层合板(FMLs)在低速冲击载荷作用下抗分层性能进行研究.内聚力模型对裂纹的模拟具有它独特的优势:一是该模型不需要预先假设初始缺陷;二是在计算过程中随着裂纹的扩展,该方法不需要重新对结构进行网格划分.借助该模型,论文对低速冲击载荷作用下,纤维层合板(FRP)分层进行了模拟,并验证了该模型计算的有效性.在此基础上,论文研究了低速冲击载荷作用下,不同金属含量的纤维/金属层合板抗分层性能,并与纤维层合板进行了比较.最后从能量的角度讨论了金属含量与铺层结构对FMLs低速冲击性能的影响.     

蔬菜种子干燥中种皮的效应与优化传热传质机理

1前言含水率大的种子在贮存过程中极易发生劣变，使发芽力与发芽势降低山。种子干燥是一个复杂的传热传质过程，而且还涉及到生命力保存的问题。虽然种子的形态存有差异，但是种子的基本结构都是一致的。一般都由胚、胚乳和种皮三部分组成。种皮对种子具有保护与协调的功能，其透气性与透水性决定了种皮是种子与周围环境进行质量与能量交换的必经之路。为此本文综合种子的生物生理特性研究了蔬菜种子干燥中种皮的作用，并结合种皮的生物学功能探讨了优化传热传质的机理。2种皮对干燥的影响实验装置见文献［2］，采用在线测量的方法可连续检…     

Combined formation and decomposition of dual-metal amidoborane NaMg(NH2BH3)3 for high-performance hydrogen storage

As a consequence of the combination of the formation and decomposition reactions of NaMg(NH(2)BH(3))(3), the 3NH(3)BH(3)/NaMgH(3) mixture can rapidly release ca. 10 wt.% of hydrogen at 80 °C within 2 min.     

Measurements of dynamic properties of concrete structures using flexural wave propagation characteristics

Flexural wave propagation characteristics influence the impact noise generation of concrete structures that are found in building floors, railroads, bridges, and many other engineering structures. The flexural vibration of the structure is affected by concrete dynamic properties. The purpose of this study is to measure the concrete dynamic characteristics using a wave propagation approach. The flexural wave speeds, bending stiffness and their loss factors were measured. The measured characteristics are essential for understanding sound radiation and vibration dissipation capabilities of the concrete structures. Various concrete beam structures were made and tested. The dynamic stiffness and loss factor were influenced by its components and showed frequency-dependent variation, especially for the measured loss factor.     

Determination of polyamines in human urine by precolumn derivatization with benzoyl chloride and high-performance liquid chromatography coupled with Q-time-of-flight mass spectrometry

A simple and sensitive HPLC/Q-TOF MS method for simultaneous determination of 1,3-diaminopropane, putrescine, cadaverine, spermidine, spermine and acetyl-spermine in human urine was developed in electrospray-ionization source by positive ion mode. The samples were firstly pretreated by 10% HClO₄ and then derivatized by benzoyl chloride with 1,6-diaminohexane as internal standard. The derived polyamines were separated on a C₁₈ column by a gradient elution with methanol-water, and then sensitively detected with Q-TOF MS. The limits of detection for polyamines ranged from 0.02 to 1.0 ng ml⁻¹ with excellent linearity within the range from 1 to 1000 ng ml⁻¹ except acetyl-spermine from 5 to 1000 ng ml⁻¹. The intra- and inter-day R.S.D. for all polyamines were 2.0-14.7% and 3.9-12.9%, respectively. The method was applied to determine the polyamines in human urine from 10 cancer patients and 15 healthy volunteers. Results showed that the mean levels of polyamines in urine of patients were all higher than those in healthy volunteers. The cluster analysis was used to establish the distinction mode between cancer sufferers and healthy individuals.     

Measurement of viscoelastic properties from the vibration of a compliantly supported beam

A laboratory method is presented by which the viscoelastic properties of compliant materials are measured over a wide frequency range. The test setup utilizes a flexible beam clamped at one end and excited by a shaker at the free end. A small specimen of a compliant material is positioned to support the beam near its midpoint. The deformation from gravity is minimized since the specimen is not loaded by an attached mass. Forced vibration responses measured at two locations along the beam are used to derive a transfer function from which the dynamic properties of compliant materials are directly determined by use of a theoretical procedure investigating the effects of specimen stiffness on the propagation of flexural waves. Sensitivity of the measured properties to experimental uncertainties is investigated. Young's moduli and associated loss factors are determined for compliant materials ranging from low-density closed-cell foams to high-density damping materials. The method is validated by comparing the measured viscoelastic properties to those from an alternative dynamic test method.     

Synthesis and Properties of Polyacrylamide-Based Conducting Gels with Enhanced Mechanical Strength

A nanocomposite conducting hydrogel, polyacrylamide/MWNT/clay (abbreviated as PAM/MWNT/clay), prepared through in situ free radical aqueous polymerization and crosslinked by both clay, as a functional physical crosslinker, and N,N′-methylenebisacrylamide (MBA) as a chemical crosslinker, is reported. The morphology of the gels was characterized by scanning electron microscopy (SEM). The mechanical properties and electrical conductivity were also studied. The results show that the prepared hydrogels had the expected chemical components, with a highly porous structure, and the gels also showed high mechanical strength. The mechanical strength and electrical conductivity value increased with increasing content of multi-walled nanotube (MWNT), and decreased with increasing content of water.