全文获取类型
收费全文 | 10432篇 |
免费 | 441篇 |
国内免费 | 56篇 |
专业分类
化学 | 7389篇 |
晶体学 | 114篇 |
力学 | 223篇 |
数学 | 827篇 |
物理学 | 2376篇 |
出版年
2023年 | 71篇 |
2022年 | 196篇 |
2021年 | 239篇 |
2020年 | 187篇 |
2019年 | 189篇 |
2018年 | 154篇 |
2017年 | 156篇 |
2016年 | 303篇 |
2015年 | 285篇 |
2014年 | 370篇 |
2013年 | 645篇 |
2012年 | 746篇 |
2011年 | 837篇 |
2010年 | 510篇 |
2009年 | 461篇 |
2008年 | 724篇 |
2007年 | 622篇 |
2006年 | 635篇 |
2005年 | 519篇 |
2004年 | 472篇 |
2003年 | 394篇 |
2002年 | 424篇 |
2001年 | 261篇 |
2000年 | 210篇 |
1999年 | 152篇 |
1998年 | 90篇 |
1997年 | 77篇 |
1996年 | 90篇 |
1995年 | 88篇 |
1994年 | 60篇 |
1993年 | 69篇 |
1992年 | 67篇 |
1991年 | 38篇 |
1990年 | 59篇 |
1989年 | 59篇 |
1988年 | 28篇 |
1987年 | 31篇 |
1986年 | 16篇 |
1985年 | 49篇 |
1984年 | 32篇 |
1983年 | 27篇 |
1982年 | 32篇 |
1981年 | 24篇 |
1980年 | 23篇 |
1979年 | 13篇 |
1978年 | 19篇 |
1977年 | 24篇 |
1976年 | 12篇 |
1975年 | 14篇 |
1970年 | 19篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
21.
Il Bong Jung Alan Lambert Jan Stochel 《Proceedings of the American Mathematical Society》2004,132(8):2291-2302
The concept of backward extension for subnormal weighted shifts is generalized to arbitrary subnormal operators. Several differences and similarities in these contexts are explored, with emphasis on the structure of the underlying measures.
22.
A new chemiluminescence method for the determination of carbamazepine (CBZ) has been developed. The method is based on the chemiluminescence produced in the reaction of tris(2,2'-bipyridine)ruthenium(III) and CBZ in an acidic medium. The chemiluminescence intensity was enhanced by organic solvents in the reaction system. Under the optimum experimental conditions, the calibration curve was linear over the range 4.0 x 10(-3)-8.6 x 10(-7) mol/L for CBZ. The detection limit (S/N = 3) was 2.5 x 10(-7) mol/L and the relative standard deviation of six replicate measurements was 2.6% for 4.0 x 10(-4) mol/L of CBZ. The possible reaction mechanism were also discussed. The chemiluminescence method was successfully applied to assay the CBZ contents in pharmaceutical tablets. 相似文献
23.
Hyun Chul Choi Min Kyu Lee Hyun Joon Shin Seung Bin Kim 《Journal of Electron Spectroscopy and Related Phenomena》2003,130(1-3):85-96
To investigate the formation of a solid electrolyte interface (SEI) on the Li1+xV3O8 electrode surface in the thermodynamic stability range of the organic electrolyte, we applied scanning photoelectron microscopy (SPEM) to a pristine electrode and to an electrode after ten cycles. The F K-edge absorption spectrum of the cycled electrode showed that LiF forms on the electrode surface during the lithium insertion–extraction process in the Li1+xV3O8/Li cell. The photoelectron spectrum for the cycled electrode showed intense spectral features corresponding to Li 1s, F 2s, F 2p, and P 2p electron signals, whereas these spectral features were of negligible intensity for the pristine electrode. The above results give strong support for the formation of an SEI that consists of LiF and compounds containing phosphorus during operation of the battery. The SPEM images also revealed that the fluorine distribution on the surface of the cycled electrode was inhomogeneous. 相似文献
24.
We establish some liminf theorems on the increments of a (N,d)-Gaussian process with the usual Euclidean norm, via estimating upper bounds of large deviation probabilities on the suprema
of the (N,d)-Gaussian process.
This revised version was published online in June 2006 with corrections to the Cover Date. 相似文献
25.
Yong‐Jin Kim Jin‐Woong Kim Jung‐Eun Lee Jee‐Hyun Ryu Junoh Kim Ih‐Seop Chang Kyung‐Do Suh 《Journal of polymer science. Part A, Polymer chemistry》2004,42(22):5627-5635
Mesoporous polymer microspheres with gold (Au) nanoparticles inside their pores were prepared considering their surface functionality and porosity. The Au/polymer composite microspheres prepared were characterized by transmission electron microscope (TEM), X‐ray diffraction (XRD), and Brunauer–Emmett–Teller (BET) techniques. The results showed that the adsorption of Au nanoparticles could be increased by imparting the pore structure and surface‐functional groups into the supporting polymer microspheres (in this study, poly (ethylene glycol dimethacrylate‐co‐acrylonitrile) and poly (EGDMA‐co‐AN) system). Above all, from this study, it was established that the porosity of the polymer microspheres is the most important factor that determines the distribution and adsorption amount of face‐centered cubic (fcc) Au nanoparticles in the final products. Our study showed that the continuous adsorption of Au nanoparticles with the aid of the large surface area and surface interaction sites formed more favorably the Au/polymer composite microspheres. The BET measurements of Au/poly(EGDMA‐co‐AN) composite microspheres reveals that the adsorption of Au nanoparticles into the pores kept the pore structure intact and made it more porous. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5627–5635, 2004 相似文献
26.
Transport of surface-modified iron nanoparticle in porous media and application to arsenic(III) remediation 总被引:1,自引:0,他引:1
Sushil Raj Kanel Dhriti Nepal Bruce Manning Heechul Choi 《Journal of nanoparticle research》2007,9(5):725-735
The surface-modified iron nanoparticles (S-INP) were synthesized, characterized and tested for the remediation of arsenite
(As(III)), a well known toxic groundwater contaminant of concern. The S-INP material was fully dispersed in the aqueous phase
with a particle size distribution of 2–10 nm estimated from high-resolution transmission electron microscopy (HR-TEM). X-ray
photoelectron spectroscopy (XPS) revealed that an Fe(III) oxide surface film was present on S-INP in addition to the bulk
zero-valent Fe0 oxidation state. Transport of S-INP through porous media packed in 10 cm length column showed particle breakthroughs of 22.1,
47.4 and 60 pore volumes in glass beads, unbaked sand, and baked sand, respectively. Un-modified INP was immobile and aggregated
on porous media surfaces in the column inlet area. Results using S-INP pretreated 10 cm sand-packed columns containing ∼2 g
of S-INP showed that 100 % of As(III) was removed from influent solutions (flow rate 1.8 mL min−1) containing 0.2, 0.5 and 1.0 mg L−1 As(III) for 9, 7 and 4 days providing 23.3, 20.7 and 10.4 L of arsenic free water, respectively. In addition, it was found
that 100% of As(III) in 0.5 mg/L solution (flow rate 1.8 mL min−1) was removed by S-INP pretreated 50 cm sand packed column containing 12 g of S-INP for more than 2.5 months providing 194.4
L of arsenic free water. Field emission scanning electron microscopy (FE-SEM) showed S-INP had transformed to elongated, rod-like
shaped corrosion product particles after reaction with As(III) in the presence of sand. These results suggest that S-INP has
great potential to be used as a mobile, injectable reactive material for in-situ sandy groundwater aquifer treatment of As(III). 相似文献
27.
S. D. Gunapala S. V. Bandara J. K. Liu S. B. Rafol J. M. Mumolo C. A. Shott R. Jones J. Woolaway II J. M. Fastenau A. K. Liu M. Jhabvala K. K. Choi 《Infrared Physics & Technology》2003,44(5-6):411-425
A 9 μm cutoff 640 × 512 pixel hand-held quantum well infrared photodetector (QWIP) camera has been demonstrated with excellent imagery. A noise equivalent differential temperature (NEDT) of 10.6 mK is expected at a 65 K operating temperature with f/2 optics at a 300 K background. This focal plane array has shown background limited performance at a 72 K operating temperature with the same optics and background conditions. In this paper, we discuss the development of this very sensitive long-wavelength infrared camera based on a GaAs/AlGaAs QWIP focal plane array and its performance in quantum efficiency, NEDT, uniformity, and operability. In the second section of this paper, we discuss the first demonstration of a monolithic spatially separated four-band 640 × 512 pixel QWIP focal plane array and its performance. The four spectral bands cover 4–5.5, 8.5–10, 10–12, and 13.5–15 μm spectral regions with 640 × 128 pixels in each band. In the last section, we discuss the array performance of a 640 × 512 pixel broad-band (10–16 μm full-width at half-maximum) QWIP focal plane. 相似文献
28.
Proton relaxation times in human red bone marrow by volume selective magnetic resonance spectroscopy
F. Schick H. Bongers W. -I. Jung B. Eismann M. Skalej H. Einsele O. Lutz C. Claussen 《Applied magnetic resonance》1992,3(6):947-963
In hematological diseases the composition of red bone marrow shows alterations. The relaxation timesT 1 andT 2 of water and lipids in human hemopoietic bone marrow of 14 normal volunteers and 10 patients with acute leukemia and bone marrow carcinosis are determined using a double spin echo spectroscopy sequencein vivo. The volumes of interest (VOI) of (13 mm)3 in the center of vertebral bodies are examined using different measurement parameters. ForT 1 measurements an inversion-recovery method is used.T 2 is evaluated from spectra with differentTE. T 1 (water) is found in a range between 1000 and 1700 ms,T 1 (lipids) in a range between 260 and 320 ms in healthy volunteers.T 2 (water) is determined between 32 and 65 ms. In some cases phase distortions of the water signals occur in the spectra. Water flow within the VOI may be a possible reason.T 2 (lipids) is evaluated between 73 and 91 ms. The patients with acute leukemia exhibit clearly reduced lipid signals in their spectra. Lipid relaxation times could not be determined in these cases.T 2 (water) is prolonged in acute leukemia to 51–98 ms.T 1 (water) was not significantly different from values of healthy volunteers in our measurements. Results are discussed in comparison to relaxometric data from imaging and STEAM spectroscopic methods of other authors. 相似文献
29.
Joo J.H. Choi J.J. 《IEEE transactions on plasma science. IEEE Nuclear and Plasma Sciences Society》2004,32(6):2263-2264
A new type of microwave amplifier module, consisting of a solid-state amplifier, a predistortion linearizer, and a traveling-wave-tube (TWT), is realized. Measurements show a noise figure of 2.2 dB at 9.5 GHz and the third-order intermodulation distortion ratio of 53 dBc at 10 dB back off from P1 dB point. 相似文献
30.
Dong Hwan Choi Yoshio Katakura Rieko Matsuda Yuzuru Hayashi Masato Hirobe Yasuhiro Goda Kazuaki Ninomiya Suteaki Shioya 《Analytical sciences》2007,23(2):215-218
The mathematical model for predicting the precision, limit of detection (LOD) and range of quantitation (ROQ) in a competitive enzyme-linked immunosorbent assay (ELISA) proposed by Hayashi et al. (Anal. Chem., 2004, 76, 1295) was validated. The model describes the relative standard deviation (RSD) of concentration estimates by the RSDs of pipetting volumes of analyte, enzyme-conjugated antigen, antibody and substrate solutions, and the standard deviation (SD) of inherent absorbances between the wells in an ELISA plate. For 6 kinds of direct competitive ELISA kits, the LOD and ROQ predicted by the model agreed well with those obtained by experiments with real samples. It was also confirmed that the model is applicable to the prediction of uncertainty that depends on the pipetting error of the viscous antiserum solution. The model was demonstrated to be useful for estimating the LOD and ROQ of competitive ELISA. 相似文献