全文获取类型
收费全文 | 7449篇 |
免费 | 385篇 |
国内免费 | 44篇 |
专业分类
化学 | 5653篇 |
晶体学 | 68篇 |
力学 | 146篇 |
数学 | 511篇 |
物理学 | 1500篇 |
出版年
2023年 | 58篇 |
2022年 | 146篇 |
2021年 | 173篇 |
2020年 | 131篇 |
2019年 | 154篇 |
2018年 | 115篇 |
2017年 | 111篇 |
2016年 | 265篇 |
2015年 | 226篇 |
2014年 | 298篇 |
2013年 | 450篇 |
2012年 | 588篇 |
2011年 | 660篇 |
2010年 | 398篇 |
2009年 | 362篇 |
2008年 | 533篇 |
2007年 | 443篇 |
2006年 | 426篇 |
2005年 | 352篇 |
2004年 | 295篇 |
2003年 | 256篇 |
2002年 | 284篇 |
2001年 | 139篇 |
2000年 | 129篇 |
1999年 | 82篇 |
1998年 | 46篇 |
1997年 | 66篇 |
1996年 | 60篇 |
1995年 | 49篇 |
1994年 | 32篇 |
1993年 | 46篇 |
1992年 | 46篇 |
1991年 | 30篇 |
1990年 | 36篇 |
1989年 | 40篇 |
1988年 | 15篇 |
1987年 | 18篇 |
1986年 | 17篇 |
1985年 | 31篇 |
1984年 | 25篇 |
1983年 | 19篇 |
1982年 | 19篇 |
1981年 | 14篇 |
1980年 | 13篇 |
1979年 | 11篇 |
1978年 | 15篇 |
1977年 | 19篇 |
1976年 | 12篇 |
1975年 | 12篇 |
1970年 | 17篇 |
排序方式: 共有7878条查询结果,搜索用时 15 毫秒
991.
The carbamoylphosphosphonate silane (CMPO analogue; 2-(diphenylphosphoryl)-N-(3-(triethoxysilyl)propyl) acetamide) modified mesoporous silica was prepared via a post-synthesis grafting method for the effective purification of rare earth elements. The guest CMPO analogue was synthesized by direct coupling reaction of 2-(diphenylphosphoryl) acetic acid and 3-(triethoxysilyl)propan-1-amine. Various mesoporous silicates such as MCM-41, SBA-15, or amorphous silica nanoparticles were adopted as host materials. The resulting surface-modified mesoporous materials were characterized with respect to their structural integrity, surface area, and pore size and the concentration of the CMPO silane species. These CMPO functionalized periodic mesostructured silicates offer the potential of applications as catalysts, sensors, or environmental sorbents. 相似文献
992.
A flux fusion method was used to obtain the various sizes of Eu3+-activated Y2O3 red phosphors. The flux material was selected as an independent variable to control the physical properties of phosphor particles and their effects on the morphology and size distribution of phosphors were examined by scanning electron microscopy. The concentration of the flux materials and synthetic temperature were optimized for maximal photoluminescence intensity. Fluoride-based flux materials were found to work for the crystal formation of Eu3+-activated Y2O3. In particular, when a BaF2 flux was used during the reaction at 1450 °C for 3 h, the photoluminescence (PL) intensity of Eu3+-activated Y2O3 was 25% higher than that without a flux and spherical phosphors had a mean particle size of 4-5 μm. The morphology and size distribution of the synthesized Eu3+-activated Y2O3 phosphor were predominantly dependent upon the type and concentration of flux material and synthetic temperature. 相似文献
993.
We derive the rigorous analytic solutions for the susceptibility of Doppler-broadened two-level atoms, valid for arbitrary laser intensities. As is usually the case with real atoms, we observe that, when the homogeneous linewidth is much narrower than the Doppler width, the real part of the susceptibility is given by the product of an imaginary error function and a Gaussian, whereas the imaginary part consists simply of a Gaussian function. By employing the analytic results, in particular, we study the effects of optical pumping and saturation on the atomic susceptibility. We also find that the real (imaginary) part of the susceptibility is weakly (strongly) dependent on such parameters as the laser intensity or the optical pumping rate. The availability of analytic solutions for the simple laser-atom interaction may provide convenient tools for its understanding as well as application to more general and realistic situations. 相似文献
994.
Nishimura K Browder TE Adachi I Aihara H Arinstein K Aushev T Bakich AM Balagura V Barberio E Belous K Bhardwaj V Bischofberger M Bondar A Bozek A Bračko M Chang MC Chao Y Chen A Chen KF Chen P Cheon BG Chiang CC Cho IS Choi Y Dalseno J Danilov M Doležal Z Drutskoy A Eidelman S Gabyshev N Golob B Ha H Haba J Hara T Hayasaka K Hayashii H Horii Y Hoshi Y Hou WS Hyun HJ Iijima T Inami K Itoh R Iwabuchi M Iwasaki Y Joshi NJ Julius T Kang JH Kapusta P Kawai H Kawasaki T Kichimi H Kiesling C Kim HJ 《Physical review letters》2010,105(19):191803
We report a first measurement of inclusive B→Xsη decays, where Xs is a charmless state with unit strangeness. The measurement is based on a pseudoinclusive reconstruction technique and uses a sample of 657×10(6)BB pairs accumulated with the Belle detector at the KEKB e+e- collider. For MXs < 2.6 GeV/c2, we measure a branching fraction of [26.1±3.0(stat)-2.1+1.9(syst)-7.1+4.0(model)]×10(-5) and a direct CP asymmetry of ACP=-0.13±0.04-0.03+0.02. Over half of the signal occurs in the range MXs > 1.8 GeV/c2. 相似文献
995.
Esen S Schwartz AJ Adachi I Aihara H Arinstein K Aulchenko V Aushev T Aziz T Bakich AM Balagura V Barberio E Bay A Bischofberger M Bondar A Bozek A Bračko M Browder TE Chang MC Chang P Chen A Chen P Cheon BG Chiang CC Choi Y Dalseno J Dash M Doležal Z Drásal Z Drutskoy A Eidelman S Goldenzweig P Golob B Ha H Haba J Hara T Hayasaka K Higuchi T Hoshi Y Hou WS Hsiung YB Hyun HJ Iijima T Inami K Itoh R Iwabuchi M Joshi NJ Julius T Kang JH Kawasaki T Kichimi H Kim HJ Kim HO Kim JH Kim YJ Kinoshita K 《Physical review letters》2010,105(20):201802
We have made the first observation of B(s)(0)→D(s)(*)+ D(s)(*)- decays using 23.6 fb(-1) of data recorded by the Belle experiment running on the Υ(5S) resonance. The branching fractions are measured to be B(B(s)(0)→D(s)+ D(s)-)=(1.03(-0.32-0.25)(+0.39+0.26))%, B(B(s)(0)→D(s)(*±) D(s)(?))=(2.75(-0.71)(+0.83)±0.69)%, and B(B(s)(0)→D(s)*+ D(s)*-)=(3.08(-1.04-0.86)(+1.22+0.85))%; the sum is B[B(s)(0)→D(s)(*)+ D(s)(*)-]=(6.85(-1.30-1.80)(+1.53+1.79))%. Assuming B(s)(0)→D(s)(*)+ D(s)(*)- saturates decays to CP-even final states, the branching fraction determines the ratio ΔΓ(s)/cosφ, where ΔΓ(s) is the difference in widths between the two B(s)-B(s) mass eigenstates, and φ is a CP-violating weak phase. Taking CP violation to be negligibly small, we obtain ΔΓ(s)/Γ(s)=0.147(-0.030)(+0.036)(stat)(-0.041)(+0.042)(syst), where Γ(s) is the mean decay width. 相似文献
996.
Christ NH Dawson C Izubuchi T Jung C Liu Q Mawhinney RD Sachrajda CT Soni A Zhou R;RBC UKQCD Collaborations 《Physical review letters》2010,105(24):241601
The large mass of the ninth pseudoscalar meson, the η', is believed to arise from the combined effects of the axial anomaly and the gauge field topology present in QCD. We report a realistic, 2+1-flavor, lattice QCD calculation of the η and η' masses and mixing which confirms this picture. The physical eigenstates show small octet-singlet mixing with a mixing angle of θ=-14.1(2.8)°. Extrapolation to the physical light quark mass gives, with statistical errors only, mη=573(6) MeV and mη'=947(142) MeV, consistent with the experimental values of 548 and 958 MeV. 相似文献
997.
We grew heterojunction light emitting diode (LED) structures with various n-type semiconducting layers by magnetron sputtering on p-type GaN at high temperature. Because the undoped ZnO used as an active layer was grown under oxygen rich atmosphere, all LED devices showed the EL characteristics corresponding to orange-red wavelength due to high density of oxygen interstitial, which was coincident with the deep level photoluminescence emission of undoped ZnO. The use of the Ga doped layers as a top layer provided the sufficient electron carriers to active region and resulted in the intense EL emission. The LED sample with small quantity of Mg incorporated in MgZnO as an n-type top layer showed more intense emission than the LED with ZnO, in spite of the deteriorated electrical and structural properties of the MgZnO film. This might be due to the improvement of output extraction efficiency induced by rough surface. 相似文献
998.
Hyun Suk Seo Yeong Mu Ko Jae Won Shim Joong-Ki Kook Byung Hoon Kim 《Applied Surface Science》2010,257(2):596-602
Plasma surface modification can be used to improve the surface properties of commercial pure Ti by creating functional groups to produce bioactive materials with different surface topography. In this study, a titanium surface was modified with acrylic acid (AA) using a plasma treatment and immobilized with bioactive arginine-glycine-aspartic acid (RGD) peptide, which may accelerate the tissue integration of bone implants. Both terminals containing the -NH2 of RGD peptide sequence and -COOH of poly(acrylic acid) (PAA) thin film were combined with a covalent bond in the presence of 1-ethyl-3-3-dimethylaminopropyl carbodiimide (EDC). The chemical structure and morphology of AA film and RGD immobilized surface were investigated by X-ray photoelectron spectroscopy (XPS), Fourier transform infrared (FT-IR), atomic force microscopy (AFM), and scanning electron microscopy (SEM). All chemical analysis showed full coverage of the Ti substrate with the PAA thin film containing COOH groups and the RGD peptide. The MC3T3-E1 cells were cultured on each specimen, and the cell alkaline phosphatase (ALP) activity were examined. The surface-immobilized RGD peptide has a significantly increased the ALP activity of MC3T3-E1 cells. These results suggest that the RGD peptide immobilization on the titanium surface has an effect on osteoblastic differentiation of MC3T3-E1 cells and potential use in osteo-conductive bone implants. 相似文献
999.
Seung-Jo Jung 《Journal of Pure and Applied Algebra》2018,222(7):1579-1605
1000.
Problem solving has long been a priority in mathematics education, and the first Common Core mathematical practice (SMP1) focuses on this priority through the language of “Make sense of problems and persevere in solving them.” We present findings from a survey about how prospective elementary teachers' (PTs) make sense of potential difficulties with fostering SMP1. Findings suggested that PTs' common anticipated difficulties relate to planning a solution pathway and self monitoring whether the solution makes sense. Moreover, a third of PTs disclosed that their anticipated difficulties are linked to their own personal struggles with aspects of SMP1. An alternative interpretation of SMP1 surfaced in which a small number of PTs described SMP1 as necessitating that a teacher teach multiple solution methods to students, instead of engaging students in productive struggle to develop their own strategies. We present a framework illustrating the connections between SMP 1 and Pólya's problem solving phases, and we discuss how these findings connect to and build on previous research of PTs' experiences with problem solving. We offer implications for the targeted support needed in teacher preparation programs to address these struggles, to prevent them from being replicated in their students. 相似文献